Materials with strong spin-textured bands

The materials that exhibit strong spin-textured bands are rapidly attracting more and more attention in past few years. In this new class of quantum materials, the band structures are strongly influenced by spin/magnetization direction, affording new twist to control topological behaviors, quantum anomalous Hall effect, transport, and optical properties by rotating the spin/magnetization. The control of spin direction in spin-textured band materials can be considered as a fundamentally new route toward desired properties compared with conventional spin ordering control. In this article, we will review the research progress on spin-textured band materials from both theoretical and experimental aspects, providing the critical ingredient of this new type of materials, united theory, challenging, and perspective for future research.


INTRODUCTION
Spin is the cornerstone of condensed matter physics. The arrangement and orientation of the spins in a material not only directly determine the magnetic properties, but also strongly affect other physical properties, such as the transport, optical, and thermal properties [1][2][3][4][5][6][7] . The magnet, which has enormous application in modern electronics, arises from long-range ferromagnetic ordering structure in which spins spontaneously align parallel to each other. On the contrary, the spontaneously antiparallel alignment of spin leads to anti-ferromagnetism. In between parallel or antiparallel alignment, there are non-collinear spin structures, such as canted or twisting spin structures. The magnetic skyrmion is one of the typical twisting spin textures 5 . Magnetic ordering can also have profound impact on macroscopic properties. For example, the antiferromagnetic (AFM) ordering that can induce a folding of the Brillouin zone and then open a bandgap triggers a Slater-type metal-to-insulator transition 8 . In correlated manganites, the metallic phase is coupled to longrange ferromagnetic ordering and magnetic phase transition from ferromagnetism to para/antiferro-magnetism will trigger a metalto-insulator transition 2 .
The spin orientation, which is another important nature of spin and is usually emphasized by anisotropic response of a material to external magnetic field, is also vital for many physical phenomena. The orientation of the spin in a magnet can be stabilized to a specific direction owing to magnetic anisotropy 9 . Rotating the magnetization direction leads to many novel magnetophenomena ( Fig. 1), such as spin-orbit interaction driven anisotropic magnetoresistance (AMR) 10 , giant magnetoresistance in ferromagnet/nonmagnet/ferromagnet sandwiched structure 6 , anomalous Hall effect 11 , magneto-optic Kerr effect 12,13 , and magnetostriction 14,15 , etc. The functionality of compass roots in magnetic anisotropy energy which stabilizes spin along a specific crystal axis, and thus this axis, which is defined as magnetic easy axis, mechanically aligns along the magnetic field of the earth. Either AMR in a material or giant magnetoresistance in a sandwiched device, the spin-dependent scattering rules the underlying physics 6,10 . However, no matter the magnetic anisotropy energy 9 , spin-dependent scattering 6,10 , or spin-dependent light matter interaction 12,13 , a change of the spin direction does not fundamentally alters a material's electronic phase, in strong contrast to spin ordering driven electronic phase transition in many correlated materials. The proposed quantum compass material, in which exchange coupling between spins is spatially dependent on the spin direction, though can generate many spinorientation-dependent novel electronic phase, is still a matter of theory 16 .
The giant spin-textured band materials, which have been predicted by theory and experimentally demonstrated in past several years [17][18][19][20] , make the spin orientation in the spotlight of condensed matter physics. In this new class of quantum materials, rotating the spin direction significantly varies the band structure by an energy scale of one order of magnitude larger than traditional Zeeman splitting, and consequently induces a large variation of physical properties and gives rise to many unprecedented phenomena (Fig. 1, left). Typical examples include the theoretically predicted spin orientation controlled direct-toindirect bandgap transition in CrI 3 17 , quantum anomalous Hall with in-plane magnetization in LaCl 21 , topological phase transitions in AFM van der Waals material MnBi 2 Te 4 22 , and switchable Weyl nodes in Kagome ferromagnetic Fe 3 Sn 2 23 . More excitingly, several experiments already demonstrated the effect of strong dependence of band structures on the magnetization directions in a couple of materials, e.g., magnetization vector governed symmetry of Fermi surface in Fe 3 Sn 2 probed by scanning tunneling microscopy (STM) and spectroscopy (STS) 18 . This new type of quantum materials affords many advantages for application in electronic devices and can be a realistic system in parallel to quantum compass materials 17 . Compared with the control of spin ordering, the direction of the spin can be readily manipulated by external magnetic field, rendering the spin-textured band materials applicable for spintronics 17,20 . The giant response of physical properties to magnetic field further makes it a promising sensor to map magnetic field vector.
