Amongst the more than 18 different forms of water ice, only the common hexagonal phase and the cubic phase are present in nature on Earth. Nonetheless, it is now widely recognized that all samples of ‘cubic ice’ discovered so far do not have a fully cubic crystal structure but instead are stacking-disordered forms of ice I (namely, ice Isd), which contain both hexagonal and cubic stacking sequences of hydrogen-bonded water molecules. Here, we describe a method to obtain large quantities of cubic ice Ic with high structural purity. Cubic ice Ic is formed by heating a powder of D2O ice XVII obtained from annealing of pristine C0 hydrate samples under dynamic vacuum. Neutron diffraction experiments performed on two different instruments and Raman spectroscopy measurements confirm the structural purity of the cubic ice, Ic. These findings contribute to a better understanding of ice I polymorphism and the existence of the two natural ice forms.
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Neutron beam time at ISIS and ILL is gratefully acknowledged, on the basis of the agreement of the CNR (Italy) with STFC (UK) and ILL (France) concerning collaboration in scientific research. L.U. and M.Celli acknowledge the PRIN project ZAPPING, no. 2015HK93L7, granted by the Italian Ministero dell’Istruzione, dell’Università e della Ricerca supporting their research in high-pressure materials science. L.U., M.Celli and L.d.R. acknowledge support from the Fondazione Cassa di Risparmio di Firenze under the contract ICEXVII. ISIS Pressure and Furnaces section and the Electronics section were vital for setting up with gas-handling system and in-situ sample heating for the HRPD experiment. Technical support by A. Donati (IFAC-CNR) for setting up of the high-pressure autoclave for the synthesis of the samples is gratefully acknowledged.
The authors declare no competing interests.
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del Rosso, L., Celli, M., Grazzi, F. et al. Cubic ice Ic without stacking defects obtained from ice XVII. Nat. Mater. 19, 663–668 (2020). https://doi.org/10.1038/s41563-020-0606-y
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