Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • News & Views
  • Published:

NUCLEATION

What atoms do when they get together

How atoms organize during the earliest stages of nucleation has been a subject of speculation for over a century. Using atomically resolved electron microscopy, the formation and ordering of metal clusters from individual atoms has now been observed in carbon nanotubes that serve as ‘test tubes’.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Fig. 1: Two-step nucleation due to inversion in the stability of phases with particle size N.

References

  1. Gibbs, J. W. The collected works of J. Willard Gibbs (Yale Univ. Press, 1948).

  2. De Yoreo, J. J. et al. Science 349, aaa6760 (2015).

    Article  Google Scholar 

  3. Vekilov, P. G. Nanoscale 2, 2346–2357 (2010).

    Article  CAS  Google Scholar 

  4. Gebauer, D., Volkel, A. & Colfen, H. Science 322, 1819–1822 (2008).

    Article  CAS  Google Scholar 

  5. Cao, K. et. al Nat. Chem. https://doi.org/10.1038/s41557-020-0538-9 (2020).

  6. Ostwald, W. Z. Phys. Chem. 22, 289 (1897).

    CAS  Google Scholar 

  7. Stranski, I. N. & Totomanow, D. Z. Phys. Chem. 163A, 399–408 (1933).

    Article  Google Scholar 

  8. tenWolde, P. R. & Frenkel, D. Science 277, 1975–1978 (1997).

    Article  CAS  Google Scholar 

  9. Ranade, M. R. et al. Proc. Natl Acad. Sci. USA 99, 6476–6481 (2002).

    Article  CAS  Google Scholar 

  10. Navrotsky, A. Proc. Natl Acad. Sci. USA 101, 12096–12101 (2004).

    Article  CAS  Google Scholar 

  11. Burton, W. K., Cabrera, N. & Frank, F. C. Philos. Trans. R. Soc. A 243, 299–358 (1951).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to J. J. De Yoreo.

Ethics declarations

Competing interests

The authors declare no competing interests.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

De Yoreo, J.J., Legg, B.A. What atoms do when they get together. Nat. Chem. 12, 883–885 (2020). https://doi.org/10.1038/s41557-020-0523-3

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/s41557-020-0523-3

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing