Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

Author Correction: A Cu(II)–ATP complex efficiently catalyses enantioselective Diels–Alder reactions

The Original Article was published on 22 September 2020

Correction to: Nature Communications https://doi.org/10.1038/s41467-020-18554-x, published online 22 September 2020.

The original version of this Article contained several errors with regards to the absolute configurations of 2’-OH and 3’-OH at ATP in the theoretical models. The errors can be found in Fig. 4a and Fig. 4b. The correct version of Fig. 4a and 4b is:

which replaces the previous incorrect version:

This has been corrected in both the PDF and HTML versions of the Article.

The associated Supplementary Figs. S22S25 also contained the same error. The correct version of Supplementary Figures S22-S25 are:

Supplementary Fig. 22. The proposed models of Cu2+ATP. The relative electronic energies are in the parenthesis with a unit of kcalmol−1.

Supplementary Fig. 23. The precursors of the intermediates of 1a-Cu2+ATP and 2 that yield the corresponding products 3a in different configurations. The relative electronic energies (ΔE) of the precursors are shown in the table.

Supplementary Fig. 24. The intermediates of 3a-ATPCu2+ and their relative electronic energies (ΔE).

Supplementary Fig. 25. The relative electronic energy profile of the reaction path for Cu2+ATP-catalyzed Diels–Alder reaction of 1a and 2 that yields 3a (endo) in the absolute configuration of 1R, 2S, 3S, 4S. TS, transition state.

which replace the previous incorrect versions:

Supplementary Fig. 22. The proposed models of Cu2+ATP. The relative electronic energies are in the parenthesis with a unit of kcalmol−1.

Supplementary Fig. 23. The precursors of the intermediates of 1a-Cu2+ATP and 2 that yield the corresponding products 3a in different configurations. The relative electronic energies (ΔE) of the precursors are shown in the table.

Supplementary Fig. 24. The intermediates of 3a-ATPCu2+ and their relative electronic energies (ΔE).

Supplementary Fig. 25. The relative electronic energy profile of the reaction path for Cu2+ATP-catalyzed Diels–Alder reaction of 1a and 2 that yields 3a (endo) in the absolute configuration of 1R, 2S, 3S, 4S. TS, transition state.

The HTML has been updated to include a corrected version of the Supplementary Information.

Due to the above errors, the text in the original version of this Article also contained errors. Page 5, right column incorrectly reads ‘The relative electronic energy (ΔE) of the optimised Cu2+·ATP structure was 1.1 kcal mol−1 lower than that of a previously described model obtained by a molecular orbital method57 and 22.7 kcal mol−1 lower than that of the Cu2+·ATP model without a hydrogen bond (Supplementary Fig. S22).’ and ‘the ΔE value of the precursor of 1a-Cu2+·ATP and 2 that yielded 3a (endo) via the attack of the Si face was 8.1 kcal mol−1 lower than that of the precursor for the Re face attack (Fig. 4b).’ The correct version states ‘The relative electronic energy (ΔE) of the optimised Cu2+·ATP structure was 0.3 kcal mol−1 lower than that of a previously described model obtained by a molecular orbital method57 and 8.7 kcal mol−1 lower than that of the Cu2+·ATP model without a hydrogen bond (Supplementary Fig. S22).’ and ‘the ΔE value of the precursor of 1a-Cu2+·ATP and 2 that yielded 3a (endo) via the attack of the Si face was 9.1 kcal mol−1 lower than that of the precursor for the Re face attack (Fig. 4b).’

Page 6, left column incorrectly reads ‘However, the ΔE value of 3a (Re-exo) was 1.3 kcal mol−1 lower than that of 3a (Si-exo), in accordance with the experimental results (Supplementary Figs. S21, S24).’ The correct version states ‘However, the ΔE value of 3a (Re-exo) was 2.6 kcal mol−1 lower than that of 3a (Si-exo), in accordance with the experimental results (Supplementary Figs. S21, S24).’

This has been corrected in the PDF and HTML versions of the Article.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Changhao Wang.

Supplementary information

Rights and permissions

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Wang, C., Qi, Q., Li, W. et al. Author Correction: A Cu(II)–ATP complex efficiently catalyses enantioselective Diels–Alder reactions. Nat Commun 13, 1631 (2022). https://doi.org/10.1038/s41467-022-28850-3

Download citation

  • Published:

  • DOI: https://doi.org/10.1038/s41467-022-28850-3

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing