Various nitrogen nucleophiles, including nitrogen heterocycles, anilines, sulfonamides and amides, can cross-couple with carboxylic acids with good efficiency. All yields are isolated unless otherwise noted. All reactions were replicated at least twice for consistency. See Supplementary Information for full experimental details. #Yield was determined by 19F NMR with an internal standard. &Yield was determined by gas-chromatography analysis with an internal standard. *Single regioisomer.