Abstract
Topological Dirac and Weyl semimetals not only host quasiparticles analogous to the elementary fermionic particles in highenergy physics, but also have a nontrivial band topology manifested by gapless surface states, which induce exotic surface Fermi arcs^{1,2}. Recent advances suggest new types of topological semimetal, in which spatial symmetries protect gapless electronic excitations without highenergy analogues^{3,4,5,6,7,8,9,10,11}. Here, using angleresolved photoemission spectroscopy, we observe triply degenerate nodal points near the Fermi level of tungsten carbide with space group \(P\bar{6}m2\) (no. 187), in which the lowenergy quasiparticles are described as threecomponent fermions distinct from Dirac and Weyl fermions. We further observe topological surface states, whose constantenergy contours constitute pairs of ‘Fermi arcs’ connecting to the surface projections of the triply degenerate nodal points, proving the nontrivial topology of the newly identified semimetal state.
Main
The standard model predicts three types of fermionic elementary particle in the universe, Dirac, Weyl and Majorana fermions. So far, only Dirac fermions have been identified and the existence of Weyl and Majorana fermions has not been confirmed experimentally in highenergy physics. In recent years, it has been realized that crystal symmetryprotected gapless electronic excitations in condensedmatter systems are analogous to these elementary particles^{1,2,12,13,14}. For example, the excitations near four and twofold degenerate nodal points in the electronic structures can be described by the Dirac and Weyl equations, respectively^{1,2}. Materials hosting Dirac and Weyl nodes near the Fermi level (E _{F}), called Dirac and Weyl semimetals, have been predicted theoretically^{1,2,15,16,17,18} and discovered experimentally^{19,20,21,22,23}. One hallmark of Dirac and Weyl semimetals is the surface Fermi arcs connecting to the surface projection points of bulk Dirac or Weyl nodes^{1,2,15,16,17,18,20,21,22,23}. The connection in Weyl semimetals is topologically protected by nonzero topological charges of Weyl nodes^{1,15,16,17,18,20,21,22,23}. By contrast, the connection in Dirac semimetals is not protected since Dirac nodes have zero topological charge, and the Fermi arcs can be deformed into a closed Fermi surface (FS) by a strong surface potential or an arbitrarily small bulk perturbation that preserves the Dirac nodes and all of the symmetries^{2,24,25,26,27}. However, the surface states (SSs) in Dirac semimetals do have topological character manifested by the gapless SS bands connecting bulk valence and conduction bands, which are protected by the twodimensional (2D) topological properties on timereversal invariant planes in the Brillouin zone (BZ)^{24,26}.
In addition to four and twofold degeneracy, it has been shown that spacegroup symmetries in crystals may protect other types of degenerate point, near which the quasiparticle excitations are not the analogues of any elementary fermions described in the standard model. Theory has proposed three, six and eightfold degenerate points at highsymmetry momenta in the BZ in several specific nonsymmorphic space groups^{3,4,10,11}, where the combination of nonsymmorphic symmetries and other point symmetries leads to three, six and eightdimensional irreducible representations. Theory has also proposed that in a symmorphic space group \(P\bar{6}m2\) (no. 187) with the tungsten carbide (WC)type structure, the combination of rotation and mirror symmetries may protect threefold degenerate points on the highsymmetry line^{5,6,7,8,9}, which are accidental degeneracy points between the bands of one and twodimensional irreducible representations due to band inversion.
In this work, we investigate the threefold degeneracy proposed in the symmorphic system WC^{6,7,8,9}. As illustrated in Fig. 1a, the threefold degeneracy lies in an intermediate state between Dirac and Weyl states. Recovering inversion symmetry makes two triply degenerate nodal points (TPs) merging into a single Dirac node, while applying a Zeeman field along the rotation axis drives a TP into two Weyl nodes^{6,7,8,9}. In contrast to isolated Dirac and Weyl nodes, the pair of TPs is connected by a doubly degenerate band. For an arbitrary E _{F} near the TPs, the two FS pockets that contain the TPs are touching. Therefore, the topological charge of the TPs in WC is undefined. This is topologically distinct from the TPs enforced by nonsymmorphic symmetries, which have nonzero topological charge^{4}.