Many novel physical phenomena together with promising applications in next-generation electronics are bringing more and more intense focus on spin-textured band materials. Theoretically, spin-vector-dependent spin-orbit coupling (SOC), which changes the electron Bloch wave is one central ingredient to induce spintextured band 17,[23][24][25][26] . In this review, we summarize recent progress in this rapid developing new field in order to provide the critical ingredients of this new type of materials, united theory, challenging and perspective for future research. We will start in Sec II by introducing the theory on spin-textured band materials where the central role of SOC and symmetry breaking is addressed. Next in Sec III, we discuss the experimental reports on spin-textured materials and their connection to theory prediction. Finally in Sec IV, a summary and perspective are given.

THEORY OF SPIN-TEXTURED BAND MATERIALS
Toy models In correlated materials, spin, charge, and orbital are all active degrees of freedom and their delicate coupling is essential for the diverse electronic phases. Among these internal degrees of freedoms, spin (S) and orbital (L) are vector components, thereby serving as indispensable components for developing compass materials where the vector of a component can significantly influence the band structures and properties. The orbital that can be controlled through lattice distortion has been demonstrated in the past in many correlated materials to effectively change the electronic properties 27 . Unfortunately, dynamic lattice control is hardly accessible, hindering practical device application. The spin, which though is easily manipulated by either magnetic field through Zeeman effect or electric field through magnetoelectric coupling 28,29 , has global SU(2) symmetry and in many circumstance has isotropic coupling. This peculiarity stands in the way of developing spin vector governed electronic phases.
In a situation where SOC is very strong, however, the spin is intensely entangled with orbital degree of freedom. As a result, the spin is no longer a good quantum number and is not dictated by SU(2) symmetry, making a material with strong SOC drastically differs from other systems with negligible SOC and exhibit many novel phenomena 30 , such as topological surface states, photogalvanic effect, chiral domain wall, and spin-charge conversion. Another important ingredient to strength the role of spin direction is to reduce the lattice symmetry, which can maximize the SOC anisotropy. Last but not least, magnetically coupled spins are essential to provide collective behavior from spin degree of freedom and to produce distinct effect on band structures. With these three ingredients, a toy model based on a two-dimensional ferromagnetic material is introduced to illustrate the influence of spin orientation on band structure. The Hamiltonian is described by Here, H 0 k ð Þ is the paramagnetic tight-binding Hamiltonian with matrix elements H αβ ¼ P R t αβ ðRÞe iKÁR . The term t αβ R ð Þ represents a hopping integral from orbital α to orbital β with lattice spacing R, and K is the wave vector. The second term λ 2 À Á σ θ; φ ð Þ describes an exchange splitting λ with magnetization oriented along a specific direction θ; φ ð Þ, and σ θ; φ ð Þis the vector of Pauli matrices. The last term is the SOC and the coefficient ξ is the coupling strength. For simplicity, only p orbitals (p x , p y , and p z ) are considered here, but it is worth to note that this toy model can be also used for more complex orbital configuration.
