Abstract
Over the past three decades, graphene has become the prototypical platform for discovering topological phases of matter. Both the Chern \(C\in {\mathbb{Z}}\) and quantum spin Hall \(\upsilon \in {{\mathbb{Z}}}_{2}\) insulators were first predicted in graphene, which led to a veritable explosion of research in topological materials. We introduce a new topological classification of twodimensional matter – the optical Nphases \(N\in {\mathbb{Z}}\). This topological quantum number is connected to polarization transport and captured solely by the spatiotemporal dispersion of the susceptibility tensor χ. We verify N ≠ 0 in graphene with the underlying physical mechanism being repulsive Hall viscosity. An experimental probe, evanescent magnetooptic Kerr effect (eMOKE) spectroscopy, is proposed to explore the Ninvariant. We also develop topological circulators by exploiting gapless edge plasmons that are immune to backscattering and navigate sharp defects with impunity. Our work indicates that graphene with repulsive Hall viscosity is the first candidate material for a topological electromagnetic phase of matter.
Similar content being viewed by others
Introduction
Monolayer graphene forms the canonical system to study twodimensional (2D) topological phases of matter. The now famous Haldane model of graphene^{1}, with timereversal breaking nextnearestneighbor (NNN) hopping, was the first proposal of a Chern phase \(C\in {\mathbb{Z}}\) and a nontrivial TKNN invariant^{2}. Conversely, the KaneMele model^{3} preserves timereversal symmetry and was the first example of a quantum spin Hall phase \(\upsilon \in {{\mathbb{Z}}}_{2}\), resulting from spin–orbit coupling in graphene. Nevertheless, the growing collection of topological phases in condensed matter can be categorized under the umbrella of electrostatics since all observables, e.g., the quantum Hall σ_{xy} = Ce^{2}/h and spin Hall \({\sigma }_{{{{{{\rm{xy}}}}}}}^{s}\,=\,\upsilon e/2\pi\) conductivity, are interpreted at zero photon energy and momentum ω = q = 0. One must go beyond this paradigm to characterize the optical properties of matter, as these are defined for electromagnetic fluctuations over all frequencies ω ≠ 0 and momenta q ≠ 0. We are quickly confronted with two important questions: what are the optical invariants of a material? Do these topological invariants represent unique electromagnetic phases of matter? Our work lays the foundations for this optical classification of condensed matter.
In this paper, we present graphene imbued with Hall viscosity as a paradigmatic example of a topological electromagnetic phase of matter. Please see Fig. 1 and Table 1 comparing the fundamental differences between the Chern phase, quantum spin Hall phase and the optical Nphase. This nontrivial topology is revealed in the magnetohydrodynamics of the 2D Navier–Stokes equations. Until quite recently however, viscous electrohydrodynamics with nonzero magnetic field B ≠ 0 has been experimentally inaccessible, mainly due to impurities and electron–phonon scattering^{4}. Exceptional grade 2D materials like graphene^{5,6} are providing the first platforms to study the fluidic behavior of electrons^{7,8,9}.
Hall viscosity η_{H}, the dissipationless component of the viscous stress tensor^{10,11,12,13,14}, is a generic feature of parity and timereversal breaking electron fluids and can exhibit quantization analogous to the Hall conductivity^{15,16,17}. It is challenging to measure with conventional techniques but multiple possible observables have been proposed to identify Hall viscosity experimentally, such as negative nonlocal resistance^{18,19} and anomalous Hall resistivity^{20,21}. Quantization of orbital spin^{22} and the WenZee shift^{23} represent unique topological numbers of these quantum fluids, which are associated with nontrivial electronic states. Nevertheless, most studies on Hall viscosity have focused on the steady state properties of the material—the optical attributes of the viscous Hall fluid have remained almost completely unexplored^{24,25,26}. We show that the magnetohydrodynamic response of Hall viscosity gives rise to novel topological phenomena for electromagnetic waves, only manifested in the optical regime.
We show that an optical phase \(N\in {\mathbb{Z}}\) is characterized by the winding number of the susceptibility tensor χ and intimately related to polarization transport. This topological quantum number is homotopy invariant and found by integrating the material response over all Matsubara frequencies and wavevectors of light. We emphasize that the optical Ninvariant is distinct from the TKNN invariant, and the first topological quantity that captures the winding in the longitudinal and transverse response functions. Using the fsum rule, we prove that N is generically quantized and immune to perturbations in the optical response. Our definition utilizes a Volovik (Green’s function) formalism^{27,28,29}, which is naturally generalized to quantum, dissipative and finite temperature systems^{30}. Although we only consider the continuum theory here, the formalism is robust and easily extended to the lattice case. We argue that N is the central topological quantity of the electromagnetic linear response theory and classifies all 2D optical media with broken timereversal symmetry.
We discover that the optical Ninvariant encodes the vorticity of spin1 Néeltype skyrmions in the bulk magnetoplasma. This opens the door to experimentally measure the Ninvariant through a unique magnetic field repulsion reminiscent of the Meissner effect. To probe this deep subwavelength phenomenon, we propose evanescent magnetooptic Kerr effect (eMOKE) spectroscopy. The angleresolved Kerr rotation is a direct observable of the skyrmion vorticity and optical Ninvariant. Lastly, we study the topologicallyprotected gapless edge states emerging at the boundary of the viscous Hall fluid and vacuum. We demonstrate robust chiral propagation around sharp defects along with backscatter immunity which we exploit for ultrasubwavelength topological circulators.
