Materials exhibiting long-lived, persistent luminescence in the visible spectrum are useful for applications in the display, information encryption and bioimaging sectors1,2,3,4. Herein, we report the development of several organic phosphors that provide colour-tunable, ultra-long organic phosphorescence (UOP). The emission colour can be tuned by varying the excitation wavelength, allowing dynamic colour tuning from the violet to the green part of the visible spectrum. Our experimental data reveal that these organic phosphors can have an ultra-long lifetime of 2.45 s and a maximum phosphorescence efficiency of 31.2%. Furthermore, we demonstrate the applications of colour-tunable UOP for use in a multicolour display and visual sensing of ultraviolet light in the range from 300 to 360 nm. The findings open the opportunity for the development of smart luminescent materials and sensors with dynamically controlled phosphorescence.
Subscribe to Journal
Get full journal access for 1 year
only $14.08 per issue
All prices are NET prices.
VAT will be added later in the checkout.
Rent or Buy article
Get time limited or full article access on ReadCube.
All prices are NET prices.
The data that support the plots within this paper and other findings of this study are available from the corresponding author upon reasonable request.
Pan, Z., Lu, Y. & Liu, F. Sunlight-activated long-persistent luminescence in the near-infrared from Cr3+-doped zinc gallogermanates. Nat. Mater. 11, 58–63 (2012).
Maldiney, T. et al. The in vivo activation of persistent nanophosphors for optical imaging of vascularization, tumours and grafted cells. Nat. Mater. 13, 418–426 (2014).
Xu, S., Chen, R., Zheng, C. & Huang, W. Excited state modulation for organic afterglow: materials and applications. Adv. Mater. 28, 9920–9940 (2016).
Su, Y. et al. Ultralong room temperature phosphorescence from amorphous organic materials toward confidential information encryption and decryption. Sci. Adv. 4, 9732–9743 (2018).
Lee, J. et al. Universal process-inert encoding architecture for polymer microparticles. Nat. Mater. 13, 524–529 (2014).
Lee, H., Kim, J., Kim, H., Kim, J. & Kwon, S. Colour-barcoded magnetic microparticles for multiplexed bioassays. Nat. Mater. 9, 745–749 (2010).
Deng, R. et al. Temporal full-colour tuning through non-steady-state upconversion. Nat. Nanotechnol. 10, 237–242 (2015).
Pan, L. et al. Truly fluorescent excitation-dependent carbon dots and their applications in multicolor cellular imaging and multidimensional sensing. Adv. Mater. 27, 7782–7787 (2015).
Farinola, G. M. & Ragni, R. Electroluminescent materials for white organic light emitting diodes. Chem. Soc. Rev. 40, 3467–3482 (2011).
Irie, M., Fukaminato, T., Matsuda, K. & Kobatake, E. Photochromism of diarylethene molecules and crystals: memories, switches, and actuators. Chem. Rev. 114, 12174–12277 (2014).
Mao, Z. et al. Linearly tunable emission colors obtained from a fluorescent–phosphorescent dual-emission compound by mechanical stimuli. Angew. Chem. Int. Ed. 54, 6270–6273 (2015).
Sun, Y. et al. Quantum-sized carbon dots for bright and colorful photoluminescence. J. Am. Chem. Soc. 128, 7756–7757 (2006).
Chen, O. et al. Excitation-intensity-dependent color-tunable dual emissions from manganese-doped CdS/ZnS core/shell nanocrystals. Angew. Chem. Int. Ed. 49, 10132–10135 (2010).
Lee, K. et al. Excitation-dependent visible fluorescence in decameric nanoparticles with monoacylglycerol cluster chromophores. Nat. Commun. 4, 1544–1551 (2013).
Xu, J. & Tanabe, S. Persistent luminescence instead of phosphorescence: History, mechanism, and perspective. J. Lumin. 205, 581–620 (2019).
Bolton, O., Lee, K., Kim, H., Lin, K. Y. & Kim, J. Activating efficient phosphorescence from purely organic materials by crystal design. Nat. Chem. 3, 205–210 (2011).
Zhang, G. et al. Multi-emissive difluoroboron dibenzoylmethane polylactide exhibiting intense fluorescence and oxygen-sensitive room-temperature phosphorescence. J. Am. Chem. Soc. 129, 8942–8943 (2007).
Yang, Z. et al. Intermolecular electronic coupling of organic units for efficient persistent room-temperature phosphorescence. Angew. Chem. Int. Ed. 55, 2181–2185 (2016).
He, Z. et al. White light emission from a single organic molecule with dual phosphorescence at room temperature. Nat. Commun. 8, 416 (2017).
Xie, Y. et al. How the molecular packing affects the room temperature phosphorescence in pure organic compounds: ingenious molecular design, detailed crystal analysis, and rational theoretical calculations. Adv. Mater. 29, 1606829–1606836 (2017).
Shoji, Y. et al. Unveiling a new aspect of simple arylboronic esters: long-lived room-temperature phosphorescence from heavy-atom-free molecules. J. Am. Chem. Soc. 139, 2728–2733 (2017).
Wei, J. et al. Induction of strong long-lived room-temperature phosphorescence of N-phenyl-2-naphthylamine molecules by confinement in a crystalline dibromobiphenyl matrix. Angew. Chem. Int. Ed. 55, 15589–15593 (2016).
Hirata, S. et al. Efficient persistent room temperature phosphorescence in organic amorphous materials under ambient conditions. Adv. Funct. Mater. 23, 3386–3397 (2013).
Yang, X. & Yan, D. Strongly enhanced long-lived persistent room temperature phosphorescence based on the formation of metal–organic hybrids. Adv. Opt. Mater. 4, 897–905 (2016).
An, Z. et al. Stabilizing triplet excited states for ultralong organic phosphorescence. Nat. Mater. 14, 685–690 (2015).
Lucenti, E. et al. Cyclic triimidazole derivatives: intriguing examples of multiple emissions and ultralong phosphorescence at room temperature. Angew. Chem. Int. Ed. 56, 16302–16307 (2017).
Ma, X., Xu, C., Wang, J. & Tian, H. Heavy-atom-free amorphous pure organic polymers with efficient room-temperature phosphorescence emission. Angew. Chem. Int. Ed. 130, 11020–11024 (2018).
Li, Q. et al. Induction of long-lived room temperature phosphorescence of carbon dots by water in hydrogen-bonded matrices. Nat. Commun. 9, 734 (2018).
Dou, X. et al. Clustering-triggered emission and persistent room temperature phosphorescence of sodium alginate. Biomacromolecules 19, 2014–2022 (2018).
Ogoshi, T. et al. Ultralong room-temperature phosphorescence from amorphous polymer poly(styrene sulfonic acid) in air in the dry solid state. Adv. Funct. Mater. 28, 1707369–1707376 (2018).
Tao, S. et al. Design of metal-free polymer carbon dots: a new class of room temperature phosphorescent materials. Angew. Chem. Int. Ed. 57, 2393–2398 (2018).
Kim, T. et al. Full-colour quantum dot displays fabricated by transfer printing. Nat. Photon. 5, 176–182 (2011).
Baryshnikov, G., Minaev, B. & Ågren, H. Theory and calculation of the phosphorescence phenomenon. Chem. Rev. 117, 6500–6537 (2017).
This work is supported by the National Natural Science Foundation of China (21875104, 51673095, 91833304, 91833302 and 61605074), National Basic Research Program of China (973 Program, No. 2015CB932200), Natural Science Fund for Distinguished Young Scholars of Jiangsu Province (BK20180037), the Natural Science Fund for Colleges and Universities (17KJB430020) of Jiangsu Province, and Nanjing Tech Start-up Grant (3983500158 and 3983500169). We are grateful to the High Performance Computing Center of Nanjing Tech University for technical support.
The authors declare no competing interests.
Publisher’s note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
About this article
Cite this article
Gu, L., Shi, H., Bian, L. et al. Colour-tunable ultra-long organic phosphorescence of a single-component molecular crystal. Nat. Photonics 13, 406–411 (2019). https://doi.org/10.1038/s41566-019-0408-4
Angewandte Chemie (2020)
Highly Regioselective Direct C-H Arylation: Facile Construction of Symmetrical Dithienophthalimide-Based π-Conjugated Molecules for Optoelectronics
Angewandte Chemie (2020)