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Crumple zones in MOFs

The applicability of metal-organic frameworks (MOFs) — in spite of their obvious potential — is hindered by stability issues, in particular towards water. Now, a ‘crumple zone’ concept has been proposed in which the presence of sacrificial bonds protects a MOF without significantly altering its structure or functionality.

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  1. 1.

    Furukawa, H., Cordova, K. E., O’Keeffe, M. & Yaghi, O. M. Science 341, 1230444 (2013).

  2. 2.

    Morris, R. E. & Brammer, L. Chem. Soc. Rev. 46, 5444–5462 (2017).

  3. 3.

    Li, N., Xu, J., Feng, R., Hu, T.-L. & Bu, X.-H. Chem. Commun. 52, 8501–8513 (2016).

  4. 4.

    Burtch, N. C., Jasuja, H. & Walton, K. S. Chem. Rev. 114, 10575–10612 (2014).

  5. 5.

    Canivet, J., Fateeva, A., Guo, Y., Coasne, B. & Farrusseng, D. Chem. Soc. Rev. 43, 5594–5617 (2014).

  6. 6.

    McHugh, L. N. et al. Nat. Chem.. (2018).

  7. 7.

    de Lange, M. F., Verouden, K. J. F. M., Vlugt, T. J. H., Gascon, J. & Kapteijn, F. Chem. Rev. 115, 12205–12250 (2015).

  8. 8.

    Wittmann, T. et al. Chem. Eur. J. 21, 314–323 (2015).

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Correspondence to Jürgen Senker.

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Fig. 1: Schematic representation of the ‘crumple zone’ mechanism.