Our work unifies the fields of topological photonics and condensed matter physics to spawn a novel area of research in materials science. Although topological photonics^{31,32,33,34} has mainly focused on artificial media like photonic crystals^{35,36,37} and metamaterials^{38}, our findings demonstrate that condensed matter can also host topological electromagnetic states. As such, the optical phases we discuss here are microscopic properties of matter and are not related to macroscopic engineering. The optical invariant \(N\in {\mathbb{Z}}\) is therefore a classification of different topological phases of matter. In previous photonics systems, Hall viscosity has been absent and therefore are optically trivial N = 0. Graphene’s viscous Hall fluid is the first candidate for a nontrivial phase N ≠ 0 and a paradigm shift in optical materials. We note that the optical Ninvariant captures universal physics beyond graphene and sheds new light on topological superconductors^{39}, fractional quantum Hall fluids^{40}, Chern insulators^{41}, Weyl semimetals^{42}, and superfluids^{43}.
Results
Dynamics of the viscous Hall fluid
Our starting point is the 2D Navier–Stokes (NS) equations subject to a uniform magnetic field B and a spatiotemporally varying electric field E(t, r). The 2D NS equations describe the viscous flow of a parity and timereversal breaking Hall fluid in Fermiliquid theory. This theory has successfully explained the experimentally observed steady state properties of graphene^{4}. On the other hand, our analysis focuses on the dynamical timedependent behavior. Viscosity characterizes the resistance to deformation and amounts to a restoring force in the NS equations. The conventional shear viscosity η is dissipative and impedes the motion of the fluid. Hall viscosity η_{H} however, is dissipationless and generates a force perpendicular to the motion. Assuming the electric field fluctuations are relatively weak, the charge density ρ = ρ_{0} + δρ will be perturbed around its equilibrium value ρ_{0} = −en_{0}, where e is the elementary charge and n_{0} is the electron density. We derive the linearized timedependent NS equations, which incorporates acceleration ∂_{t}J ≠ 0 and compressibility ∇ ⋅ J ≠ 0 of the Hall fluid,
E represents the parallel electric field at the location of the electron fluid z = 0. The full derivation is provided in Supplementary Note 2. Combining Eq. (1) with the continuity equation ∂_{t}ρ + ∇ ⋅ J = 0 completely specifies the charge ρ and current J densities with appropriate boundary conditions. The speed of sound is \({v}_{{{{{{\rm{s}}}}}}}\simeq {v}_{{{{{{\rm{F}}}}}}}/\sqrt{2}\) and we have assumed Dirac dispersion characteristic of graphene^{44} to obtain the proportionality of v_{s} to the Fermi velocity v_{F}. Here, γ = τ^{−1} is the phenomenological damping rate characterizing momentumnonconserving collisions and ω_{c} = eB/(mc) is the cyclotron frequency. m is the effective mass of the electron and c is the speed of light. The kinetic shear and kinetic Hall viscosities are given by ν = η/(mn_{0}) and ν_{H} = η_{H}/(mn_{0}), respectively. We can also define three important length scales: the shear \({D}_{\nu }\,=\,\sqrt{\nu \tau }\) and Hall \({D}_{{{{{{\rm{H}}}}}}}=\sqrt{ {\nu }_{{{{{{\rm{H}}}}}}}/{\omega }_{{{{{{\rm{c}}}}}}} }\) diffusion lengths, as well as the cyclotron radius r_{c} = ∣v_{s}/ω_{c}∣, which characterize the hydrodynamic behavior at mesoscopic scales. The relative sign of ν_{H} with respect to ω_{c} is paramount to the topological physics and dictates whether Hall viscosity repels or reinforces the magnetic field. Optical Nphases and nontrivial electromagnetic states emerge in the repulsive regime ω_{c}ν_{H} > 0.
Magnetohydrodynamic susceptibility
We now derive the bulk linear response theory (LRT) of an unbounded viscous Hall fluid, specifically in the ultrasubwavelength regime. Assuming translational symmetry in the r = (x, y) plane, the inplane momentum q = (q_{x}, q_{y}) is conserved which means we can Fourier transform to the reciprocal space. Due to nonlocality arising from pressure v_{s} ≠ 0 and viscosity ν ≠ 0, the momentum space is particularly useful to understand the LRT. To facilitate this, we utilize the susceptibility tensor χ,
which gives the induced polarization density P to an applied electric field E. The response function χ completely characterizes the bulk optical properties of the material, for every energy ω and momentum q of the photon. Note that both ω and q are real parameters here. Exploiting rotational symmetry, we derive the components of the susceptibility tensor in an orthogonal basis,
where \({\hat{q}}_{{{{{{\rm{i}}}}}}}={q}_{{{{{{\rm{i}}}}}}}/q\) is the unit vector directed along the inplane momentum and \(q=\sqrt{{{{{{{{\bf{q}}}}}}}}\cdot {{{{{{{\bf{q}}}}}}}}}\) is its magnitude. δ_{ij} is the identity and ϵ_{ij} is the 2D LeviCivita symbol. In traditional LRT (q ≈ 0), this crucial distinction between longitudinal and transverse response functions is ignored. However, the optical Ninvariant captures the deep subwavelength topology of matter and requires both the current–current (transverse) and density–density (longitudinal) response. The transverse χ^{T} and longitudinal χ^{L} response functions can be identified in the induced polarization using a transverse q ⋅ E = 0 and longitudinal q × E = 0 electric field respectively. Gyrotropy g couples these two components.
Note, the response function is temporally dispersive (ω dependent) as well as spatially dispersive (q dependent), and both properties are essential to realize optical Nphases. Temporal dispersion quantifies the degrees of freedom of the electronic excitations, while spatial dispersion characterizes the geometric phase of the induced polarization. We decompose the components of χ into its transverse χ^{T},
longitudinal χ^{L},
and gyrotropic g response,
\(\tilde{\omega }=\omega +i{{\Gamma }}\) is the shifted energy, where Γ(q) = γ + νq^{2} is the viscous damping rate that describes the decay pathways. Ω_{c}(q) is the viscous cyclotron frequency,
Due to Hall viscosity ν_{H}, the effective magnetic field in the Hall fluid is momentum dependent \({B}_{{{{{{{{\rm{eff}}}}}}}}}(q)\,=\,mc{{{\Omega }}}_{{{{{{\rm{c}}}}}}}(q)/e=B(1{D}_{{{{{{\rm{H}}}}}}}^{2}{q}^{2})\) and varies on the scale of the Hall diffusion length D_{H}. In the dissipationless (Hermitian) limit Γ → 0, we obtain the LRT of an ideal quantum Hall fluid χ = χ^{†}.
