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# Observation of an exotic narrow doubly charmed tetraquark

## Abstract

Conventional, hadronic matter consists of baryons and mesons made of three quarks and a quark–antiquark pair, respectively1,2. Here, we report the observation of a hadronic state containing four quarks in the Large Hadron Collider beauty experiment. This so-called tetraquark contains two charm quarks, a $$\overline{{{{{u}}}}}$$ and a $$\overline{{{{{d}}}}}$$ quark. This exotic state has a mass of approximately 3,875 MeV and manifests as a narrow peak in the mass spectrum of D0D0π+ mesons just below the D*+D0 mass threshold. The near-threshold mass together with the narrow width reveals the resonance nature of the state.

## Main

Quantum chromodynamics, the theory of the strong force, describes the interactions of coloured quarks and gluons and the formation of hadronic matter, that is, mesons and baryons. While quantum chromodynamics makes precise predictions at high energies, the theory has difficulties describing the interactions of quarks in hadrons from first principles due to the highly nonperturbative regime at the corresponding energy scale. Hence, the field of hadron spectroscopy is driven by experimental discoveries that are sometimes unexpected, which could lead to changes in the research landscape. Along with conventional mesons and baryons, made of a quark–antiquark pair ($${{{{{q}}}}}_{1}{\overline{{{{{q}}}}}}_{2}$$) and three quarks (q1q2q3), respectively, particles with an alternative quark content, known as exotic states, have been actively discussed since the birth of the constituent quark model1,2,3,4,5,6,7,8. This discussion has been revived by recent observations of numerous tetraquark $${{{{{q}}}}}_{1}{{{{{q}}}}}_{2}{\overline{{{{{q}}}}}}_{3}{\overline{{{{{q}}}}}}_{4}$$ and pentaquark $${{{{{q}}}}}_{1}{{{{{q}}}}}_{2}{{{{{q}}}}}_{3}{{{{{q}}}}}_{4}{\overline{{{{{q}}}}}}_{5}$$ candidates9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36. Due to the closeness of their masses to known particle-pair thresholds37,38, many of these states are likely to be hadronic molecules39,40,41,42 where colour-singlet hadrons are bound by residual nuclear forces similar to the electromagnetic van der Waals forces attracting electrically neutral atoms and molecules. An ordinary example of a hadronic molecule is the deuteron formed by a proton and a neutron. On the other hand, an interpretation of exotic states as compact multiquark structures is also possible43.

All exotic hadrons observed so far predominantly decay via the strong interaction, and their decay widths vary from a few to a few hundred MeV. A discovery of a long-lived exotic state, stable with respect to the strong interaction, would be intriguing. A hadron with two heavy quarks Q and two light antiquarks $$\overline{{{{{q}}}}}$$, that is, $${{{{{Q}}}}}_{1}{{{{{Q}}}}}_{2}{\overline{{{{{q}}}}}}_{1}{\overline{{{{{q}}}}}}_{2}$$, is a prime candidate to form such a state44,45,46,47,48,49. In the limit of a large heavy-quark mass, the two heavy quarks Q1Q2 form a point-like, heavy, colour-antitriplet object that behaves similarly to an antiquark, and the corresponding state should be bound. It is expected that the b quark is heavy enough to sustain the existence of a stable $${{{{b}}}}{{{{b}}}}\overline{{{{{u}}}}}\overline{{{{{d}}}}}$$ state with a binding energy of about 200 MeV with respect to the sum of the masses of the pseudoscalar, B or $${\overline{{{{{B}}}}}}^{0}$$, and vector, B*− or $${\overline{{{{{B}}}}}}^{* 0}$$, beauty mesons, which defines the minimal mass for the strong decay to be allowed. In the case of the $${{{{b}}}}{{{{c}}}}\overline{{{{{u}}}}}\overline{{{{{d}}}}}$$ and $${{{\rm{c}}}}{{{\rm{c}}}}\overline{{{{\rm{u}}}}}\overline{{{{\rm{d}}}}}$$ systems, there is currently no consensus regarding whether such states exist and are narrow enough to be detected experimentally. The similarity of the $$cc\overline{{{{{u}}}}}\overline{{{{{d}}}}}$$ tetraquark state and the $$\Xi_{cc}^{++}$$ baryon containing two c quarks and a u quark leads to a relationship between the properties of the two states. In particular, the measured mass of the $$\Xi_{cc}^{++}$$ baryon with quark content ccu50,51,52 implies that the mass of the $${{{{c}}}}{{{{c}}}}\overline{{{{{u}}}}}\overline{{{{{d}}}}}$$ tetraquark is close to the sum of the masses of the D0 and D*+ mesons with quark content of $${{{{c}}}}\overline{{{{{u}}}}}$$ and $${{{{c}}}}\overline{{{{{d}}}}}$$, respectively, as suggested in ref. 53. Theoretical predictions for the mass of the $${{\mbox{}}}{{{{c}}}}{{\mbox{}}}{{{{c}}}}{{\mbox{}}}\overline{{{{{u}}}}}{{\mbox{}}}\overline{{{{{d}}}}}{{\mbox{}}}$$ ground state with spin-parity quantum numbers JP = 1+ and isospin I = 0, denoted hereafter as $${{{{{T}}}}}_{{{{{c}}}}{{{{c}}}}}^{+}$$, relative to the D*+D0 mass threshold

$$\updelta m\equiv {m}_{{{{{{T}}}}}_{{{{{c}}}}{{{{c}}}}}^{+}}-\left({m}_{{{{{{D}}}}}^{* +}}+{m}_{{{{{{D}}}}}^{0}}\right)$$
(1)

lie in the range of −300 < δm < 300 MeV (refs. 53,54,55,56,57,58,59,60,61,62,63,64,65,66,67,68,69,70,71,72,73,74,75,76,77,78,79,80,81,82,83,84), where $${m}_{{{{{{D}}}}}^{* +}}$$ and $${m}_{{{{{{D}}}}}^{0}}$$ denote the known masses of the D*+ and D0 mesons38. Lattice quantum chromodynamics calculations also do not provide a definite conclusion on the existence of the $${{{{{T}}}}}_{{{{{c}}}}{{{{c}}}}}^{+}$$ state or its binding energy73,85,86,87. The observation of the $${{{\varXi }}}_{{{{{cc}}}}}^{++}$$ baryon50,51 and of a new exotic resonance decaying to a pair of J/ψ mesons29 by the LHCb experiment motivates the search for the $${{{{{T}}}}}_{{{{{c}}}}{{{{c}}}}}^{+}$$ state.

In this Letter, the observation of a narrow state in the D0D0π+ mass spectrum near the D*+D0 mass threshold compatible with being a $${{{{{T}}}}}_{{{{{c}}}}{{{{c}}}}}^{+}$$ tetraquark state is reported. Throughout this Letter, charge conjugate decays are implied. The study is based on proton–proton (pp) collision data collected by the LHCb detector at the Large Hadron Collider at the European Organization for Nuclear Research at centre-of-mass energies of 7, 8 and 13 TeV, corresponding to integrated luminosity of 9 fb−1. The LHCb detector88,89 is a single-arm forward spectrometer covering the pseudorapidity range of 2 < η < 5, designed to study particles containing b or c quarks and is further described in Methods. The pseudorapidity η is defined as $$-\log \left(\tan \frac{\theta }{2}\right)$$, where θ is a polar angle of the track relative to the proton beam line.

The D0D0π+ final state is reconstructed by selecting events with two D0 mesons and a positively charged pion, all produced at the same pp interaction point. Both D0 mesons are reconstructed in the D0Kπ+ decay channel. The selection criteria are similar to those used in ref. 90. To subtract the background not originating from two D0 candidates, an extended, unbinned maximum-likelihood fit to the two-dimensional distribution of the masses of the two D0 candidates is performed. The corresponding procedure, together with the selection criteria, is described in detail in Methods. To improve the δm mass resolution and to make the determination insensitive to the precision of the D0 meson mass, the mass of the D0D0π+ combinations is calculated with the mass of each D0 meson constrained to the known value38. The resulting D0D0π+ mass distribution for selected D0D0π+ combinations is shown in Fig. 1. A narrow peak near the D*+D0 mass threshold is clearly visible.