The presence of TPs was first demonstrated by our previous angleresolved photoemission spectroscopy (ARPES) measurements on MoP, which is isostructural to WC^{28}. MoP has recently been reported to have extremely low resistivity and high carrier mobility, although the TPs are far below E _{F} and the threecomponent fermions are thought to have little contribution to lowenergy quasiparticle excitations^{29}. Since topological SSs are not observed in MoP^{28}, evidence of the topological nature for the TP semimetal state is still lacking. In this work, using ARPES we clearly observe the TPs near E _{F} in the electronic structure of WC. The lowenergy quasiparticles on the FSs containing the TPs are described as threecomponent fermions. Very recently, we have observed quite strong anisotropic longitudinal magnetoresistance in WC^{30}, which is likely to be related to the behaviour of threecomponent fermions under magnetic fields applied along different directions, as theoretically proposed^{6}. This is in sharp contrast to the isotropic longitudinal magnetoresistance observed in Dirac and Weyl semimetals^{31,32}. Moreover, we identify surface Fermi arcs connecting to the projections of the TPs on the (100) surface of WC. It should be noted that the connection in WC is not protected due to the undefined topological charge of the TPs. We thus classify them as Diractype Fermi arcs, which are distinct from the Weyltype Fermi arcs whose connection is protected by nonzero topological charges. As with Dirac semimetals, our study reveals that WC hosts gapless SS bands protected by the bulk band topology on the timereversal invariant k _{ z } = π planes, explicitly demonstrating the nontrivial topology of the semimetallic phase of WC.
Band calculations of WC indicate an inversion between the \({d}_{{z}^{2}}\) and \({e}_{g}\) states at the A point, leading to a band crossing along Γ–A^{6,7,8,9}. When spin–orbit coupling (SOC) is considered, these bands along Γ–A are reconstructed into two doubly degenerate J _{ z } = 1/2 bands and two singly degenerate J _{ z } = 3/2 bands^{6}. The C _{3z } symmetry protects the crossing points between the J _{ z } = 1/2 and 3/2 bands, resulting in four TPs on the Γ–A line (Fig. 1c). In the plane perpendicular to Γ–A, three singly degenerate bands converge at a TP (Fig. 1g,h). The strong SOC of W 5d electrons causes large band splitting in WC as compared with MoP, which facilitates the identification of TPs and the investigation of associated topological properties in ARPES experiments.
The measured samples have a typical triangular shape. The triangle surface is the (001) plane and its edge is along the [010] direction, as illustrated in the inset of Fig. 1d. We obtained mirrorlike (001) and (100) surfaces on a macroscopic scale (~ 0.1 × 0.1 mm^{2}) by cleavage. However, in the ARPES experiments with vacuum ultraviolet (VUV) light, we did not observe any dispersive bands on both surfaces. In contrast, we observe clear band dispersions with photon energy (hν) larger than 300 eV. To understand this phenomenon, we measured the (100) cleavage surface with scanning tunnelling microscopy (STM). A typical STM topographic image is shown in Fig. 4g. We did not observe any ordered lattice in all of the measured regions on several cleaved surfaces, indicating that the top layer is disordered and should not support a welldefined band structure. As the photoelectrons excited by VUV light have a mean free path on the order of a few ångströms, we detect the electronic states only in the disordered layer in the VUV ARPES experiments. By contrast, the photoelectrons excited by soft xray light have a much longer mean free path^{33}, and therefore using soft xray ARPES we are able to detect the welldefined band structure in the ordered lattice beneath the disordered layer.
The measured electronic structure exhibits a periodic modulation with varying hν. Figure 2d,e plots the FSs recorded with two different hν values on the (001) surface, which are qualitatively consistent with the calculated bulk FSs in the k _{ z } = 0 (Fig. 2h) and π (Fig. 2i) planes, respectively. The ARPES results exhibit four FSs located around Γ, K, A and L. Although the calculations indicate that SOC splits each FS in two, the splitting is not resolved in the FSs measured by ARPES. To further characterize the FS structures, we have performed quantum oscillation (QO) measurements with magnetic fields (B) up to 38 tesla (Fig. 2c), which is a powerful experimental technique to measure the extreme crosssections of FSs in the planes perpendicular to B ^{34}. The fast Fourier transform (FFT) spectra of the QO data with B // c exhibit eight principal frequencies F _{1}–F _{8}, which should correspond to the split FSs at Γ, L, K and A in the k _{ x }–k _{ y } planes. Considering the crosssectional areas, the two doublepeak structures F _{1,2} and F _{3,4} are assigned to the split FSs at Γ and L, respectively. However, it is difficult to assign F _{5}–F _{8} since the sizes of the FSs at K and A are close. We derive the Fermi velocities from the FFT spectra at different temperatures in the Supplementary Information. By comparing them with those of the band dispersions recorded by ARPES, we assign F _{5,7} and F _{6,8} to the split FSs at K and A, respectively.