Lastly, we verify that the susceptibility tensor satisfies the reality condition,
since electromagnetism is a realvalued vector field theory. Due to Eq. (6), the components of χ cannot be completely independent, implying the excitations belong to universality class D, the same symmetry class as topological superconductors^{45}. This should be contrasted with the electron, which belongs to symmetry class A, or class AII in the presence of timereversal symmetry. Particle number is conserved in the complex fermionic classes due to U(1) symmetry, but this is not true for the bosonic classes since the excitations are their own antiparticle. Generically, the spatiotemporally dispersive susceptibility tensor χ(ω, q) represents a mapping from the 2 + 1D momentum space to the general real linear group \({{{{{{{{\rm{GL}}}}}}}}}_{{{{{{\rm{n}}}}}}}({\mathbb{R}})\). n denotes the degrees of freedom—i.e., the total n × n matrix dimension of χ.
Optical Ninvariant
The susceptibility tensor χ is precisely the Green’s function of the polarization density P and is therefore a topological object. The cornerstone of the Green’s function approach developed by Volovik^{27,28,29}, lies the following 2 + 1D topological invariant,
where χ(ω, q) → χ(Ω, q) is parameterized by the complex frequency variable ω → Ω. In this case, ∂_{α} indicates partial derivatives with respect to the total momentum coordinate q_{α} = (Ω, q) and \({{{{{{{\rm{tr}}}}}}}}\) denotes the trace over the tensor indices of χ. Note that the temporal integral dΩ is performed vertically over all imaginary (Matsubara) frequencies^{46},
ω = ℜ(Ω) is the photon energy that is assumed to lie within the electronic band gap 0 < ℏω < E_{bg}. Bulk current cannot be generated since the photon does not possess sufficient energy to stimulate a transition – it can only polarize the material. With parabolic dispersion (\(2{\omega }_{{{{{{\rm{c}}}}}}}{\nu }_{{{{{{\rm{H}}}}}}} < {v}_{{{{{{\rm{s}}}}}}}^{2}\)), the band gap of an ideal quantum Hall fluid is defined by the first Landau level (E_{bg} = ℏ∣Ω_{c}(0)∣ = ℏ∣ω_{c}∣). A plot of the contour integral is shown in Fig. 2b.
Equations (7) and (8) clearly highlight the differences from the Chern number (TKNN invariant) and previous theories in the field of topological photonics. We reiterate that the optical Ninvariant is fundamentally different than the electronic Chern number as they describe physically distinct quantities. The Chern number C is related to the U(1) Berry phase of the wave function ψ. On the other hand, the Ninvariant quantifies the spectral asymmetry in the susceptibility tensor χ. Accordingly, the Chern number C characterizes the topology of the bulk electronic band structure while the Ninvariant characterizes the topology of the bulk polaritonic band structure^{25,26}. These are plasmons for the quantum Hall fluid, but all dipolecarrying excitations such as excitons, phonons, magnons, and Cooperpairs^{47} can be accounted for in our theory.
To prove N is a quantized topological invariant, we consult a few fundamental properties of the response function. Every solid is transparent at ∣Ω∣ → ∞ since all electrons respond as free particles to rapidly varying temporal oscillations. The susceptibility tensor approaches a purely diamagnetic response which is independent of q and nonsingular \(\det \chi \,\ne\, 0\),
This is a universal property of optical materials and ultimately a consequence of the fsum rule, also known as the optical, conductivity, or ThomasReicheKuhn (TRK) sum rule^{48}. The fsum rule guarantees that our contours in the complex frequency plane are nondegenerate which is essential for homotopy invariance^{29,46}. The detailed proof is presented in Supplementary Note 3. By including the point at infinity (∣Ω∣ = ∞), each contour in Eq. (8) defines a circle S^{1} in the extended complex plane. Moreover, due to viscosity, the susceptibility tensor is naturally regularized and approaches a directionally independent value as q → ∞,
Again, by including the point at infinity (q = ∞), the q space is topologically equivalent to the sphere S^{2}. The combined 2 + 1D momentum space is compactified and effectively S^{2} × S^{1}. A visualization of this manifold is depicted in Fig. 2a. The susceptibility tensor χ(Ω, q) is therefore an element of the third homotopy group of \({{{{{{{{\rm{GL}}}}}}}}}_{{{{{{\rm{n}}}}}}}({\mathbb{R}})\),
which is isomorphic to \({\mathbb{Z}}\). Equation (11) epitomizes the crucial fact that the optical Ninvariant is universal and modelindependent. The integral in Eq. (7) calculates the precise element of \(N\in {\mathbb{Z}}\) the response function corresponds to, where each integer represents a unique optical phase. This should be contrasted with the generalized TKNN invariant C, which is characterized by complex fields \({\pi }_{3}[{{{{{{{{\rm{GL}}}}}}}}}_{n}({\mathbb{C}})]={\mathbb{Z}}\). We stress that although both N and C are integer invariants, the symmetry classes are fundamentally different.
