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Random interstratification in hydrated graphene oxide membranes and implications for seawater desalination

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The Original Article was published on 03 April 2017

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  1. Abraham, J. et al. Tunable sieving of ions using graphene oxide membranes. Nat. Nanotechnol. 12, 546–550 (2017).

    Article  CAS  Google Scholar 

  2. Bober, E. S. et al. Final Report on Reverse Osmosis Membranes Containing Graphitic Oxide Research and Development Progress Report no. 544 (US Department of the Interior, 1970).

  3. Boehm, H. P., Clauss, A. & Hofmann, U. Graphite oxide and its membrane properties. J. Chim. Phys. 58, 141–147 (1961).

    Article  CAS  Google Scholar 

  4. Nair, R. R., Wu, H. A., Jayaram, P. N., Grigorieva, I. V. & Geim, A. K. Unimpeded permeation of water through helium-leak-tight graphene-based membranes. Science 335, 442–444 (2012).

    Article  CAS  Google Scholar 

  5. Joshi, R. K. et al. Precise and ultrafast molecular sieving through graphene oxide membranes. Science 343, 752–754 (2014).

    Article  CAS  Google Scholar 

  6. Hofmann, U. & Frenzel, A. Quellung von Graphit und die Bildung der Graphitsaure. Ber. Dtsch. Chem. Ges. 63, 1248–1262 (1930).

    Article  Google Scholar 

  7. Lerf, A. et al. Hydration behavior and dynamics of water molecules in graphite oxide. J. Phys. Chem. Solids 67, 1106–1110 (2006).

    Article  CAS  Google Scholar 

  8. Barroso-Bujans, F. et al. Permanent adsorption of organic solvents in graphite oxide and its effect on the thermal exfoliation. Carbon 48, 1079–1087 (2010).

    Article  CAS  Google Scholar 

  9. Ban, S. et al. Insight into the nanoscale mechanism of rapid H2O transport within a graphene oxide membrane: impact of oxygen functional group clustering. ACS Appl. Mater. Interfaces 8, 321–332 (2016).

    Article  CAS  Google Scholar 

  10. Solin, S. A. Clays and clay intercalation compounds: properties and physical phenomena. Annu. Rev. Mater. Sci. 27, 89–115 (1997).

    Article  CAS  Google Scholar 

  11. Rezania, B., Severin, N., Talyzin, A. V. & Rabe, J. P. Hydration of bilayered graphene oxide. Nano Lett. 14, 3993–3998 (2014).

    Article  CAS  Google Scholar 

  12. Bourlinos, A. B. et al. Graphite oxide: chemical reduction to graphite and surface modification with primary aliphatic amines and amino acids. Langmuir 19, 6050–6055 (2003).

    Article  CAS  Google Scholar 

  13. Klechikov, A., Yu, J. C., Thomas, D., Sharifi, T. & Talyzin, A. V. Structure of graphene oxide membranes in solvents and solutions. Nanoscale 7, 15374–15384 (2015).

    Article  CAS  Google Scholar 

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Correspondence to Alexandr V. Talyzin.

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Talyzin, A.V. Random interstratification in hydrated graphene oxide membranes and implications for seawater desalination. Nat. Nanotechnol. 17, 131–133 (2022).

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