Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • News & Views
  • Published:

COORDINATION CHEMISTRY

Crumple zones in MOFs

The applicability of metal-organic frameworks (MOFs) — in spite of their obvious potential — is hindered by stability issues, in particular towards water. Now, a ‘crumple zone’ concept has been proposed in which the presence of sacrificial bonds protects a MOF without significantly altering its structure or functionality.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Fig. 1: Schematic representation of the ‘crumple zone’ mechanism.

References

  1. Furukawa, H., Cordova, K. E., O’Keeffe, M. & Yaghi, O. M. Science 341, 1230444 (2013).

    Article  Google Scholar 

  2. Morris, R. E. & Brammer, L. Chem. Soc. Rev. 46, 5444–5462 (2017).

    Article  CAS  Google Scholar 

  3. Li, N., Xu, J., Feng, R., Hu, T.-L. & Bu, X.-H. Chem. Commun. 52, 8501–8513 (2016).

    Article  CAS  Google Scholar 

  4. Burtch, N. C., Jasuja, H. & Walton, K. S. Chem. Rev. 114, 10575–10612 (2014).

    Article  CAS  Google Scholar 

  5. Canivet, J., Fateeva, A., Guo, Y., Coasne, B. & Farrusseng, D. Chem. Soc. Rev. 43, 5594–5617 (2014).

    Article  CAS  Google Scholar 

  6. McHugh, L. N. et al. Nat. Chem.. https://doi.org/10.1038/s41557-018-0104-x (2018).

    Article  PubMed  Google Scholar 

  7. de Lange, M. F., Verouden, K. J. F. M., Vlugt, T. J. H., Gascon, J. & Kapteijn, F. Chem. Rev. 115, 12205–12250 (2015).

    Article  Google Scholar 

  8. Wittmann, T. et al. Chem. Eur. J. 21, 314–323 (2015).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jürgen Senker.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Senker, J. Crumple zones in MOFs. Nature Chem 10, 1079–1081 (2018). https://doi.org/10.1038/s41557-018-0161-1

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/s41557-018-0161-1

This article is cited by

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing