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Entropy in halide perovskites

Claudine Katan, Aditya D. Mohite and Jacky Even discuss the possible impact of various entropy contributions (stochastic structural fluctuations, anharmonicity and lattice softness) on the optoelectronic properties of halide perovskite materials and devices.

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Fig. 1: Sources of dynamic disorder in halide perovskites.

References

  1. Even, J., Carignano, M. & Katan, C. Nanoscale 8, 6222–6236 (2016).

    Article  CAS  Google Scholar 

  2. Patrick, C. E., Jacobsen, K. W. & Thygesen, K. S. Phys. Rev. B 92, 201205 (2015).

    Article  Google Scholar 

  3. Marronnier, A. et al. J. Phys. Chem. Lett. 8, 2659–2665 (2017).

    Article  CAS  Google Scholar 

  4. Fabini, D. H. et al. J. Phys. Chem. Lett. 7, 376–381 (2016).

    Article  CAS  Google Scholar 

  5. Lynden-Bell, R. M. & Michel, K. H. Rev. Mod. Phys. 66, 721–762 (1994).

    Article  CAS  Google Scholar 

  6. Bussmann-Holder, A., Büttner, H. & Bishop, A. R. Phys. Rev. Lett. 99, 167603 (2007).

    Article  CAS  Google Scholar 

  7. Boardman, A. D. Proc. Phys. Soc. 85, 141–148 (1965).

    Article  CAS  Google Scholar 

  8. Senanayak, S. P. et al. Sci. Adv. 3, e1601935 (2017).

    Article  Google Scholar 

  9. Létoublon, A. et al. J. Phys. Chem. Lett. 7, 3776–3784 (2016).

    Article  Google Scholar 

  10. Giustino, F. Rev. Mod. Phys. 89, 015003 (2017).

    Article  Google Scholar 

  11. Yang, J. et al. Nat. Commun. 8, 14120 (2017).

    Article  CAS  Google Scholar 

  12. Neukirch, A. J. et al. Nano Lett. 16, 3809–3816 (2016).

    Article  CAS  Google Scholar 

  13. Wu, X. et al. Sci. Adv. 3, e1602388 (2017).

    Article  Google Scholar 

  14. Ghosh, T., Aharon, S., Etgar, L. & Ruhman, S. J. Am. Chem. Soc. 139, 18262–18270 (2017).

    Article  CAS  Google Scholar 

  15. Taylor, V. C. A. et al. J. Phys. Chem. Lett. 9, 895–901 (2018).

    Article  CAS  Google Scholar 

Download references

Acknowledgements

In memory of G. C. Papavassiliou. The work at Los Alamos National Laboratory (LANL) was supported by the LDRD programme (A.D.M.). Part of the work was conducted at the Center for Integrated Nanotechnologies (CINT), a US Department of Energy Office of Science user facility. The work in France was supported by Agence Nationale pour la Recherche (TRANSHYPERO project). ADM acknowledges the DOE_EERE-0001647-1544 programme for funding for this work.

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Katan, C., Mohite, A.D. & Even, J. Entropy in halide perovskites. Nature Mater 17, 377–379 (2018). https://doi.org/10.1038/s41563-018-0070-0

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