Abstract
On-chip polarization-sensitive photodetectors offer unique opportunities for next-generation ultra-compact polarimeters. So far, mainstream approaches have relied on the anisotropic absorption of natural materials or artificial structures. However, such a model is inherently restricted by correlation between the polarization ratio (PR) and diattenuation, leading to small PR values (1 < PR < 10). Here, we report nanoantenna-mediated semimetal photodetectors, which enable configurable polarity transition by exploiting the vectorial and non-local photoresponse in semimetals. By tuning the orientation of nanoantennas, PR values vary from positive (unipolar regime) to negative (bipolar regime), covering all possible numbers (1 → ∞/−∞ → −1). In particular, the PR values at the polarity-transition point could approach infinity. Such a polarity transition hereby transcends the conventional PR–diattenuation relationship. Furthermore, our device allows the subtle measurement of polarization-angle perturbation down to 0.02° Hz−1/2 in the mid-infrared range. Our findings highlight the potential of semimetals as a promising material platform for miniaturized polarimetry.
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Data availability
All technical details for producing the figures are enclosed in the Supplementary Information. Data are available from the corresponding authors C.-W.Q. or C.L. upon request.
Code availability
All technical details for implementing the simulation of nanoantenna-driven photocurrents in graphene are enclosed in the Supplementary Information. Python codes are available from the corresponding authors C.-W.Q. or C.L. upon request.
References
Rubin, N. A. et al. Matrix Fourier optics enables a compact full-Stokes polarization camera. Science 365, eaax1839 (2019).
Graydon, O. Global position by polarization. Nat. Photonics 12, 318–318 (2018).
Tyo, J. S., Goldstein, D. L., Chenault, D. B. & Shaw, J. A. Review of passive imaging polarimetry for remote sensing applications. Appl. Opt. 45, 5453–5469 (2006).
Martínez, A. Polarimetry enabled by nanophotonics. Science 362, 750–751 (2018).
Lepetit, T. & Kanté, B. Simultaneous Stokes parameters. Nat. Photonics 9, 709–710 (2015).
Pors, A., Nielsen, M. G. & Bozhevolnyi, S. I. Plasmonic metagratings for simultaneous determination of Stokes parameters. Optica 2, 716–723 (2015).
Gruev, V., Perkins, R. & York, T. CCD polarization imaging sensor with aluminum nanowire optical filters. Opt. Express 18, 19087–19094 (2010).
Maruyama, Y. et al. 3.2-MP back-illuminated polarization image sensor with four-directional air-gap wire grid and 2.5-μm pixels. IEEE Trans. Electron Devices 65, 2544–2551 (2018).
Yuan, H. et al. Polarization-sensitive broadband photodetector using a black phosphorus vertical p–n junction. Nat. Nanotechnol. 10, 707–713 (2015).
Bullock, J. et al. Polarization-resolved black phosphorus/molybdenum disulfide mid-wave infrared photodiodes with high detectivity at room temperature. Nat. Photonics 12, 601–607 (2018).
Tong, L. et al. Stable mid-infrared polarization imaging based on quasi-2D tellurium at room temperature. Nat. Commun. 11, 2308 (2020).
Guo, Q. et al. Efficient electrical detection of mid-infrared graphene plasmons at room temperature. Nat. Mater. 17, 986–992 (2018).
Li, W. et al. Circularly polarized light detection with hot electrons in chiral plasmonic metamaterials. Nat. Commun. 6, 8379 (2015).
Ji, Z. et al. Photocurrent detection of the orbital angular momentum of light. Science 368, 763–767 (2020).
Afshinmanesh, F., White, J. S., Cai, W. & Brongersma, M. L. Measurement of the polarization state of light using an integrated plasmonic polarimeter. Nanophotonics 1, 125–129 (2012).
Wang, J., Gudiksen, M. S., Duan, X., Cui, Y. & Lieber, C. M. Highly polarized photoluminescence and photodetection from single indium phosphide nanowires. Science 293, 1455–1457 (2001).
Singh, A. et al. Polarization-sensitive nanowire photodetectors based on solution-synthesized CdSe quantum-wire solids. Nano Lett. 7, 2999–3006 (2007).
Feng, J. et al. Crystallographically aligned perovskite structures for high-performance polarization-sensitive photodetectors. Adv. Mater. 29, 1605993 (2017).
Xiao, M. et al. Symmetry-reduction enhanced polarization-sensitive photodetection in core–shell SbI3/Sb2O3 van der Waals heterostructure. Small 16, 1907172 (2020).
Wang, X. et al. Short-wave near-infrared linear dichroism of two-dimensional germanium selenide. J. Am. Chem. Soc. 139, 14976–14982 (2017).
Hong, T. et al. Polarized photocurrent response in black phosphorus field-effect transistors. Nanoscale 6, 8978–8983 (2014).
Yang, Y. et al. Polarization‐sensitive ultraviolet photodetection of anisotropic 2D GeS2. Adv. Funct. Mater. 29, 1900411 (2019).
Peng, Y. et al. Exploiting the bulk photovoltaic effect in a 2D trilayered hybrid ferroelectric for highly sensitive polarized light detection. Angew. Chem. Int. Ed. 59, 3933–3937 (2020).
Venuthurumilli, P. K., Ye, P. D. & Xu, X. Plasmonic resonance enhanced polarization-sensitive photodetection by black phosphorus in near infrared. ACS Nano 12, 4861–4867 (2018).
Wu, D. et al. Highly polarization-sensitive, broadband, self-powered photodetector based on graphene/PdSe2/germanium heterojunction. ACS Nano 13, 9907–9917 (2019).