We further investigate the FSs in the k _{ y }–k _{ z } planes by ARPES measurements on the (100) surface. The calculated bulk FSs in the k _{ y }–k _{ z } plane (Fig. 2j) are consistent with our observation in Fig. 2f,g, although the FS splitting is not resolved experimentally. In addition, we observe almost straight FS lines in Fig. 2f,g, which are absent in the calculated bulk FSs. The hν dependence measurements (Supplementary Fig. 1) show that the extra feature has a constant momentum location, which is an indication of SSs. Its spectral intensity is strongly modulated with a periodicity in agreement with the bulk BZ. This indicates that the SSs are strongly hybridized with the bulk states. Next we demonstrate the presence of TPs in the bulk electronic structure of WC (Fig. 3) and discuss the topological properties of the SSs (Fig. 4).
The band calculations indicate that only TP no. 1 is located below E _{F} (Fig. 1c). A schematic threedimensional (3D) plot of the band structure near TP no. 1 in the k _{ x } = 0 plane is displayed in Fig. 3a. To search for the theoretically proposed TP no. 1, we have systematically measured the band dispersions on the (100) surface. The ARPES data along Γ–A in Fig. 3c exhibit three electron bands around A. In Fig. 3d, we overlap the calculated band structure on top of the experimental data around A. According to the Kramers theorem, the bands must be spindegenerate at the timereversal invariant momentum A. The calculations in Fig. 3d show that the two deep bands are degenerate at Α and exhibit Rashbalike splitting on dispersing towards Γ, whereas the shallow band remains doubly degenerate along the Γ–A direction, which is protected by the vertical mirror symmetry M _{ y }. The doubly degenerate band crosses the inner singly degenerate band at ~200 meV below E _{F}, which produces TP no. 1. The calculated band structure, especially the band crossing, is fully consistent with our experimental band dispersions, confirming the presence of TP no. 1 in the electronic structure of WC.
To further characterize TP no. 1, we measured the band dispersions perpendicular to Γ–A. Figure 3f–j shows the experimental band dispersions along five representative cuts at different k _{ z } values, whose momentum locations are illustrated in Fig. 3a,b. We observe one electron band and one hole band along cut 1 (k _{ z } = π) in Fig. 3f. The hole band splits into two bands when sliding the cut away from k _{ z } = π. The upper hole band touches the electron band at ~200 meV below E _{F} along cut 3 (Fig. 3h). We further resolve double peaks from the momentum distribution curve at E _{F} in Fig. 3h, which is supported by the curvature intensity plot in Fig. 3e. This indicates that the electron band dispersion consists of two nearby bands. The experimental band dispersions are well reproduced by our calculations in Fig. 3m, which show that two electron bands and one hole band are touching at one point along cut 3. This consistency between experiment and calculation provides further evidence for the presence of TP no. 1.
Next, we prove the nontrivial topology of the semimetal state in WC by investigating the SSs observed on the (100) surface. As the disordered top layer does not have a welldefined band structure, the SSs that we observe should lie on the boundary of the ordered lattice, which is beneath the disordered layer.
The intensity map at 200 meV below E _{F}, corresponding to the energy of TP no. 1, shows that the FS lines enter into the bulk states at the projection points of TP no. 1 (Fig. 4a). A similar feature is also observed in our slab calculations (Fig. 4b), although the calculations cannot simulate the real surface covered by a disordered layer. The calculations reveal two pairs of Fermi arcs, which are the constantenergy contours of two nearly parallel SS bands, as seen in Fig. 4e. A slight splitting of the SS bands is also observed in our experimental data (Fig. 4c,d), suggesting that the observed FS lines are composed of two pairs of Fermi arcs, which are indicated as SS1 in Fig. 4j. To understand the surface Fermi arcs, we investigate the 2D topological property on the k _{ z } = 0 plane (see details in the Supplementary Information). This is because the Fermi arcs cross the (100) surface projection line \(\widetilde{{\rm{\Gamma }}}\widetilde{{\rm{X}}}\) of the timereversal invariant k _{ z } = 0 plane, so that they are dictated by the bulk band topology on the k _{ z } = 0 plane^{35,36}. The topological invariant Z _{2} for the k _{ z } = 0 plane is found to be trivial, meaning that there are pairs of SS bands between \(\widetilde{{\rm{\Gamma }}}\) and \(\widetilde{{\rm{X}}}\), which constitute the double pairs of Fermi arcs, as illustrated in Fig. 4j.