An extended, unbinned, maximum-likelihood fit to the D0D0π+ mass distribution is performed using a model consisting of the signal and background components. The signal component is described by the convolution of the detector resolution with a resonant shape, which is modelled by a relativistic P-wave two-body Breit–Wigner (BW) function modified by a Blatt–Weisskopf form factor with a meson radius parameter of 3.5 GeV−1. The use of a P-wave resonance is motivated by the expected JP = 1+ quantum numbers for the $${{{{{T}}}}}_{{{{{c}}}}{{{{c}}}}}^{+}$$ state. A two-body decay structure $${{{{{T}}}}}_{{{{{cc}}}}}^{+}\to {{{{AB}}}}$$ is assumed with $${m}_{{{{{A}}}}}=2{m}_{{{{{{D}}}}}^{0}}$$ and $${m}_{{{{{B}}}}}={m}_{{\pi }^{+}}$$, where $${m}_{{\pi }^{+}}$$ stands for the known mass of the π+ meson. Several alternative prescriptions are used for the evaluation of the systematic uncertainties. Despite its simplicity, the model serves well to quantify the existence of the $${{{{{T}}}}}_{{{{{c}}}}{{{{c}}}}}^{+}$$ state and to measure its properties, such as the position and the width of the resonance. A follow-up study91 investigates the underlying nature of the $${{{{{T}}}}}_{{{{{c}}}}{{{{c}}}}}^{+}$$ state, expanding on the modelling of the signal shape and the determination of its physical properties. The detector resolution is modelled by the sum of two Gaussian functions with a common mean, where the additional parameters are taken from simulation (Methods) with corrections applied32,92,93. The root mean square of the resolution function is around 400 keV c−2. A study of the D0π+ mass distribution for D0D0π+ combinations in the region above the D*0D+ mass threshold but below 3.9 GeV c−2 shows that approximately 90% of all random D0D0π+ combinations contain a genuine D*+ meson. On the basis of this observation, the background component is parameterized by the product of a two-body phase space function and a positive second-order polynomial. The resulting function is convolved with the detector resolution.

The fit results are shown in Fig. 1, and the parameters of interest, namely the signal yield, N, the mass parameter of the BW function relative to the D*+D0 mass threshold, $$\delta {m}_{{{{\rm{BW}}}}}\equiv {m}_{{{{\rm{BW}}}}}-({m}_{{{{{{D}}}}}^{* +}}+{m}_{{{{{{D}}}}}^{0}})$$, and the width parameter, ΓBW, are listed in Table 1. The statistical significance of the observed $${{{{{T}}}}}_{{{{{cc}}}}}^{+}{{{{{D}}}}}^{0}{{{{{D}}}}}^{0}{\pi }^{+}$$ signal is estimated using Wilks’ theorem to be 22 s.d. The fit suggests that the mass parameter of the BW shape is slightly below the D*+D0 mass threshold. The statistical significance of the hypothesis δmBW < 0 is estimated to be 4.3 s.d.

To validate the presence of the signal component, several additional cross-checks are performed. The data are categorized according to data-taking periods, including the polarity of the LHCb dipole magnet and the charge of the $${{{{{T}}}}}_{{{{{c}}}}{{{{c}}}}}^{+}$$ candidates. Instead of statistically subtracting the non-D0 background, the mass of each D → Kπ+ candidate is required to be within a narrow region around the known mass of the D0 meson38. The results are found to be consistent among all samples and analysis techniques. Furthermore, dedicated studies are performed to ensure that the observed signal is not caused by kaon or pion misidentification, doubly Cabibbo-suppressed D0 → K+π decays or $${{{{{D}}}}}^{0}{\overline{{{{{D}}}}}}^{0}$$ oscillations, decays of charm hadrons originating from beauty hadrons or artefacts due to the track reconstruction creating duplicate tracks.

Systematic uncertainties for the δmBW and ΓBW parameters are summarized in Table 2 and described below. The largest systematic uncertainty is related to the fit model and is studied using pseudoexperiments with alternative parameterizations of the D0D0π+ mass shape. Several variations in the fit model are considered: changes in the signal model due to the imperfect knowledge of the detector resolution, an uncertainty in the correction factor for the resolution taken from control channels, parameterization of the background component and the additional model parameters of the BW function. The model uncertainty related to the assumption of JP = 1+ quantum numbers of the state is estimated and listed separately. The results are affected by the overall detector momentum scale, which is known to a relative precision of δα = 3 × 10−4 (ref. 94). The corresponding uncertainty is estimated using simulated samples where the momentum scale is modified by factors of $$\left(1\pm \updelta \alpha \right)$$. In the reconstruction, the momenta of charged tracks are corrected for energy loss in the detector material, the amount of which is known with a relative uncertainty of 10%. The resulting uncertainty is assessed by varying the energy loss correction by ±10%. As the mass of the D0D0π+ combinations is calculated with the mass of each D0 meson constrained to the known value of the D0 mass, the δmBW parameter is insensitive to the precision of the D0 mass. However, the small uncertainty of 2 keV c−2 for the D*+ − D0 mass difference38 directly affects the δmBW value. The corresponding systematic uncertainty is added.

In summary, using the full dataset corresponding to an integrated luminosity of 9 fb−1 collected by the LHCb experiment at centre-of-mass energies of 7, 8 and 13 TeV, a narrow peak is observed in the mass spectrum of D0D0π+ candidates produced promptly in pp collisions. The statistical significance of the peak is overwhelming. Using the BW parameterization, the location of the peak relative to the D*+D0 mass threshold, δmBW, and the width, ΓBW, are determined to be

$$\begin{array}{rcl}\updelta {m}_{{{{\rm{BW}}}}}&=&-273\pm 61\pm {5\,}_{-14}^{+11}\,{{{\rm{keV}}}}\, {c}^{-2},\\ {{{\varGamma }}}_{{{{\rm{BW}}}}}&=&410\pm 165\pm 4{3\,}_{-38}^{+18}\,{{{\rm{keV}}}},\end{array}$$

where the first uncertainty is statistical, the second is systematic and the third is related to the assignment of the JP quantum numbers. The measured δmBW value corresponds to a mass of approximately 3,875 MeV. This is the narrowest exotic state observed to date37,38. The minimal quark content for this state is $${{{{c}}}}{{{{c}}}}\overline{{{{{u}}}}}\overline{{{{{d}}}}}$$. Two heavy quarks of the same flavour make it manifestly exotic, that is, beyond the conventional pattern of hadron formation found in mesons and baryons. Moreover, the combination of the near-threshold mass, narrow decay width and its appearance in prompt hadroproduction demonstrates its genuine resonance nature. The measured mass and width are consistent with the expected values for a $${{{{{T}}}}}_{{{{{c}}}}{{{{c}}}}}^{+}$$ isoscalar tetraquark ground state with quantum numbers JP = 1+. The precision of the mass measurement with respect to the corresponding threshold is superior to those of all other exotic states, which will give better understanding of the nature of exotic states. A dedicated study of the reaction amplitudes for the $${{{{{T}}}}}_{{{{{cc}}}}}^{+}\to{{{{{D}}}}}^{0}{{{{{D}}}}}^{0}{\pi }^{+}$$ and $${{{{{T}}}}}_{{{{{cc}}}}}^{+}\to{{{{{D}}}}}^{0}{{{{{D}}}}}^{+}{\pi }^{0}(\gamma )$$ decays that uses the isospin symmetry for the $${{{{{T}}}}}_{{{{{cc}}}}}^{+}\to{{{{{D}}}}}^{* }{{{{D}}}}$$ transition91 yields insights into the fundamental resonance properties, such as the pole position, the scattering length and the effective range. The observation of this $${{{{c}}}}{{{{c}}}}\overline{{{{{u}}}}}\overline{{{{{d}}}}}$$ tetraquark candidate close to the D*+D0 threshold provides strong support for the theoretical approaches and models that predict the existence of a $${{{{b}}}}{{{{b}}}}\overline{{{{{u}}}}}\overline{{{{{d}}}}}$$ tetraquark that is stable with respect to the strong and electromagnetic interactions.

## Methods

### Experimental setup

The LHCb detector88,89 is a single-arm forward spectrometer covering the pseudorapidity range of 2 < η < 5, designed to study particles containing b or c quarks. The detector includes a high-precision tracking system consisting of a silicon-strip vertex detector surrounding the pp interaction region, a large-area silicon-strip detector located upstream of a dipole magnet with a bending power of about 4 T m and three stations of silicon-strip detectors and straw drift tubes placed downstream of the magnet. The tracking system provides a measurement of the momentum, p, of charged particles with a relative uncertainty that varies from 0.5% at low momentum to 1.0% at 200 GeV c−1. The minimum distance of a track to a primary pp collision vertex, the impact parameter, is measured with a resolution of (15 + 29/pT) μm, where pT is the component of the momentum transverse to the beam, in GeV c−1. Different types of charged hadrons are distinguished using information from two ring-imaging Cherenkov detectors95. Photons, electrons and hadrons are identified by a calorimeter system consisting of scintillating-pad and preshower detectors and an electromagnetic and a hadronic calorimeter. Muons are identified by a system composed of alternating layers of iron and multiwire proportional chambers. The online event selection is performed by a trigger consisting of a hardware stage, based on information from the calorimeter and muon systems, followed by a software stage, which applies full event reconstruction. The trigger selection algorithms are primarily based on identifying key characteristics of beauty and charm hadrons and their decay products, such as high-pT final state particles, and a decay vertex that is significantly displaced from any of the pp interaction vertices in the event.

