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Reply to: [{Th(C8H8)Cl2}3]2− is stable but not aromatic

The Original Article was published on 23 March 2022

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Fig. 1: The highest occupied molecular orbital of [{Th(C8H8)Cl2}3K2].

References

  1. Cuyacot, B. J. R. & Foroutan-Nejad, C. [{Th(C8H8)Cl2}3]2− is stable but not aromatic. Nature https://doi.org/10.1038/s41586-021-04319-z (2022).

  2. Boronski, J. T. et al. A crystalline tri-thorium cluster with σ-aromatic metal–metal bonding. Nature 598, 72–75 (2021).

  3. Krämer, K. The search for a grand theory of aromaticity. Chemistry World 18, 20–25 (2021).

    Google Scholar 

  4. Chen, Z., Wannere, C. S., Corminboeuf, C., Puchta, R. & von Ragué Schleyer, P. Nucleus-independent chemical shifts (NICS) as an aromaticity criterion. Chem. Rev. 105, 3842–3888 (2005).

    Article  CAS  Google Scholar 

  5. Szczepanik, D. W. et al. The electron density of delocalised bonds (EDDB) applied for quantifying aromaticity. Phys. Chem. Chem. Phys. 19, 28970 (2017).

    Article  CAS  Google Scholar 

  6. Báez-Grez, R., Ruiz, L., Pino-Rios, R. & Tiznado, W. Which NICS method is most consistent with ring current analysis? Assessment in simple monocycles. RSC Adv. 8, 13446 (2018).

    Article  ADS  Google Scholar 

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S.T.L. and N.K. wrote the Reply with all other authors commenting on the draft to produce the final version. All authors agreed on the final version.

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Correspondence to Nikolas Kaltsoyannis or Stephen T. Liddle.

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Boronski, J.T., Seed, J.A., Hunger, D. et al. Reply to: [{Th(C8H8)Cl2}3]2− is stable but not aromatic. Nature 603, E21–E22 (2022). https://doi.org/10.1038/s41586-021-04320-6

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