Optical Ninvariant of the viscous Hall fluid
We verify that graphene’s viscous Hall fluid is the first candidate material for a topological electromagnetic phase of matter. Specifically, it has nontrivial optical invariant (N ≠ 0) when Hall viscosity is repulsive ω_{c}ν_{H} > 0. Utilizing the magnetohydrodynamic theory [Eq. (4)] and the homotopy equation [Eq. (7)] we arrive at,
where \(\tilde{{{\Omega }}}={{\Omega }}+i{{\Gamma }}\) and the sign of the dissipation is implied \({{\Gamma }}\to {{{{{{{\rm{sgn}}}}}}}}[\Im ({{\Omega }})]{{\Gamma }}\) to preserve causality. We integrate Eq. (12) numerically in Fig. 2c but it is important to confirm that N is quantized in the zero temperature quantum limit Γ → 0. Integrating over all Matsubara frequencies and wavevectors, we acquire the optical Ninvariant of the viscous Hall fluid,
The invariant is quantized to N = ±2 when Hall viscosity is repulsive ω_{c}ν_{H} > 0 and trivial N = 0 for ω_{c}ν_{H} < 0. We note that the definition of N through the homotopy group [Eq. (7)] is robust and does not rely on any symmetries of the NS theory such as Galilean invariance and frequencymomentum independence in the viscosity coefficients. Thus, the Ninvariant can be immediately generalized beyond graphene to more exotic materials; for instance the magnetoroton excitations in fractional quantum Hall fluids^{24,49}.
eMOKE spectroscopy and skyrmion texture
Here we put forth an experimental probe of the optical Ninvariant. The Ninvariant encodes a peculiar vorticity in the bulk magnetoplasmons (BMPs) that arises from repulsive Hall viscosity (ω_{c}ν_{H} > 0). We prove these are spin1 skyrmions^{50} carrying deep subwavelength texture of the optical Ninvariant. The fundamental reason why they are spin1 is because electromagnetism is a vector field theory so spin arises from the circular polarization state of P. The selfconsistent solutions of Poisson’s equation and the NS equations [Eq. (1)] produces the BMP dispersion ω = ω_{b}(q). A short review is provided in the Supplementary Note 5. At low q, we obtain the characteristic square root dispersion (\(\sqrt{q}\)) of a BMP which is generated from the longrange Coulomb interaction. However, the hydrodynamic behavior dominates at high q and is the origin of topologically nontrivial electromagnetic states.
Although BMPs in quantum Hall fluids have been studied for many years, the effect Hall viscosity has on dynamical variables like the angular momentum (AM) has never been considered. From first principles electrodynamics, we derive the energy density u_{q} and AM density m_{q} in the bulk momentum space. The ratio of these two quantities gives the AM j_{z} per unit energy ω_{b} of the BMP,
j_{z} is the AM of a spin1 Néeltype skyrmion^{51} which varies dynamically with the momentum q,
Ω_{p} being the effective plasma frequency. As a consequence of rotational symmetry, the skyrmion number is determined by the difference in AM eigenvalues Δj_{z} at the rotationally invariant momentum q = 0 and q = ∞. The eigenvalues must be integers j_{z} = ±1 or 0 at these points due to the spin1 representation^{25}. For the BMP we obtain,
Notice that the AM flips direction giving ∣Δj_{z}∣ = 2 in the repulsive regime ω_{c}ν_{H} > 0—the signature of a topologically nontrivial skyrmion. Indeed, the skyrmion winding number is exactly equal to the optical Ninvariant derived in Eq. (13),
It should be noted that Eq. (16) only holds in the presence of rotational symmetry, nonetheless the quantization of N remains robust even without symmetry [Eq. (11)]. In this case, the Ninvariant is solely determined by the j_{z} eigenvalues at highsymmetry points q = 0 and q = ∞ which does not rely on the specific physical model of Hall viscosity. The dynamical skyrmion texture encodes a “knot” in the polarization density that cannot be undone through any continuous deformation. The AM texture j_{z}(q) as a function of the inplane momentum q is depicted in Fig. 3e.
As can be seen directly from Fig. 3e, the optical Ninvariant and skyrmion number is only nontrivial (N = Δj_{z} ≠ 0) when the viscous cyclotron frequency changes sign [Eq. (5)]. We define this phenomenon as the cyclotron null (Ω_{c}(q) = 0) which occurs at a particular inplane momentum \(q\,=\,{D}_{{{{{{\rm{H}}}}}}}^{1}\) and cannot be removed unless there is a topological phase transition. \(q\,=\,{D}_{{{{{{\rm{H}}}}}}}^{1}\) is the momentum where the effective magnetic field is completely expelled from the fluid (B_{eff}(q) = 0) and is unique to the nontrivial repulsive regime ω_{c}ν_{H} > 0. At the null, the cyclotron motion switches handedness and the circulating currents appear to rotate in the opposite direction. This interesting phenomenon is reminiscent of the Meissner effect in a superconductor, that causes all magnetic fields to be expelled from the electron fluid. The difference is that the cyclotron null Ω_{c}(q) = 0 is a deep subwavelength effect as it is a consequence of Hall viscosity.
Our goal is to measure the optical Ninvariant in bulk graphene through this unique magnetic field repulsion. These topological properties are revealed in the Kerr rotation of reflected photons. The Faraday and Kerr effects have been utilized in condensed matter physics to measure the quantized magnetoelectric response in 3D topological insulators like Bi_{2}Se_{3}^{52}. However, all such experiments have been performed with low momentum electromagnetic waves at small incident angles (q ≈ 0), which cannot probe Hall viscosity or the Ninvariant. In fact, evanescent waves are necessary q ≫ 2π/λ since the Hall diffusion length D_{H} ≪ λ/2π is generally much smaller than the wavelength of light λ.
