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Lithium titanium disulfide cathodes

It is now almost 50 years since the first rechargeable lithium batteries, based on the reversible intercalation of lithium into layered structured titanium disulfide, were conceived. They were the precursor to the structurally related layered oxides that now dominate energy storage for electronics, the grid and vehicles.

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References

  1. 1.

    Gamble, F. R. et al. Science 174, 493–497 (1971).

    Article  Google Scholar 

  2. 2.

    Whittingham, M. S. Prog. Solid State Chem. 12, 41–99 (1978).

    Article  Google Scholar 

  3. 3.

    Thompson, A. H. Phys. Rev. Lett. 35, 1786–1789 (1975).

    Article  Google Scholar 

  4. 4.

    Dines, M. B. Method for lithiating metal chalcogenides and intercalated products thereof. US patent 3,933,688 (1974).

  5. 5.

    Whittingham, M. S. Chalcogenide battery. US patent 4,009,052 (1973).

  6. 6.

    Whittingham, M. S. Chalcogenide battery. UK patent 1,468,416 (1973).

  7. 7.

    Whittingham, M. S. Science 192, 1126–1127 (1976).

    Article  Google Scholar 

  8. 8.

    Rao, B. M. L., Francis, R. W. & Christopher, H. A. J. Electrochem. Soc. 124, 1490–1492 (1977).

    Article  Google Scholar 

  9. 9.

    Thorp, A. J., Clamp, F., Feld, R., Page-Gibson, J. E. & Archer, K. Process for the production of titanium disulfide. US patent 4,137,297 (1977).

  10. 10.

    Panster, P., Mueller, R. & Kleinschmit, P. Preparing titanium disulfide for use in batteries. US patent 4,772,457 (1986).

  11. 11.

    Chianelli, R. R., Scanlon, J. C. & Rao, B. M. L. J. Electrochem. Soc. 125, 1563–1566 (1978).

    Article  Google Scholar 

  12. 12.

    Thompson, A. H. Phys. Rev. Lett. 40, 1511–1514 (1978).

    Article  Google Scholar 

  13. 13.

    Whittingham, M. S. Mater. Res. Bull. 13, 959–965 (1978).

    Article  Google Scholar 

Download references

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Correspondence to M. Stanley Whittingham.

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Whittingham, M.S. Lithium titanium disulfide cathodes. Nat Energy 6, 214 (2021). https://doi.org/10.1038/s41560-020-00765-7

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