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Liquid-phase syntheses of sulfide electrolytes for all-solid-state lithium battery

Nature Reviews Chemistry volume 3, pages 189–198 (2019)Cite this article

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Abstract

Solid sulfide electrolytes are key materials in all-solid-state lithium batteries because of their high lithium-ion conductivity and deformability, which enable the lithium-ion path to be connected between the material’s grain boundaries under pressure near room temperature. However, sulfur species are moisture-sensitive and exhibit high vapour pressures; therefore, syntheses of sulfide electrolytes need to be carefully designed. Liquid-phase reactions can be performed at low temperatures in controlled atmospheres, opening up the prospect of scalable processes for the preparation of sulfide electrolytes. Here, we review liquid-phase syntheses for the preparation of sulfide-based solid electrolytes and composites of electrolytes and electrodes, and we compare the charge–discharge performances of the all-solid-state lithium batteries using these components.

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Fig. 1: Schematic of liquid-phase syntheses of sulfide electrolytes.
Fig. 2: Suspension synthesis of sulfide electrolyte.
Fig. 3: Dissolution–precipitation of sulfide electrolyte.
Fig. 4: Liquid-phase processes for composite electrodes of all-solid-state lithium batteries.

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Acknowledgements

This Review includes research achievements partially supported by the Japan Science and Technology Agency (JST), the Advanced Low Carbon Technology Research and Development Program (ALCA) and the Specially Promoted Research for Innovative Next Generation Batteries (SPRING) project.

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Authors and Affiliations

  1. Faculty of Engineering, Hokkaido University, Sapporo, Japan

    Akira Miura, Nataly Carolina Rosero-Navarro & Kiyoharu Tadanaga

  2. Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Sakai, Japan

    Atsushi Sakuda, Akitoshi Hayashi & Masahiro Tatsumisago

  3. Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, Toyohashi, Japan

    Nguyen H. H. Phuc & Atsunori Matsuda

  4. Department of Chemistry, Konan University, Kobe, Japan

    Nobuya Machida

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  1. Akira Miura
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A.Mi., N.C.R.N., A.S. and K.T. wrote the draft. N.H.H.P., A.Ma., N.M., A.H. and M.T. discussed the Review. All the authors agreed upon the final version of the manuscript.

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Correspondence to Kiyoharu Tadanaga or Masahiro Tatsumisago.

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Miura, A., Rosero-Navarro, N.C., Sakuda, A. et al. Liquid-phase syntheses of sulfide electrolytes for all-solid-state lithium battery. Nat Rev Chem 3, 189–198 (2019). https://doi.org/10.1038/s41570-019-0078-2

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