By contrast, our calculations show that the timereversal invariant k _{ z } = π plane has a nontrivial topological invariant Z _{2} = 1 (Supplementary Fig. 2), and thus gapless Dirac SS bands connecting the bulk valence and conduction bands should appear along \(\widetilde{{\rm{A}}}\widetilde{{\rm{R}}}\) (refs ^{35,36}). In Fig. 3f, we observe a hole band that almost touches the bulk electron band at A, but its spectral intensity recorded with linearly horizontal polarized light is very low. Using righthand circular polarized light, the spectral intensity of the hole band is substantially enhanced, as shown in Fig. 4h. Our hν dependence measurements indicate that the hole band is also SSs, which is strongly hybridized with the bulk states. Since no other SSs are observed along \(\widetilde{{\rm{A}}}\widetilde{{\rm{R}}}\), we attribute the hole band to the lower branch of the expected surface Dirac bands. This means that the surface Dirac node at \(\widetilde{{\rm{A}}}\) is very close to the bottom of bulk conduction bands (Fig. 4i) and therefore the upper branch is difficult to resolve. However, the nontrivial topology in the k _{ z } = π plane guarantees the existence of the upper branch. The constantenergy contour of the upper branch constitutes either a closed FS circle enclosing \(\widetilde{{\rm{A}}}\) or a pair of Fermi arcs connecting to the surface projections of two TP no. 1 points on both sides of the surface BZ boundary, which is indicated as SS2 in Fig. 4j.
Our results suggest that three pairs of Fermi arcs emanate from the (100) surface projection of TP no. 1 (Fig. 4j). We note that the SS1 is topologically distinct from the SS2. As the k _{ z } = 0 plane has a trivial topological invariant Z _{2} = 0, the existence of SS1 is not guaranteed and it can be fully removed by continuous deformation^{35,36}. By contrast, the k _{ z } = π plane has a nontrivial topological invariant Z _{2} = 1, which guarantees the existence of gapless Dirac SS bands along \(\widetilde{{\rm{A}}}\widetilde{{\rm{R}}}\) ^{35,36}. Therefore, the SS2 can be deformed into a closed FS enclosing \(\widetilde{{\rm{A}}}\) but cannot be fully removed. With the observation of topological SSs in WC, we prove the nontrivial topology of the new type of semimetal state beyond Dirac and Weyl semimetals.
Finally, we mention that the threecomponent fermions observed in WC are essentially distinct from the chiral fermions enforced by filling and symmetry in the nonsymmorphic systems^{4,10,11,18}, in which the nonzero topological charges protect the Weyltype Fermi arcs. In the latter case, the bulk nodes with opposite topological charges are pinned at either the centre or the corner of the bulk BZ, and thus the surface Fermi arcs connecting their projections can span over a wider segment of the surface BZ. As far as we know, all of the topological semimetals experimentally identified are driven by band inversion and the effects of SOC. The discovery of symmetryenforced topological semimetals calls for future experimental efforts.
Methods
Sample growth
Highquality single crystals of WC were grown by the flux method^{30}. The starting materials, W, C and Co, were mixed in the ratio of 1:1:5, and placed in a graphite crucible with a cap. The crucible was heated to 1,700 °C, held for 50 h, and then cooled to 1,400 °C at a rate of 1 °C h^{–1} in an argon atmosphere. The Co flux was then removed by dissolving in a warm hydrochloric acid solution. The obtained single crystals are in the form of equilateral triangles with sides of 3 mm and thickness of 0.3 mm. The crystal structure was characterized by Xray diffraction using a PANalytical diffractometer with Cu K_{α} radiation at room temperature. The elemental compositions were checked by Oxford XMax energy dispersive Xray spectroscopy analysis in a Hitachi S4800 scanning electron microscope^{30}.
ARPES and quantum oscillation measurements
Soft xray ARPES measurements were performed at the ‘Dreamline’ beamline of the Shanghai Synchrotron Radiation Facility with a Scienta Omicron DA30L analyser. The energy and angular resolutions were set to 60–100 meV and 0.2°, respectively. The samples for ARPES measurements were cleaved in situ and measured at 30 K in a vacuum better than 5 × 10^{−11} torr. Highfield magnetoresistance oscillation was measured on the bar specimen by a standard fourpoint probe technique at the Steady High Magnetic Field Facilities, High Magnetic Field Laboratory, Chinese Academy of Sciences and at the National High Magnetic Field Laboratory, Tallahassee, USA.