For a 2D ferromagnetic material, it is natural to define the outof-plane direction as the z direction and in-plane as (x, y). The ferromagnetic exchange interaction shifts the spin down channel to higher energy, unoccupied states. Meanwhile, the p z" i orbital (where " indicates spin up) is split off by 2D confinement effect. Therefore, we mainly focus on p x" i and p y" i orbitals, which form bands near the Fermi energy. We first consider a situation where the spin is oriented along the out-of-plane direction (M//c). In this case, one has p x" L Á S p y" i ¼ Ài. As a result, the Hamiltonian has some non-zero off-diagonal mixing terms and the bands at Γ become non-degenerate. A splitting energy ΔE of ∼200 meV is found at the Γ point when ξ = 100 meV is used for calculation (see Fig. 2a). This energy splitting is indeed induced by SOC, as the splitting disappears if the SOC is not included (e.g., ξ = 0). In contrast to the situation of M//c, the off-diagonal term p x! h jL Á S p y! i becomes zero (! denotes spin up channel along in-plane direction) for M//a. Accordingly, the former splitting is removed and bands at Γ are degenerate as shown in Fig. 2b. As the SOC term L Á S continuously changes with rotating the spin from outof-plane toward in-plane, the SOC-induced gap ΔE gradually decreases with increasing angle of the spin relative to out-of-plane The toy model suggests three criteria for discovering spintextured band materials: (i) strong SOC to induce non-equivalent electronic behavior for different spin orientations; (ii) a low crystal symmetry that has large crystalline anisotropy to maximize SOC anisotropy; (iii) magnetically coupled electrons to obtain the collective behavior. To illustrate the role of symmetry, the model is extended to a non-layered 3D cubic system where the structure is isotropic. It is found that the change of the band structure at Γ in the 3D case is not observed because of equivalent spin orientations resulting from the high symmetry. These criteria suggest that the most promising candidates are ferromagnetic materials with strong SOC and high crystalline anisotropy. In light of these criteria, a series of promising spin-textured band materials have been predicted in recent 2 years, such as CrI 3 17 , Fe 3 Sn 2 18,23 , Fe 3 GeTe 2 19 , LaCl 21 , CoGa 2 X 4 (X = S, Se, or Te) 26 , Sr 2 IrO 4 32 , Co 3 Sn 2 S 2 25 , MnBi 2 Te 4 22 , NiTl 2 S 4 33 , C 4 CrX 3 (X = Ge and Si) 34 , and (Bi, Sb) 2 Te 3 /Cr x (Bi,Sb) 2-x Te 3 heterostructure 35 .
Spin direction controlled spin-orbit gap As indicated in the toy model, the spin direction controlled energy splitting in spin-textured band materials should be intimately correlated to SOC. Such an energy splitting could lead to the opening or tuning of the bandgap, i.e., spin-orbit gap. A large spin-orbit gap likely occurs in a material with strong SOC. Several materials with large spin-orbit gap have been predicted previously, and one paradigm is the 2D ferromagnetic CrI 3 17 , in which the heavy I element hosts strong SOC and Cr hosts the magnetic coupling. Theoretical calculation suggests that rotating the spin direction of CrI 3 can significantly modify electronic band structures as shown in Fig. 3. In the case of M//c, the splitting energies between the two highest valence bands and the two lowest conduction bands at Γ are 174.50 and 64.42 meV, respectively. When the spin lies in-plane, i.e., M//a, however, such energy splitting vanishes. As a consequence, the bandgap is tuned from 0.91 eV to 0.96 eV. More importantly, the magnetic moment switching causes a direct-to-indirect bandgap transition.
Another example of spin-orbit gap is found in the 2D ternary chalcogenides, i.e., the CoGa 2 X 4 (X = S, Se, or Te) family 26 . Density functional theory calculations demonstrate that easy plane magnetization is favored in CoGa 2 X 4 . However, the magnetic anisotropic energy between in-plane (easy axis) and out-of-plane (hard axis) magnetization is much smaller than 1 meV, e.g., 0.047 meV for CoGa 2 S 4 . Therefore, magnetization or spin direction can be easily tuned by an external magnetic field. When tuning the magnetization from in-plane to out-of-plane direction, an energy splitting of 32 meV at K point occurs and thus opens a bandgap. As the magnetization direction can be also tuned by applying a tensile strain, the strain is found to affect the spin-orbit gap as well in these ternary chalcogenides.
Topological phase transition In magnetic materials, the spin direction has a significant influence on the symmetry of a crystal, and the magnetic symmetry or group is quite complex to address. Here we introduce a simple example in 2D magnetic crystals. In these crystals, the plane symmetry is conserved under out-of-plane spin direction, but is broken for the cases of in-plane spin directions. The change of symmetry can cause large change of electronic band structure at specific k point, e.g., the opening of bandgap at band crossings, and then might result in topological phase transition.
