The seminal paper by Yves Chauvin and Jean-Louis Hérisson on the mechanism of alkene metathesis is elegant, simple and insightful. Published more than 50 years ago, it deserves appreciation and admiration even today.
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References
Hérisson, J.-L. & Chauvin, Y. Catalyse de transformation des oléfines par les complexes du tungstène. II. Télomérisation des oléfines cycliques en présence d’oléfines acycliques [French]. Makromol. Chem. 141, 161–176 (1971).
Basset, J.-M. Yves Chauvin (1930–2015). Nature 519, 159 (2015).
Peters, E. F. & Evering, B. L. Catalysts and their preparation. US Patent 2,963,447 (1960).
Natta, G., Dall’Asta, G., Mazzanti, G. & Motroni, G. Stereospecific polymerization of cyclobutene. Makromol. Chem. 69, 163–179 (1963).
Wenzel, A. G. & Grubbs, R. H. Ruthenium metallacycles derived from 14-electron complexes — new insights into olefin metathesis intermediates. J. Am. Chem. Soc. 128, 16048–16049 (2006).
Schrock, R. R. et al. Synthesis of molybdenum imido alkylidene complexes and some reactions involving acyclic olefins. J. Am. Chem. Soc. 112, 3875–3886 (1990).
Nguyen, S. T., Johnson, L. K., Grubbs, R. H. & Ziller, J. W. Ring-opening metathesis polymerization (ROMP) of norbornene by a group VIII carbene complex in protic media. J. Am. Chem. Soc. 114, 3974–3975 (1992).
Huang, J., Stevens, E. D., Nolan, S. P. & Petersen, J. L. Olefin metathesis-active ruthenium complexes bearing a nucleophilic carbene ligand. J. Am. Chem. Soc. 121, 2674–2678 (1999).
Scholl, M., Trnka, T. M., Morgan, J. P. & Grubbs, R. H. Increased ring closing metathesis activity of ruthenium-based olefin metathesis catalysts coordinated with imidazolin-2-ylidene ligands. Tetrahedron Lett. 40, 2247–2250 (1999).
Weskamp, T., Kohl, F. J., Hieringer, W., Gleich, D. & Herrmann, W. A. Highly active ruthenium catalysts for olefin metathesis: the synergy of N-heterocyclic carbenes and coordinatively labile ligands. Angew. Chem. Int. Ed. 38, 2416–2419 (1999).
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Cazin, C.S.J. An alkene dance. Nat Rev Chem 5, 672–673 (2021). https://doi.org/10.1038/s41570-021-00318-w
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DOI: https://doi.org/10.1038/s41570-021-00318-w