### Simulated samples

Simulation is required to model the effects of the detector acceptance and resolution and the imposed selection requirements. In the simulation, pp collisions are generated using PYTHIA with a specific LHCb configuration96. Decays of unstable particles are described by EVTGEN97. The interaction of the generated particles with the detector, and its response, are implemented using the GEANT4 toolkit as described in ref. 98.

### Selection

The selection of D → Kπ+ candidates and D0D0π+ combinations is similar to those used in ref. 90. Kaon and pion candidates are selected from well-reconstructed tracks within the acceptance of the spectrometer. Particle identification is provided using information from the ring-imaging Cherenkov detectors. Kaons and pions that have transverse momenta larger than 250 MeV c−1 and are inconsistent with being produced in a pp interaction vertex are combined together to form D0 candidates. The resulting D0 candidates are required to have good vertex quality, mass within ±65 MeV of the known D0 mass38 (the mass resolution for the D → Kπ+ signal being 7 MeV), transverse momentum larger than 1 GeV c−1, decay time longer than 100 μm c−1 and a momentum direction that is consistent with the vector from the primary to the secondary vertex. Selected pairs of D0 candidates consistent with originating from a common primary vertex are then combined with pion candidates of the same charge as the pions from the D → Kπ+ decay candidates to form D0D0π+ candidates. At least one of the two D0π+ combinations is required to have good vertex quality and mass not exceeding the known D0 mass by more than 155 MeV. For each D0D0π+ candidate, a kinematic fit99 is performed. This fit requires both D0 candidates and a pion to originate from the same primary vertex. A requirement on the quality of this fit is applied to further suppress combinatorial background and reduce the background from D0 candidates produced in two independent pp interactions or in decays of beauty hadrons90. To suppress the background from kaon and pion candidates reconstructed from one common track, all track pairs of the same charge are required to have an opening angle inconsistent with being zero and the mass of the combination inconsistent with the sum of the masses of the two constituents.

### Non-D0 background subtraction

The two-dimensional distribution of the mass of one D0 candidate versus the mass of the other D0 candidate from selected D0D0π+ combinations is used to subtract the background due to fake D0 candidates. The procedure employs the sPlot technique100, where an extended, unbinned, maximum-likelihood fit to the two-dimensional distribution is performed. The signal is described using a modified Novosibirsk function, and the background is modelled by a product of an exponential function and a positive polynomial function90. Each candidate is assigned a positive weight for being signal-like or a negative weight for being background-like, with the masses of the two D0 candidates as the discriminating variables. All candidates are then retained, and the weights are used in the further analysis for the statistical subtraction of the non-D0 background.

### Contributions from the $${{{{{D}}}}}^{0}{\overline{{{{{D}}}}}}^{0}$$ oscillations

A hypothetical, narrow, charmonium-like state decaying into the $${{{{{D}}}}}^{0}{\overline{{{{{D}}}}}}^{0}{\pi }^{+}$$ final state, followed by the $${\overline{{{{{D}}}}}}^{0}\to {{{{{D}}}}}^{0}$$ transition or doubly Cabibbo-suppressed decay $${\bar{D}}^{0}\to {{{{{K}}}}}^{-}{\pi }^{+}$$, would produce a narrow signal in the reconstructed D0D0π+ mass spectrum. If the observed, narrow, near-threshold peak in the reconstructed D0D0π+ system is caused by the $${{{{{D}}}}}^{0}{\overline{{{{{D}}}}}}^{0}$$ oscillations or doubly Cabibbo-suppressed decays, a much larger signal should be visible in the reconstructed $${{{{{D}}}}}^{0}{\overline{{{{{D}}}}}}^{0}{\pi }^{+}$$ mass spectrum at the same mass. No such structure is observed (see fig. 9 in ref. 91).