Topological phase transition triggered by change of spin direction has been predicted in 2D ferromagnetic CrI 3 17 . As indicated by blue circles in Fig. 3, the second and third conduction bands of CrI 3 monolayer cross each other without opening a gap along the K-Γ direction for M//c. Whereas, the bands cross is broken and a gap is opened when rotating the spin direction to in-plane (M//a). Consequently, the topological character of CrI 3 monolayer transforms from Dirac semimetal to Chern topological insulator. Similar behavior was also predicted in 2D LaCl 21 . The 2D  LaCl has hexagonal lattice which has three mirror planes. As the magnetization is tuned to different in-plane directions, the mirror symmetry is preserved if the magnetization direction is perpendicular to the mirror plane. Otherwise, the mirror symmetry will be broken. The variation of mirror symmetry under different magnetization directions leads to periodical change of the Chern number in LaCl as shown in Fig. 4a-f. Angle-dependent quantized Hall conductivity with 120°symmetry was also theoretically calculated as shown in Fig. 4h, which could be experimentally confirmed by measuring the Hall at different in-plane magnetization angles as shown in Fig. 4g.
For a newly discovered AFM topological insulator MnBi 2 Te 4 22,36-41 , its van der Waals nature and interlayer AFM coupling suggest that the magnetic order and orientation can be variously changed, e.g., ferromagnetic or AFM order with different spin orientations, by applying magnetic field. Under such a change, the symmetry, orbital hybridization, and band structures can be highly controlled, which leading to various topological phase transitions, such as AFM mirror topological crystalline insulators and type-I topological Weyl semimetals 22 .
Furthermore, rotating the magnetization direction has been found to be able to create and control Weyl nodes in several materials, such as Fe 3 Sn 2 23 , Co 3 Sn 2 S 2 25 , and C 4 CrX 3 (X = Ge and Si) 34 . Taking the Kagome ferromagnet Fe 3 Sn 2 as an example, as its symmetry can be controlled by magnetization direction, the Fe 3 Sn 2 exhibits different symmetry operation under different magnetization directions 23 . In detail, the system is protected by space inversion symmetry P, C 2y , and the mirror operation M y for M//y, by space inversion symmetry P for M//x, and by P-symmetry, C 3z , and C 3z for M//z. As shown in Fig. 5, the resulted difference in symmetry gives rise to eight pairs, ten pairs, and six pairs Weyl nodes at different points for M//y, M//x, M//z, respectively.

EXPERIMENTS ON SPIN-TEXTURED BAND MATERIALS
As many physical properties are strongly determined by the band structures, manipulation of the band structures by spin rotation is expected to significantly change the physical properties, leading to many novel magneto-phenomena. Taking the CrI 3 as an example, the direct-to-indirect bandgap transition triggered by spin rotated from out-of-plane to in-plane will lead to markedly suppressed photoluminescence 17 . AMR is another important effect in spin-textured band materials, because of that transport property highly depends on the band structure. In the situation that spin-orbit gap is opened at Fermi level, a remarkable spindirection-driven metal-to-insulator transition can occur, which is worth to be revealed and investigated further in future. The spin reorientation induced topological phase transition and quantum anomalous Hall are another tantalizing phenomena to be revealed experimentally. As these phenomena are sensitive to local band change and do not require large change of the whole band, local modification of the band topologies then can cause huge effect on properties. Ballistic AMR The first and intuitive glance of incarnation of spin-textured band effect is the AMR. As the magnetic field will induce a Zeeman energy and thus force the spin to align along field direction, a vector field therefore can rotate the spin and change the band structure. Accordingly, the conductivity varies with field direction, leading to AMR. This novel AMR that is owing to the change of Fermi surface is fundamentally different from conventional ARM owing to spin-direction-dependent scattering 10 . The AMR owing to spin-textured band effect was early reported in ballistic anisotropic magnetoresistance (BAMR). With respect to ballistic transport in a ferromagnetic material, the sample dimension is smaller than the mean free path of electrons and the electron