Ether-based electrolytes are desired for lithium metal batteries owing to their low reduction potentials; however, they suffer from low anodic stability. Strategic methylation of ether solvents is shown to extend their electrochemical stability and facilitate the formation of LiF-rich interphases, enabling high-voltage lithium metal batteries while avoiding the use of fluorinated solvents.
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This is a summary of: Li, A.-M. et al. Methylation enables the use of fluorine-free ether electrolytes in high-voltage lithium metal batteries. Nat. Chem. https://doi.org/10.1038/s41557-024-01497-x (2024).
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Methylation enables high-voltage ether electrolytes for lithium metal batteries. Nat. Chem. 16, 852–853 (2024). https://doi.org/10.1038/s41557-024-01498-w
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DOI: https://doi.org/10.1038/s41557-024-01498-w