To overcome this obstacle, we propose evanescent magnetooptic Kerr effect (eMOKE) spectroscopy—an angleresolved and highmomentum probe of the optical Ninvariant. A schematic of the eMOKE system is displayed in Fig. 3a. The polar configuration is graphene on substrate with an applied Bfield and the top exposed to vacuum. For incident light, we exploit a high index prism available at THz frequencies to interface total internally reflected evanescent waves with the viscous Hall fluid. Although the local interaction at the sample location has large momentum, the subwavelength gyrotropic information is carried to the far field by reflected photons facilitating the readout of eMOKE data through traditional lockin techniques. The experimental smoking gun of Bfield repulsion and a nontrivial Ninvariant is the switch in ellipticity of reflected light, depicted in Fig. 3b. This vanishing Kerr rotation can be measured even at room temperature. Theoretical plots of the Kerr rotation are displayed in Fig. 3c, d.
Topological edge magnetoplasmons and circulators
We now uncover the topological edge states emerging at the boundary of the viscous Hall fluid (N = 2) and show they are incredibly robust, impervious to boundary effects, as well as immune to backscattering. We strongly emphasize that the edge states considered here are fundamentally different than traditional edge magnetoplasmons (EMPs) predicted by Fetter^{53}, because they are gapless and only manifest in the magnetohydrodynamic regime. Topological EMPs with Hall viscosity cannot be regarded as a correction to gapped Fetter EMPs, since they cannot be continuously deformed into one another. This is demonstrated explicitly in Supplementary Note 6.
The extraordinary property of topological EMPs is that they are completely unaffected by boundary slip. The electron fluid exerts zero shear stress on the boundary (stressfree) while simultaneously having zero tangential current (noslip). This is very peculiar because slip usually plays a significant role in the boundary layer physics. Indeed, many factors can alter the magnitude of slip such as surface roughness, interfacefluid attraction, nanobubble nucleation and high shear rates^{54}, but the dispersion of the topological EMP remains independent. Note that this phenomenon is only possible in the nontrivial phase ∣N∣ = 2 and absolutely no edge state exists in the trivial regime N = 0. Visualizations of the hydrodynamic boundary conditions are shown in Fig. 4a with a comparison to traditional magnetooptics in Fig. 4b. The dispersion relations of the BMP ω_{b}(q_{y}) and topological EMP ω_{e}(q_{y}) are displayed in Fig. 4c. We have calculated the dispersion for arbitrary boundary slip conditions to demonstrate the robustness of the edge state.
Lastly, we numerically simulate an ultrasubwavelength topological circulator and illustrate the robust unidirectional transport of topological edge plasmons in complicated geometries. We choose a hexagonal sample of viscous Hall fluid with a center to edge length of d = 20r_{c}, where r_{c} = ∣v_{s}/ω_{c}∣ is the cyclotron radius. To excite the topological EMPs we let the dipole source oscillate in the band gap 0 < ω < ∣ω_{c}∣ such that no bulk current can be generated. The normalized charge density fluctuation δρ/ρ_{0} is plotted in Fig. 4d. For an excitation frequency of ω = ∣ω_{c}∣/2, the edge wave propagates at approximately the speed of sound v_{s}. Interestingly, the edge state propagates around sharp defects with zero backscattering and is impervious to boundary effects. Supplementary Movie 1 showcases the propagation of the edge state around a sharp defect. Supplementary Fig. 2 displays the geometry of a 3port topological circulator.
Discussion
We have introduced the optical phases \(N\in {\mathbb{Z}}\) of twodimensional quantum matter—a topological classification emerging from the invariant optical proprieties of a material. As a particularly important platform, we have shown that N ≠ 0 is nontrivial in graphene’s viscous Hall fluid and fundamentally tied to repulsive Hall viscosity. In addition, we have proposed a unique probe of topological matter: evanescent magnetooptic Kerr effect (eMOKE) spectroscopy to search for nontrivial spin1 skyrmion texture and the Bfield expulsion that is reminiscent of the Meissner effect. Robustness and backscatter immunity of the topological edge states was demonstrated by analyzing an ultrasubwavelength circulator. These intriguing optical Nphases are also expected in topological superconductors, fractional quantum Hall fluids, Chern insulators, Weyl semimetals and superfluids^{39,40,41,42,43}, leading to a new generation of effects at the interface of topological photonics and condensed matter physics.
Methods
Energy regularization from the fsum rule
The fsum rule [Eq. (9)] is a form of energy conservation on lightmatter interactions. It implies the sum over all electronic transitions must equal the total energy put into the system. This places a fundamental constraint on the electromagnetic LRT. Over the entire frequency space, the susceptibility tensor can be expressed as \(\chi =\chi ^{\prime} +i\chi ^{\prime\prime}\) with \(\chi ^{\prime}\) and χ″ both Hermitian. χ″ accounts for dissipation and absorption mechanisms from electron transitions. In a quantum system, χ″ is zero in the band gap 0 < ℏω < E_{bg} but contains δfunctions at the transition energies. In any case, the absorption over all ω is invariant due to the fsum rule^{48},
where \(\sigma ^{\prime}\) is the dissipative part of the conductivity tensor \(\sigma =\sigma ^{\prime} +i\sigma ^{\prime\prime}\). It is clear that Eq. (17a) can never vanish, otherwise transitions would cost no energy. Using the Kramers–Kronig relations for large ∣Ω∣ → ∞, we immediately obtain the asymptotic behavior of χ,
Topologically, the fsum rule can be understood as an energy (Ω) regularization. Since the susceptibility asymptotically approaches the identity, all singularities (poles and zeros) of χ occur at finite values of Ω. Hence, any sufficiently large contour in the complex plane is nondegenerate which is a necessary condition for homotopy invariance.
Topological stability of the optical Nphases
Here we demonstrate explicitly that N is a quantized topological invariant and stable under variations. To prove this, we need only consult the fsum rule and the regularity of χ at q → ∞, outlined in Eq. (9) and (10) respectively. This definition generalizes beyond the NS equations to encompass all continuous optical media. We consider an arbitrary perturbation to the response function χ → χ + δχ, which takes N → N + δN,
All perturbations amount to a total divergence in the integrand. Since the susceptibility tensor is regular at q → ∞, the spatial q boundary terms necessarily vanish. This is equivalent to the periodic boundary condition in the lattice theory. However, temporal Ω boundary terms can contribute if the system is nonHermitian (dissipative) since χ is discontinuous along the imaginary line of Ω. This is observed in Fig. 2c. In the dissipationless quantum limit Γ → 0, the response function is Hermitian χ = χ^{†} and therefore continuous along the entire imaginary line. Due to the fsum rule, the temporal boundaries are zero and δN = 0 vanishes identically. \(N\in {\mathbb{Z}}\) is thus topologically quantized and immune to variations in the optical response.
eMOKE setup and read out
The MOKE spectroscopy setup we consider is in polar geometry, with the external magnetic field B applied normal to the graphene sample. Since graphene is a 2D material, this experiment is more specifically known as the surface MOKE (SMOKE)^{55}. The Kerr effect, or Kerr rotation, is the phenomenon where linearly polarized light becomes elliptical upon reflection. The cross polarization term r_{ps} that couples \(\hat{s}\) and \(\hat{p}\) polarized waves is directly proportional to the gyrotropy r_{ps} ∝ g ∝ Ω_{c} and a definite measurement of the Kerr rotation. We incident THz frequency light on the sample at steep angles to probe the highmomentum modes of the electron fluid. To determine if the sample is topologically nontrivial, we must look for nulls in the Kerr rotation,
The exact expressions for the reflection coefficients are derived in the Supplementary Note 4 along with a short review of boundary conditions on 2D charge densities in Supplementary Note 1. The Kerr rotation is defined by the ratio of reflected \(\hat{p}\) to \(\hat{s}\) polarization due to an incident \(\hat{s}\) polarized wave. Θ ∈ [0, π] is the relative magnitude and Φ ∈ [−π, π] is the relative phase. Theoretical plots of the MOKE are displayed in Fig. 3c, d. We explicitly calculate the relevant parameters for monolayer graphene under conventional laboratory settings to isolate the frequencymomentum space that should be explored for topological phenomena [see Table 2].
Boundary conditions on viscous Hall fluids
An important feature of an electron fluid, as opposed to an ordinary fluid, is that it interacts through the Coulomb potential. Accordingly, we must ensure continuity of the electric potential ϕ and its normal derivative \(\hat{n}\cdot {{{{{{{\boldsymbol{\nabla }}}}}}}}\phi\) at the boundary. Although edge states in chiral active fluids have been studied in the context of the NS equations^{56,57}, scarce few works have coupled them to Poisson’s equation^{58}. The most significant impact of the longrange Coulomb interaction is that at low momentum q_{y} → 0, the group velocity of the EMP diverges logarithmically \(\partial {\omega }_{{{{{{\rm{e}}}}}}}/\partial {q}_{{{{{{\rm{y}}}}}}} \sim {{{{{{\mathrm{log}}}}}}}\,{q}_{{{{{{\rm{y}}}}}}}\), which is characteristic of a 1D plasmon^{59}.
Due to nonlocality in a hydrodynamic electron fluid^{60}, we also require boundary conditions on the current density J. In optics these are known as additional boundary conditions (ABCs)^{61} since the charge configuration at any point is not uniquely determined by the electric field at the same point. Nonlocal theories were first utilized to understand the anomalous skin effect in metals at high frequencies^{62}. We show that a topological skin effect occurs in the nontrivial phase ∣N∣ = 2, where an AC current propagates unidirectionally at the edge and decays exponentially into the bulk. The BCs on J follow from elementary conservation laws. Charge conservation necessitates a vanishing normal current,
where \(\hat{n}\) is the outward normal unit vector and ∂V denotes the boundary of the volume V. A viscous hydrodynamic fluid also requires a BC on the tangential current, which is related to momentum conservation. The tangential current is proportional to the shear stress (offdiagonal stress) on ∂V^{21},
\(\hat{t}=\hat{n}\times \hat{z}\) is the unit tangential vector, ς is the viscous stress tensor and v_{b} is the boundary scattering velocity that dictates the slip flow. Note that both shear ν and Hall ν_{H} viscosity generate a shear stress on the boundary so a frictional force remains even in the quantum limit ν → 0.
The scattering velocity v_{b} ≥ 0 is generally positive for electron fluids but can be negative in principle^{63}. In the extreme limits of v_{b} = 0 and v_{b} = ∞, we recover the familiar stressfree and noslip BCs respectively. Although noslip is approximately valid at macroscopic scales, it has no microscopic justification and is normally not satisfied. We must consider the partialslip scenario 0 < v_{b} < ∞ to accurately describe the boundary physics. A visualization of the various hydrodynamic BCs is depicted in Fig. 4a. Another significant issue with stressfree and noslip is that they can generate unstable spurious solutions^{64,65}. These unphysical states will be gapped out immediately if we continuously deform the BC. The topological ones, however, will remain. This is the case for topological EMPs which is shown in Supplementary Fig. 1. In the nontrivial phase ∣N∣ = 2, the EMP satisfies noslip and stressfree BCs simultaneously and is therefore independent of the boundary slip flow. Indeed, Eq. (20b) is fulfilled automatically for any value of v_{b}, including negative values. This interesting property is demonstrated in Fig. 4c, d, which is simulated for arbitrary values of v_{b}.
Data availability
The authors declare that the data supporting the findings of this study are available within the paper and its supplementary information files.
Code availability
The code compiled for numerical simulations are available from the corresponding author upon reasonable request.
References
Haldane, F. D. M. Model for a Quantum Hall effect without Landau levels: condensedmatter realization of the "Parity anomaly”. Phys. Rev. Lett. 61, 2015–2018 (1988).
Thouless, D. J., Kohmoto, M., Nightingale, M. P. & den Nijs, M. Quantized hall conductance in a twodimensional periodic potential. Phys. Rev. Lett. 49, 405–408 (1982).