conductivity is quantized to G ¼ Ne 2 =h 42 , where N is the number of electron sub-bands that cross the Fermi level and h is the Planck constant. Change of N owing to band structure reconstruction with different magnetization direction is expected to generate quantized magnetoresistance (ΔNe 2 =h). Early experiment in 2002 on Ni ballistic nanocontacts revealed the change of conductance from magnetization parallel to current (m//I) configuration to m⊥I configuration 43 . Later in 2004, Yang et al. 44 found the conductance change ΔG is of the order of e 2 =h. Since spin-direction-dependent scattering is not applicable in the situation of ballistic transport any more, the BAMR was theoretically suggested to arise from effect of spin-orbit interaction on the band structure, which is magnetization dependent 45 . Ab-initio calculation by Velev et al. 45 showed a reduction of bands crossing the Fermi energy when magnetization changes from m⊥z to m//z as shown in Fig. 6. Here the z is long axis of ferromagnetic metal nanowires. For m⊥z, the structure is nearly the same with situation without considering SOC. However, the SOC removes the spin degeneracy when m//z and more significantly the band splitting removes one band from Fermi surface, reducing the conduction channel.
The predicted quantized magnetoresistance in ballistic transport owing to spin-textured band effect has been ambiguously demonstrated by Sokolov et al. 46 in cobalt nanocontact as shown in Fig. 7. A stepwise variation in the ballistic conduction is Fig. 6 Calculated band structure of monoatomic Ni wire. a Without SOC and b with SOC for magnetization parallel to z axis (M//z) and c with SOC for M⊥z. The solid/dashed lines in a indicate the minority/majority-spin bands. The irreducible representation (labels in Figure) of the group C ∞ν are displayed for minority-spin bands only. (adapted from ref. 45 with permission, copyright American Physical Society 2005). observed with changing magnetic field angle (Θ) with respect to the plane of the electrode (see Fig. 7). Remarkably, the conduction is quantized into Ne 2 /h step, validating not only the feature of ballistic transport, but also corroborating the picture of change of the number of the band crossing Fermi energy owing to magnetization reorientation. The observed stepwise variation with magnetization angle is due to the fact that only the number of the band crossing Fermi energy matters 42 .
Strong spin-textured band effect can also occur in AFM ordering materials. This was demonstrated in Ruddlesden-Popper Sr 2 IrO 4 . The Sr 2 IrO 4 contains heavy 5d Ir element, which produces strong SOC and leads to J eff = 1/2 Mott state 47,48 . The spin is locked to the tilted IrO 6 octahedra, as a result, each layer has weak net moment and they anti-align to their nearest neighbors 49 . Under external magnetic field, spin-flip transition occurs and Sr 2 IrO 4 exhibits weak FM phase. Theory calculation by Lu et al. 32 shows that rotating the axis of the weak FM phase will change bandgap. With magnetic moment m Ir //[100], the bandgap between J 1/2 -LHB and J 1/2 -UHB is 25.9 meV, whereas this bandgap is increased to 35 Anomalous Hall effect A local non-zero Berry curvature can have profound impact on electronic properties no matter whether the global topological Chern number (the integral of Berry curvature) is non-trivial 50,51 . This fact suggests that local variation of band structure, especially the band crossing and anti-crossing features can have striking physical impact, whereas the global change of band topology is not required. Such characteristics allow us to achieve novel anomalous transport in spin-textured band materials. In a ferromagnetic van der Waals Fe 3 GeTe 2 , which is suggested to be a nodal-line semimetal, the SOC can lift the degeneracy of the nodal-line and open a spin-orbit gap 19 . In 2D ferromagnetic material, the the SOC does not have influence on the band when S//x(or y) and the band remains intact (Fig. 8a). On the contrary, the S//z will involve the SOC term, which lifts the twofold degeneracy along nodal-line, leading to large Berry curvature (see Fig. 8b). Benefit from the fact that the magnetic easy axis is along z axis, the spin moment is aligned parallel to z axis, producing large Berry curvature. This effect manifests itself in very large anomalous Hall effect as shown in Fig. 8c simultaneously, which is found to be contributed by Berry curvature rather than skew scattering or side jump.
