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Raw NMR data files for compounds 2a and 2b have been deposited with figshare (https://doi.org/10.6084/m9.figshare.7639703.v1).
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Extended data figures and tables
Extended Data Fig. 1 Minimum energy diastereomer of compound 1, two diastereomers of an alternative product, and comparison with a known vinyl acetate.
Compound numbering is indicated in red. Chemical shift values (in p.p.m.) are shown in blue.
Proposed mechanism leading to the observed product 2.
Isolation of vinyl esters 2a and 2b, and further evidence for their assignment from hydrolysis.
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Sader, J.K., Wulff, J.E. Reinvestigation of a robotically revealed reaction. Nature 570, E54–E59 (2019). https://doi.org/10.1038/s41586-019-1176-5
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