Kane, C. L. & Mele, E. J. Quantum Spin Hall effect in graphene. Phys. Rev. Lett. 95, 226801 (2005).
Berdyugin, A. I. et al. Measuring Hall viscosity of graphene’s electron fluid. Science 364, 162–165 (2019).
Lucas, A. & Fong, K. C. Hydrodynamics of electrons in graphene. Journal of Physics: Condensed Matter 30, 053001 (2018).
Crossno, J. et al. Observation of the Dirac fluid and the breakdown of the WiedemannFranz law in graphene. Science 351, 1058–1061 (2016).
Müller, M., Schmalian, J. & Fritz, L. Graphene: a nearly perfect fluid. Phys. Rev. Lett. 103, 025301 (2009).
Bandurin, D. A. et al. Negative local resistance caused by viscous electron backflow in graphene. Science 351, 1055–1058 (2016).
Bandurin, D. A. et al. Fluidity onset in graphene. Nat. Commun. 9, 4533 (2018).
Mendoza, M., Herrmann, H. J. & Succi, S. Hydrodynamic model for conductivity in graphene. Sci. Rep. 3, 1052 (2013).
Scaffidi, T., Nandi, N., Schmidt, B., Mackenzie, A. P. & Moore, J. E. Hydrodynamic electron flow and Hall viscosity. Phys. Rev. Lett. 118, 226601 (2017).
Bradlyn, B., Goldstein, M. & Read, N. Kubo formulas for viscosity: Hall viscosity, Ward identities, and the relation with conductivity. Phys. Rev. B 86, 245309 (2012).
Soni, V. et al. The odd free surface flows of a colloidal chiral fluid. Nat. Phys. 15, 1188–1194 (2019).
Narozhny, B. N. & Schütt, M. Magnetohydrodynamics in graphene: shear and Hall viscosities. Phys. Rev. B 100, 035125 (2019).
Avron, J. E., Seiler, R. & Zograf, P. G. Viscosity of Quantum Hall fluids. Phys. Rev. Lett. 75, 697–700 (1995).
Hoyos, C. & Son, D. T. Hall viscosity and electromagnetic response. Phys. Rev. Lett. 108, 066805 (2012).
Sherafati, M., Principi, A. & Vignale, G. Hall viscosity and electromagnetic response of electrons in graphene. Phys. Rev. B 94, 125427 (2016).
Levitov, L. & Falkovich, G. Electron viscosity, current vortices and negative nonlocal resistance in graphene. Nat. Phys. 12, 672–676 (2016).
Alekseev, P. S. Negative magnetoresistance in viscous flow of twodimensional electrons. Phys. Rev. Lett. 117, 166601 (2016).
Delacrétaz, L. V. & Gromov, A. Transport signatures of the Hall viscosity. Phys. Rev. Lett. 119, 226602 (2017).
Pellegrino, F. M. D., Torre, I. & Polini, M. Nonlocal transport and the Hall viscosity of twodimensional hydrodynamic electron liquids. Phys. Rev. B 96, 195401 (2017).
Read, N. & Rezayi, E. H. Hall viscosity, orbital spin, and geometry: Paired superfluids and quantum Hall systems. Phys. Rev. B 84, 085316 (2011).
Wen, X. G. & Zee, A. Shift and spin vector: new topological quantum numbers for the Hall fluids. Phys. Rev. Lett. 69, 953–956 (1992).
Tokatly, I. V. Magnetoelasticity theory of incompressible quantum Hall liquids. Phys. Rev. B 73, 205340 (2006).
Van Mechelen, T. & Jacob, Z. Quantum gyroelectric effect: photon spin1 quantization in continuum topological bosonic phases. Phys. Rev. A 98, 023842 (2018).
Van Mechelen, T. & Jacob, Z. Viscous MaxwellChernSimons theory for topological electromagnetic phases of matter. Phys. Rev. B 102, 155425 (2020).
Volovik, G. E. The Universe in a Helium Droplet. International Series of Monographs on Physics (OUP Oxford, 2009).
Wang, Z., Qi, X.L. & Zhang, S.C. Topological order parameters for interacting topological insulators. Phys. Rev. Lett. 105, 256803 (2010).
Gurarie, V. Singleparticle Green’s functions and interacting topological insulators. Phys. Rev. B 83, 085426 (2011).
Hirsbrunner, M. R., Philip, T. M. & Gilbert, M. J. Topology and observables of the nonHermitian Chern insulator. Phys. Rev. B 100, 081104 (2019).
Silveirinha, M. G. Chern invariants for continuous media. Phys. Rev. B 92, 125153 (2015).
Lu, L., Joannopoulos, J. D. & Soljačić, M. Topological states in photonic systems. Nat. Phys. 12, 626–629 (2016).
Stone, M. Berry phase and anomalous velocity of Weyl fermions and Maxwell photons. Int. J. Modern Phys. B 30, 1550249 (2016).
Horsley, S. A. R. Indifferent electromagnetic modes: bound states and topology. Phys. Rev. A 100, 053819 (2019).
Yuan, L., Lin, Q., Xiao, M. & Fan, S. Synthetic dimension in photonics. Optica 5, 1396–1405 (2018).
Wang, M. et al. Topologically protected entangled photonic states. Nanophotonics 8, 1327–1335 (2019).
Cerjan, A. et al. Experimental realization of a Weyl exceptional ring. Nat. Photonics 13, 623–628 (2019).
Liu, C., Rybin, M. V., Mao, P., Zhang, S. & Kivshar, Y. Disorderimmune photonics based on mieresonant dielectric metamaterials. Phys. Rev. Lett. 123, 163901 (2019).
Rose, F., Golan, O. & Moroz, S. Hall viscosity and conductivity of twodimensional chiral superconductors. SciPost Phys. 9, 6 (2020).