Direct imaging of spin-textured band Although BAMR provides substantial evidence of the vector fieldcontrolled band structures, a direct probe of the band structure change is still required to confirm microscopically the effect of spin direction controlled band structures and offer more detail of their underlying physics. Direct probe of band structure changes has been done by STM and angle resolved photoemission spectroscopy (ARPES). This can be traced back to the earlier work done by Bode et al. 52 in 2002 who first revealed a difference of STS of thin Fe film between domain region and domain wall. As STS probes the density of state, the difference indicates band structure change. Given that the spin direction in domain wall rotates gradually from out-of-plane to in-plane and spins within domains lie in-plane, such difference implies a magnetization directiondependent density of states, which is attributed to magnetizationdependent mixing between minority d xy+xz and minority d z 2 orbitals thanks to SOC. This magnetization-direction-dependent tunneling effect, which is termed tunneling anisotropic magnetoresistance (TAMR) is further extended to magnetic tunneling junction, wherein anisotropic magneto-density-of-state causes a spin-valve like tunneling magnetoresistance 53 . Inspired by TAMR effect, direct visualization of the magnetization-dependent band structure is further demonstrated by ARPES 24   structure of a 100 monolayers Fe film on Au (001) single crystal and directly showed the magnetization-dependent spin-orbit gap. As the stray magnetic field from remnant magnetization of this thin Fe film was too weak to distort the photoemission electrons, a true APRES was collected. The ARPES for different magnetization directions are summarized in Fig. 9. A spin-orbit gap is found for magnetization parallel to [010] or ½010, whereas this gap closes for magnetization pointing to [100] or ½100. The asymmetry between M and −M, e.g., M//k x , M//−k x , is owing to symmetry breaking caused by the presence of magnetization. The field lifts the symmetry and only single mirror plane, which is perpendicular to the magnetization, can be identified and exists. The experimental data can be well fitted into the theory calculation with SOC included 24 . ARPES directly confirms the vector-field-dependent band structure, consistent with aforementioned vector-fielddependent STS and also supported the central role of spin-orbit in spin-textured band materials.
A recent experimental breakthrough on spin-textured band materials comes from the STM study of correlated Kagome magnet Fe 3 Sn 2 , wherein a spin-driven giant electronic response going beyond Zeeman physics has been confirmed by STM/STS 18 . The conductance spectrum exhibits strong magnetic field direction dependent. Under 1 T field, which is high enough to saturate the magnetization, the side peak (indicated by the blue dots) is found to shift with field angle (see Fig. 10a), following a cosine function ΔE ¼ E À E B¼0 j j¼3:2 À 3:2cosð2θÞ. The energy modulation amplitude of 3.2 meV is much larger than Zeeman splitting induced by 1 T magnetic field. The anisotropic vectorfield-driven energy shift is mapped into contour surface plot of energy shift ΔE as a function of magnetization vector M with a nodal line along a axis as shown in Fig. 10b. The a axis nodal line arises from the fact that the spontaneous magnetization is along the a axis. Owing to strong entanglement between spin space and orbital space, the symmetry of the quasiparticle interference rotates with magnetization direction (see Fig. 10c).

SUMMARY AND FUTURE PERSPECTIVE
Many novel and exciting phenomena have been revealed in spintextured band materials such as vector-field-controlled Weyl node, semiconductor bandgap, Berry curvature, and Berry phases, opening a new paradigm for discovering new functional materials and novel device applications. A summary of experimentally discovered or theoretically predicted materials with strong  spin-textured bands, spanning many types of functional materials, from semiconductors, ferromagnets, topological insulators, to Weyl metals, are shown in Table 1. The surprisingly wide spectrum of spin-textured bands materials owes to one key feature that spin direction becomes a pivotal knob to tune the band structures. As a result, rotating spin can change the semiconducting bandgap (e.g., CrI 3 ), Fermi surface topology and symmetry (Fe 3 Sn 2 ), Berry curvature (e.g., Fe 3 GeTe 2 ), and therefore can lead to many emergent spin-direction-triggered electronic phase transition and novel phenomena as summarized in Table 1.