Calculation
WC is crystallized in a hexagonal lattice with space group \(P\bar{6}m2\) (no. 187). The lattice constants a = b = 2.918 Å, and c = 2.846 Å are adopted in our calculations. The W and C atoms are located at Wyckoff positions 1d (1/3, 2/3, 1/2) and 1a (0, 0, 0), respectively. The Vienna Ab initio Simulation Package (VASP)^{37,38} with the generalized gradient approximation–Perdew, Burke and Ernzerhof (PBE–GGA)type exchange correlation potential is employed in our firstprinciples calculations^{39}. The planewave cutoff energy is 500 eV and the kpoint sampling grid is 11 × 11 × 11. The maximally localized Wannier functions for 5d orbitals on W and 2p orbitals on C have been constructed by using the Wannier90 package^{40}. SOC is taken into account in all of the above calculations. A slab with a thickness of 15 unit cells along the c lattice has been used in our (100) surfacestate calculations. The slab is separated by a vacuum layer of 10 Å, above which the calculated electronic structures are converged, indicating that the interactions between different slabs are avoided sufficiently.
Data availability
The data that support the plots within this paper and other findings of this study are available from the corresponding author upon reasonable request.
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Acknowl1edgements
We acknowledge G. Li for valuable discussion. This work was supported by the Ministry of Science and Technology of China (2016YFA0300600, 2016YFA0401000, 2016YFA0302400, 2015CB921300, 2013CB921700, 2016YFA0202301 and 2016YFA0300300), the National Natural Science Foundation of China (11622435, 11474340, 11422428, 11674369, 11234014, 11404175, 61725107 and 11674371) and the Chinese Academy of Sciences (XDB07000000 and XDB06). Y.B.H. acknowledges funding from the CAS Pioneer Hundred Talents Program (type C). A portion of this work performed at the National High Magnetic Field Laboratory, Tallahassee, USA, is supported by the National Science Foundation Cooperative Agreement DMR1157490 and the State of Florida.
Author information
Author notes
J.Z. Ma, J.B. He and Y.F. Xu contributed equally to this work.
Affiliations
Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Beijing, China
 J.Z. Ma
 , J.B. He
 , Y.F. Xu
 , B. Q. Lv
 , D. Chen
 , W.L. Zhu
 , S. Zhang
 , L.Y. Kong
 , X. Gao
 , P. Richard
 , Y. Shao
 , Y.L. Wang
 , H.J. Gao
 , X. Dai
 , C. Fang
 , H.M. Weng
 , G.F. Chen
 , T. Qian
 & H. Ding
School of Physics, University of Chinese Academy of Sciences, Beijing, China
 J.Z. Ma
 , Y.F. Xu
 , B. Q. Lv
 , D. Chen
 , W.L. Zhu
 , L.Y. Kong
 , X. Gao
 , L.Y. Rong
 , P. Richard
 , Y. Shao
 , Y.L. Wang
 , H.J. Gao
 , X. Dai
 , G.F. Chen
 & H. Ding
College of Physics and Electronic Engineering, Nanyang Normal University, Nanyang, China
 J.B. He
Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai, China
 L.Y. Rong
 & Y.B. Huang
Collaborative Innovation Center of Quantum Matter, Beijing, China
 P. Richard
 , Y.L. Wang
 , H.J. Gao
 , X. Dai
 , H.M. Weng
 , G.F. Chen
 , T. Qian
 & H. Ding
Anhui Province Key Laboratory of Condensed Matter Physics at Extreme Conditions, High Magnetic Field Laboratory of the Chinese Academy of Sciences, Hefei, Anhui, China
 C.Y. Xi
National High Magnetic Field Laboratory, Tallahassee, FL, USA
 E. S. Choi
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Contributions
H.D. and T.Q. conceived the ARPES experiments; J.Z.M. and T.Q. performed ARPES measurements with the assistance of B.Q.L., L.Y.K., X.G., L.Y.R. and Y.B.H.; Y.F.X. and H.M.W. performed ab initio calculations; J.B.H., D.C., W.L.Z. and G.F.C. synthesized the single crystals; S.Z., D.C., C.Y.X., E.S.C. and G.F.C. performed quantum oscillation measurements; J.Z.M., T.Q. and H.D. analysed the experimental data; J.Z.M., Y.F.X., T.Q. and J.B.H. plotted the figures; X.D. discussed the experimental and calculated data; Y.S., J.Z.M., Y.L.W. and H.J.G. performed STM experiments. T.Q., C.F., H.M.W., H.D., J.Z.M. and P.R. wrote the manuscript.
Competing interests
The authors declare no competing financial interests.
Corresponding authors
Correspondence to G.F. Chen or T. Qian or H. Ding.
Supplementary information
Supplementary Information
Supplementary Information, Supplementary Figures 1–3, Supplementary Table, References
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