Zhu, W., Sheng, D. N. & Yang, K. Topological interface between Pfaffian and antiPfaffian order in ν = 5/2 Quantum Hall effect. Phys. Rev. Lett. 125, 146802 (2020).
Hughes, T. L., Leigh, R. G. & Parrikar, O. Torsional anomalies, Hall viscosity, and bulkboundary correspondence in topological states. Phys. Rev. D 88, 025040 (2013).
Varnavides, G., Jermyn, A. S., Anikeeva, P., Felser, C. & Narang, P. Electron hydrodynamics in anisotropic materials. Nat. Commun. 11, 4710 (2020).
Furusawa, T., Fujii, K. & Nishida, Y. Hall viscosity in the A phase of superfluid ^{3}He. Phys. Rev. B 103, 064506 (2021).
Kolomeisky, E. B. & Straley, J. P. Screening and plasma oscillations in an electron gas in the hydrodynamic approximation. Phys. Rev. B 96, 165116 (2017).
Ryu, S., Schnyder, A. P., Furusaki, A. & Ludwig, A. W. W. Topological insulators and superconductors: tenfold way and dimensional hierarchy. New J. Phys. 12, 065010 (2010).
Zhou, Y. & Liu, J. Note on the Green’s function formalism and topological invariants. J. Stat. Mech. 2020, 033101 (2020).
Basov, D. N., Fogler, M. M. & García de Abajo, F. J. Polaritons in van der Waals materials. Science 354, 6309 (2016).
Gusynin, V. P., Sharapov, S. G. & Carbotte, J. P. Sum rules for the optical and Hall conductivity in graphene. Phys. Rev. B 75, 165407 (2007).
Girvin, S. M., MacDonald, A. H. & Platzman, P. M. Magnetoroton theory of collective excitations in the fractional quantum Hall effect. Phys. Rev. B 33, 2481–2494 (1986).
Mechelen, T. V. & Jacob, Z. Photonic Dirac monopoles and skyrmions: spin1 quantization [invited]. Opt. Mater. Express 9, 95–111 (2019).
Hoffmann, M. et al. Antiskyrmions stabilized at interfaces by anisotropic DzyaloshinskiiMoriya interactions. Nat. Commun. 8, 308 (2017).
Wu, L. et al. Quantized Faraday and Kerr rotation and axion electrodynamics of a 3D topological insulator. Science 354, 1124–1127 (2016).
Fetter, A. L. Edge magnetoplasmons in a bounded twodimensional electron fluid. Phys. Rev. B 32, 7676–7684 (1985).
Rothstein, J. P. Slip on superhydrophobic surfaces. Annu. Rev. of Fluid Mech. 42, 89–109 (2010).
Qiu, Z. Q. & Bader, S. D. Surface magnetooptic Kerr effect. Rev. Sci. Instrum. 71, 1243–1255 (2000).
Banerjee, D., Souslov, A., Abanov, A. G. & Vitelli, V. Odd viscosity in chiral active fluids. Nat. Commun. 8, 1573 (2017).
Souslov, A., Dasbiswas, K., Fruchart, M., Vaikuntanathan, S. & Vitelli, V. Topological waves in fluids with odd viscosity. Phys. Rev. Lett. 122, 128001 (2019).
Cohen, R. & Goldstein, M. Hall and dissipative viscosity effects on edge magnetoplasmons. Phys. Rev. B 98, 235103 (2018).
Volkov, V. A. & Mikhailov, S. A. Edge magnetoplasmons—lowfrequency weakly damped excitations in homogeneous twodimensional electron systems. Zhurnal Eksperimentalnoi i Teoreticheskoi Fiziki 94, 217–241 (1988).
Kiselev, E. I. & Schmalian, J. Boundary conditions of viscous electron flow. Phys. Rev. B 99, 035430 (2019).
Halevi, P. & Fuchs, R. Generalised additional boundary condition for nonlocal dielectrics. I. Reflectivity. J. Phys. C 17, 3869–3888 (1984).
Reuter, G. E. H. & Sondheimer, E. H. The theory of the anomalous skin effect in metals. Proc. R. Soc. Lond. Ser. A 195, 336–364 (1948).
Hyväluoma, J. & Harting, J. Slip flow over structured surfaces with entrapped microbubbles. Phys. Rev. Lett. 100, 246001 (2008).
Bal, G. Continuous bulk and interface description of topological insulators. J. Math. Phys. 60, 081506 (2019).
Tauber, C., Delplace, P. & Venaille, A. Anomalous bulkedge correspondence in continuous media. Phys. Rev. Res. 2, 013147 (2020).
Acknowledgements
This research was supported by the Defense Advanced Research Projects Agency (DARPA) Nascent LightMatter Interactions (NLM) Program.
Author information
Authors and Affiliations
Contributions
T.V.M. conceived of the idea and developed the theoretical treatment. W.S. designed the circulator and performed the numerical simulations. Z.J. proposed the experiment, helped interpret the mathematics and supervised the project. All authors contributed to discussions, results and development of the manuscript.
Corresponding author
Ethics declarations
Competing interests
The authors declare no competing interests.
Additional information
Peer review information Nature Communications thanks the anonymous reviewer(s) for their contribution to the peer review of this work. Peer reviewer reports are available.
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
About this article
Cite this article
Van Mechelen, T., Sun, W. & Jacob, Z. Optical Ninvariant of graphene’s topological viscous Hall fluid. Nat Commun 12, 4729 (2021). https://doi.org/10.1038/s41467021250972
Received:
Accepted:
Published:
DOI: https://doi.org/10.1038/s41467021250972
This article is cited by

Topological properties that can be heard
Nature Materials (2022)

Hydrodynamic approach to twodimensional electron systems
La Rivista del Nuovo Cimento (2022)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.