The SOC is one of the well-known spin-direction-dependent interactions that play in the band structure. Besides the tens of materials mentioned in this review, we are expecting to discover more and more spin-textured band materials based on three proposed criteria, including strong SOC, low structural symmetry, and long-range magnetic order, which might be satisfied by many under investigated 2D magnetic materials and other similar materials, as these systems involve heavy elements that hold strong SOC. The large amount of spin-textured band materials and wide spectrum of spin-driven electronic phases strongly suggest the promising application of these materials for diverse applications. It is worth to cultivate the spin-textured band materials to establish new spintronics where spin direction is a key knob.
Regarding that many topological phases and collective competing electronics phases are driven by SOC, many more unprecedented physical properties are yet to be discovered theoretically and experimentally in spin-textured band materials where SOC now can be controlled by spin orientation. Several proposed new phenomena are shown in Fig. 11. In massless Dirac system of graphene, to open the gap is crucial for semiconducting device application. Introducing long-range magnetic ordering and SOC may lead to spin-orbit gap, which can be further controlled by magnetization direction. Such novel phases in graphene can lead to fundamentally new devices combining spintronics and massless Dirac electronics. In addition, if the spin orientation controlled spin-orbit gap is located near Fermi surface, a spin direction controlled metal-to-insulator transition can occur, leading to colossal AMR driven by band structure change. This can be explored in two-dimensional or layer structural ferromagnetic metal. Owing to the coupling of the magnetization to other physical properties, the field-dependent physical properties measurement will not only show the signature of fieldmagnetization hysteresis loop, such as coercive field and saturation field, but also field orientation dependence, distinguishing the spin-textured band effect from conventional magnetoresistance.
Another exciting system to cultivate the spin-textured band effect is the inversion symmetry breaking where spin up and down lead to two different band structures and hence physical properties. This has big advantage in practical application, as most magnets exhibit spin bistability owing to magnetic anisotropy. The spin is stabilized at direction parallel (S↑) or antiparallel (S↓) to easy axis. If the (S↑) and (S↓) have different band structures and thus different resistances, a non-volatile bi-resistance states then can be realized. We can use this material itself as a non-volatile memory unit. To break the inversion symmetry, we need to explore new types of spin-vector-dependent interaction.
In term of materials candidate for exploring giant spin-textured band effect, oxide heterostructures and van der Waals heterostructures are very promising besides the two-dimensional ferromagnets. Interfacial two-dimensional magnets with strong SOC Fig. 10 Vector-magnetization-dependent band structures in Fe 3 Sn 2 . a The dependence of the scanning tunneling spectra on the angle of in-plane magnetic field relative to a axis. b 3D mapping of magnetic vector M dependent saturated energy shift ΔE ¼ E B À E B¼0 . A nodal line exists along the a axis. c Magnetic field direction dependent pattern of quantum particle interference. The field direction is indicated in the insets with respect to the Kagome lattice. (adapted from ref. 18 with permission, copyright Springer Nature 2018). can be artificially designed and fabricated in heterostructures. In addition, broken inversion symmetry and Rashba SOC can be easily introduced at interface. Therefore, the heterostructures are idea system to explore more exciting phenomena, residing in giant spin-textured band materials. In summary, intense research has just started and many novel spin-textured band materials have been reported. More exciting phenomena, functionalities, and devices applications need to be cultivated. At the same times, there are still many challenges. The coercive field is very high for many magnets, but the high field is not compatible with ARPES. Therefore, the direct imaging of the band structure change using ARPES is not feasible. The STM faces another technique problem that STM can only probe density of state in conductive samples. New characterization tools and methods, in these regards, are required to be developed to boost the discovery of new spin-textured band materials. Moreover, high throughput theoretical calculation is another promising and efficient route to unearth giant spin-textured band materials.