Zeng, L. et al. Multilayered PdSe2/perovskite Schottky junction for fast, self-powered, polarization-sensitive, broadband photodetectors, and image sensor application. Adv. Sci. 6, 1901134 (2019).
Pi, L. et al. Highly in-plane anisotropic 2D PdSe2 for polarized photodetection with orientation selectivity. Adv. Funct. Mater. 31, 2006774 (2020).
Kim, D. J. & Alexe, M. Bulk photovoltaic effect in monodomain BiFeO3 thin films. Appl. Phys. Lett. 110, 183902 (2017).
Bhatnagar, A., Roy Chaudhuri, A., Heon Kim, Y., Hesse, D. & Alexe, M. Role of domain walls in the abnormal photovoltaic effect in BiFeO3. Nat. Commun. 4, 2835 (2013).
Wei, J. et al. Zero-bias mid-infrared graphene photodetectors with bulk photoresponse and calibration-free polarization detection. Nat. Commun. 11, 6404 (2020).
Freitag, M. et al. Photocurrent in graphene harnessed by tunable intrinsic plasmons. Nat. Commun. 4, 1951 (2013).
Park, J., Ahn, Y. H. & Ruiz-Vargas, C. Imaging of photocurrent generation and collection in single-layer graphene. Nano Lett. 9, 1742–1746 (2009).
Xia, F., Mueller, T., Lin, Y., Valdes-Garcia, A. & Avouris, P. Ultrafast graphene photodetector. Nat. Nanotechnol. 4, 839–843 (2009).
Gabor, N. M. et al. Hot carrier-assisted intrinsic photoresponse in graphene. Science 334, 648–652 (2011).
Woessner, A. et al. Near-field photocurrent nanoscopy on bare and encapsulated graphene. Nat. Commun. 7, 10783 (2016).
Alonso-González, P. et al. Controlling graphene plasmons with resonant metal antennas and spatial conductivity patterns. Science 344, 1369–1373 (2014).
Lundeberg, M. B. et al. Thermoelectric detection and imaging of propagating graphene plasmons. Nat. Mater. 16, 204–207 (2017).
Giovannetti, G. et al. Doping graphene with metal contacts. Phys. Rev. Lett. 101, 026803 (2008).
Zuev, Y. M., Chang, W. & Kim, P. Thermoelectric and magnetothermoelectric transport measurements of graphene. Phys. Rev. Lett. 102, 096807 (2009).
Yao, Y. et al. High-responsivity mid-infrared graphene detectors with antenna-enhanced photocarrier generation and collection. Nano Lett. 14, 3749–3754 (2014).
Wang, D. et al. Enhancing the graphene photocurrent using surface plasmons and a p-n junction. Light Sci. Appl. 9, 126 (2020).
Song, J. C. W. & Levitov, L. S. Shockley-Ramo theorem and long-range photocurrent response in gapless materials. Phys. Rev. B 90, 075415 (2014).
Latil, S. & Henrard, L. Charge carriers in few-layer graphene films. Phys. Rev. Lett. 97, 036803 (2006).
Liu, J., Xia, F., Xiao, D., García de Abajo, F. J. & Sun, D. Semimetals for high-performance photodetection. Nat. Mater. 19, 830–837 (2020).
Bandurin, D. A. et al. Negative local resistance caused by viscous electron backflow in graphene. Science 351, 1055–1058 (2016).
Bandurin, D. A. et al. Fluidity onset in graphene. Nat. Commun. 9, 4533 (2018).
Sturman, B. I. & Fridkin, V. M. Photovoltaic and Photo-refractive Effects in Noncentrosymmetric Materials Vol. 8 (CRC, 1992).
Mueller, T., Xia, F. & Avouris, P. Graphene photodetectors for high-speed optical communications. Nat. Photonics 4, 297–301 (2010).
Tomberg, T., Muraviev, A., Ru, Q. & Vodopyanov, K. L. Background-free broadband absorption spectroscopy based on interferometric suppression with a sign-inverted waveform. Optica 6, 147–151 (2019).
Zeng, L. et al. Van der Waals epitaxial growth of mosaic‐like 2D platinum ditelluride layers for room‐temperature mid‐infrared photodetection up to 10.6 µm. Adv. Mater. 32, 2004412 (2020).
Acknowledgements
We thank Y. Li, G. Hu and X. Le for helpful discussions. This research was supported by the National Research Foundation Singapore (Grant No. NRF-CRP15-2015-02). C.-W.Q. acknowledges financial support from the National Research Foundation, Prime Minister’s Office, Singapore under Competitive Research Program Award NRF-CRP22-2019-0006. C.-W.Q. is also supported by a grant (R-261-518-004-720) from Advanced Research and Technology Innovation Centre (ARTIC).
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J.W., C.-W.Q. and C.L. conceived the project. J.W. did the theoretical analysis, numerical simulation and sample fabrication. J.W. carried out the device characterization with assistance from C.X. and B.D. All authors discussed the results. J.W., C.-W.Q. and C.L. wrote the manuscript with comments from all authors. C.-W.Q. and C.L. supervised the project.
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Supplementary Notes 1–6, Figs. 1–27 and Tables 1–3.
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Wei, J., Xu, C., Dong, B. et al. Mid-infrared semimetal polarization detectors with configurable polarity transition. Nat. Photon. 15, 614–621 (2021). https://doi.org/10.1038/s41566-021-00819-6
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DOI: https://doi.org/10.1038/s41566-021-00819-6
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