Article

Exceptional power density and stability at intermediate temperatures in protonic ceramic fuel cells

  • Nature Energyvolume 3pages202210 (2018)
  • doi:10.1038/s41560-017-0085-9
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Abstract

Over the past several years, important strides have been made in demonstrating protonic ceramic fuel cells (PCFCs). Such fuel cells offer the potential of environmentally sustainable and cost-effective electric power generation. However, their power outputs have lagged behind predictions based on their high electrolyte conductivities. Here we overcome PCFC performance and stability challenges by employing a high-activity cathode, PrBa0.5Sr0.5Co1.5Fe0.5O5+δ (PBSCF), in combination with a chemically stable electrolyte, BaZr0.4Ce0.4Y0.1Yb0.1O3 (BZCYYb4411). We deposit a thin dense interlayer film of the cathode material onto the electrolyte surface to mitigate contact resistance, an approach which is made possible by the proton permeability of PBSCF. The peak power densities of the resulting fuel cells exceed 500 mW cm−2 at 500 °C, while also offering exceptional, long-term stability under CO2.

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Acknowledgements

This research was funded in part by the US Department of Energy, through ARPA-e Contract DE-AR0000498, via subcontract from United Technologies Research Center, and by the National Science Foundation, DMR-1505103. Selected facilities used were supported by the National Science Foundation via Northwestern University’s MRSEC, DMR-1121262.

Author information

Affiliations

  1. Materials Science and Engineering, Northwestern University, Evanston, IL, USA

    • Sihyuk Choi
    • , Chris J. Kucharczyk
    • , Ho-Il Ji
    •  & Sossina M. Haile
  2. Applied Physics & Materials Science, California Institute of Technology, Pasadena, CA, USA

    • Chris J. Kucharczyk
    •  & Ho-Il Ji
  3. Materials Science and Engineering, University of Maryland, College Park, MD, USA

    • Yangang Liang
    • , Xiaohang Zhang
    •  & Ichiro Takeuchi

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Contributions

S.M.H led the development of the concept, guided the experimental design, and supervised the research. S.C. developed the materials, fabricated the cells, and performed the following experiments and analyses: conductivity, thermogravimetry, fuel cell polarization, and impedance spectroscopy. Y.L. and X.Z. prepared and characterized PLD microdot electrodes, on which C.J.K. performed electrochemical measurements. I.T. supervised PLD film growth and characterization. H.-I. J. provided critical suggestions for experimental and analytical methods. S.M.H. and S.C. wrote the paper with contributions from all authors.

Corresponding author

Correspondence to Sossina M. Haile.

Supplementary information

  1. Supplementary Information

    Supplementary Figures 1–15, Supplementary Table 1 and Supplementary References