### Systematic uncertainties

Several sources of systematic uncertainty on the mass δmBW and width ΓBW of the $${{{{{T}}}}}_{{{{{c}}}}{{{{c}}}}}^{+}$$ state have been evaluated. The largest systematic uncertainty is related to the fit model and is studied using a set of alternative parameterizations and pseudoexperiments. For each alternative model, an ensemble of pseudoexperiments is produced. Each is generated using the model under consideration with parameters obtained from a fit to the data. A subsequent fit with the default model to each pseudoexperiment is performed and the mean values of the parameters of interest over the ensemble are evaluated. The absolute value of the difference between the ensemble mean and the value of the parameter obtained from the fit to the data sample is used to characterize the difference between the alternative model and the default model. The maximal value of such a difference over the considered set of alternative models is taken as the corresponding systematic uncertainty for the mass δmBW and width ΓBW of the $${{{{{T}}}}}_{{{{{c}}}}{{{{c}}}}}^{+}$$ state. The following sources of systematic uncertainties related to the fit model are considered:

• The imperfect knowledge of the detector resolution model: To estimate the associated systematic uncertainty, alternative resolution functions are studied, namely a symmetric variant of an Apollonios function, a modified Gaussian function with symmetric power-law tails on both sides of the distribution, a generalized symmetric Student’s t-distribution, a symmetric Johnson’s SU distribution and a modified Novosibirsk function.

• The difference in the detector resolution due to imperfect modelling: A correction factor of 1.05 for the resolution is applied for the default fit to account for such a difference. This factor was studied for several other decays measured with the LHCb detector and found to lie between 1.0 and 1.1 (refs. 92,93). For decays with relatively low-momentum tracks, this factor is close to 1.05. The factor is also cross-checked using large samples of D*+ → D0π+ decays, where a value of 1.06 is obtained. To assess the systematic uncertainty related to this factor, detector resolution models with correction factors of 1.0 and 1.1 are studied as alternative models.

• The parameterization of the background component: To assess the associated systematic uncertainty, the order of the positive polynomial function used for the baseline fit is varied. In addition, to estimate the possible effect of a small contribution from D0D0π+ combinations without an intermediate D*+ meson, a three-body background component is added to the fit. This component is described by a product of the three-body phase-space function and a positive linear or second-order polynomial function. The contribution from the non-resonant D0D0π+ background is negligible in the low-mass region due to the O(Q2) scaling of the three-body phase-space factor near threshold.

• The model parameters of the BW function: Alternative parameterizations include different choices for the decay structure, $${m}_{{{{{A}}}}}={m}_{{{{{{D}}}}}^{0}}$$ and $${m}_{{{{{B}}}}}={m}_{{{{{{D}}}}}^{0}}+{m}_{{\pi }^{+}}$$; the meson radius, 1.5 GeV−1 and 5 GeV−1, and the orbital angular momentum between A and B particles, corresponding to S- and D-waves. The effect of the different decay structure and the choice of the meson radius is smaller than 1 keV c−2 and 1 keV for the δmBW and ΓBW parameters, respectively. The parameters of interest are more sensitive to the choice of orbital angular momentum, in which the S-wave function gives larger δmBW and smaller ΓBW, whereas the D-wave function corresponds to smaller δmBW and larger ΓBW. As the S-wave and D-wave imply that the quantum numbers of the $${{{{{T}}}}}_{{{{{c}}}}{{{{c}}}}}^{+}$$ state differ from JP = 1+, the corresponding systematic uncertainty is considered separately and is not included it in the total systematic uncertainty.

The calibration of the momentum scale of the tracking system is based upon large calibration samples of B+J/ψK+ and J/ψμ+μ decays. The accuracy of this procedure has been checked using other fully reconstructed B decays together with two-body ϒ(nS) and $${{{{{K}}}}}_{{{{{S}}}}}^{0}$$ decays, and the largest deviation of the bias in the momentum scale of δα = 3 × 10−4 is taken as the uncertainty94. This is then propagated to uncertainties for the parameters of interest using simulated samples, where momentum scale corrections of $$\left(1\pm \updelta \alpha \right)$$ are applied. Half of the difference between the peak locations obtained with the 1 + δα and 1 − δα corrections applied to the same simulated sample is taken as an estimate of the systematic uncertainty due to the momentum scale. The main contribution to this uncertainty is due to the bachelor pion track, since the D0 mass constraint reduces the contributions from the kaon and pion tracks originating from D0 meson decays.

In the reconstruction, the momenta of the charged tracks are corrected for the energy loss in the detector material. The energy loss corrections are calculated using the Bethe–Bloch formula. The amount of material traversed in the tracking system by a charged particle is known to 10% accuracy. To assess the corresponding uncertainty, the magnitude of the calculated corrections is varied by ±10%. Half of the difference between the peak locations obtained with the +10% and −10% corrections applied to the same simulated sample is taken as an estimate of the systematic uncertainty due to the energy loss corrections.

The mass of the D0D0π+ combinations is calculated with both D0 candidate masses constrained to the known D0 meson mass38. This procedure removes the uncertainty on the δmBW parameter related to imprecise knowledge of the D0 mass. In contrast, the small uncertainty of 2 keV c−2 for the known D*+ − D0 mass difference38 directly affects the δmBW value and is therefore assigned as the corresponding systematic uncertainty.

## Data availability

LHCb data used in this analysis will be released according to the LHCb external data access policy, that can be downloaded from http://opendata.cern.ch/record/410/files/LHCb-Data-Policy.pdf.

The raw data shown in all of the figures of this manuscript can be downloaded from https://cds.cern.ch/record/2780001, where no access codes are required. In addition, the unbinned background-subtracted data, shown in Fig. 1 have been added to the HEPData record at https://www.hepdata.net/record/ins1915457.

## Code availability

LHCb software used to process the data analysed in this manuscript is available at GitLab repository https://gitlab.cern.ch/lhcb. The specific software used in data analysis is available at Zenodo repository https://doi.org/10.5281/zenodo.5595937.

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## Acknowledgements

This Letter is dedicated to the memory of our dear colleague Simon Eidelman, whose friendship, deep physics insights and contributions to improving the quality of our papers were greatly appreciated and will be missed. We express our gratitude to our colleagues in the CERN accelerator departments for the excellent performance of the LHC. We thank the technical and administrative staff at the LHCb institutes. We acknowledge support from CERN and from the following national agencies: CAPES, CNPq, FAPERJ and FINEP (Brazil); MOST and NSFC (China); CNRS/IN2P3 (France); BMBF, DFG and MPG (Germany); INFN (Italy); NWO (the Netherlands); MNiSW and NCN (Poland); MEN/IFA (Romania); MSHE (Russia); MICINN (Spain); SNSF and SER (Switzerland); NASU (Ukraine); STFC (United Kindgom); DOE NP and NSF (United States). We acknowledge the computing resources that are provided by CERN, IN2P3 (France), KIT and DESY (Germany), INFN (Italy), SURF (the Netherlands), PIC (Spain), GridPP (United Kingdom), RRCKI and Yandex LLC (Russia), CSCS (Switzerland), IFIN-HH (Romania), CBPF (Brazil), PL-GRID (Poland) and NERSC (United States). We are indebted to the communities behind the multiple open-source software packages on which we depend. Individual groups or members have received support from ARC and ARDC (Australia); AvH Foundation (Germany); EPLANET, Marie Skłodowska-Curie Actions and ERC (European Union); A*MIDEX, ANR, IPhU and Labex P2IO, and Région Auvergne-Rhône-Alpes (France); Key Research Program of Frontier Sciences of CAS, CAS PIFI, CAS CCEPP, Fundamental Research Funds for the Central Universities, and Sci. & Tech. Program of Guangzhou (China); RFBR, RSF and Yandex LLC (Russia); GVA, XuntaGal and GENCAT (Spain); the Leverhulme Trust, the Royal Society and UKRI (United Kingdom).

## Author information

### Contributions

All contributing authors, as listed at the end of this manuscript, have contributed to the publication, being variously involved in the design and construction of the detector, in writing software, calibrating sub-systems, operating the detector and acquiring data and finally analysing the processed data.

### Corresponding author

Correspondence to I. Belyaev.

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LHCb Collaboration. Observation of an exotic narrow doubly charmed tetraquark. Nat. Phys. (2022). https://doi.org/10.1038/s41567-022-01614-y

• Accepted:

• Published:

• DOI: https://doi.org/10.1038/s41567-022-01614-y

• ### Observation of an exotic narrow doubly charmed tetraquark

• R. Aaij
• A. S. W. Abdelmotteleb
• G. Zunica

Nature Physics (2022)

• ### Study of the doubly charmed tetraquark $${{{{{{\rm{T}}}}}}}_{{{{{{\rm{c}}}}}}{{{{{\rm{c}}}}}}}^{+}$$

• R. Aaij
• A. S. W. Abdelmotteleb
• G. Zunica

Nature Communications (2022)