Abstract
Rational design of the catalysts is impressive for sustainable energy conversion. However, there is a grand challenge to engineer active sites at the interface. Herein, hierarchical transition bimetal oxides/sulfides heterostructure arrays interacting two-dimensional MoOx/MoS2 nanosheets attached to one-dimensional NiOx/Ni3S2 nanorods were fabricated by oxidation/hydrogenation-induced surface reconfiguration strategy. The NiMoOx/NiMoS heterostructure array exhibits the overpotentials of 38 mV for hydrogen evolution and 186 mV for oxygen evolution at 10 mA cm−2, even surviving at a large current density of 500 mA cm−2 with long-term stability. Due to optimized adsorption energies and accelerated water splitting kinetics by theory calculations, the assembled two-electrode cell delivers the industrially relevant current densities of 500 and 1000 mA cm−2 at record low cell voltages of 1.60 and 1.66 V with excellent durability. This research provides a promising avenue to enhance the electrocatalytic performance of the catalysts by engineering interfacial active sites toward large-scale water splitting.
Similar content being viewed by others
Introduction
The generation of clean energy from water electrolysis is a feasible solution to overcome the problems of energy issues1. The sustainable alternative for hydrogen generation is electrocatalytic water splitting, involving hydrogen evolution reaction (HER) and oxygen evolution reaction (OER)2. Generally, noble materials, Pt for HER and RuO2 or IrO2 for OER, are typical electrocatalysts. Nevertheless, the practical application is limited by the use of noble materials owing to the scarcity and the high cost. To this end, it is interesting to produce bifunctional materials by the integration of OER and HER catalysts towards water splitting in various media3. To address the challenges, catalyzing HER, OER and overall water splitting have been conducted by extensive catalysts, such as oxides, hydroxides, phosphides, nitrides and chalcogenides4,5,6,7,8,9,10,11. Thus, it is urgently needed to design earth-abundant and low-cost non-noble-metal catalysts for industrial applications.
Among various materials, Mo- and Ni-based sulfides are promising transition-metal electrocatalysts. To improve the performance of these catalysts, various strategies, such as morphology engineering, defect engineering, and heterostructure engineering have been adopted in this field. Architectural nanostructures have been controlled by the synthesis regulation of the electrocatalysts owe to inherent anisotropy and high flexibility5,6,7,8. Inspired by the advantages of the architectures, the integration of different nanostructures can effectively optimize the electrocatalytic performance. For example, MoO3 nanodots supported on MoS2 monolayer, MoNi4 anchored MoO2 cuboids or MoO3-x nanorods and NiS2/N-NiMoO4 nanosheets/nanowires have been produced for the excellent electrocatalytic water splitting12,13,14,15, providing an appealing platform with the hierarchical nanostructures. Apart from morphology engineering, the hybrids can be extensively constructed by use of different transition-metal electrocatalysts through heterostructure engineering, regulating electron transfer and active site as well as the activity owe to the construction of coupling interfaces and the synergistic effect of the heterostructures. For instance, a large number of the heterostructures, such as NiMo/NiMoOx8, Co3O4/Fe0.33Co0.66P16, Ni2P/NiP217, NiFe(OH)x/FeS18, Pt2W/WO319, CuCo/CuCoOx20, Co(OH)2/PANI21, FeOOH/Co/FeOOH22, Co0.85Se/NiFe/graphene23, Ni3N/VN24, NiCu–NiCuN25, have been extensively synthesized for the enhanced electrochemical activities. Typically, sulfides-based heterostructures, such as CoS-doped β-Co(OH)2/MoS2+x26, MoS2/Fe5Ni4S827, MoS2/Ni3S228, NiS2/MoS229, MoS2/Co9S8/Ni3S2/Ni30, and MoS2/(Co,Fe,Ni)9S8 coupled FeCoNi-based arrays31, have been systematically explored for the improved activities of electrochemical water splitting. With regard to transition-metal dichalcogenides, MoS2 and Ni3S2 materials have been substantially explored as HER electrocatalysts32,33,34,35. However, the HER performance of transition metal sulfides is limited by poor charge transport, low active site reactivity, and inefficient electrical contact with the supported catalysts36. Especially, the generation of S–Hads bonds (H atoms adsorption, Hads) on the surface of metal sulfides is beneficial for H adsorption, while it is difficult to conduct the conversion of the Hads to H236,37. However, the OER performance of metal sulfides remains far from satisfactory27,28,29,30,31. Owe to long-time durability as major obstacle, there is less report about the electrocatalysts, delivering large catalytic current densities (e.g., 500 and 1000 mA cm−2) for practical application38,39,40,41. Based on the above-mentioned analysis, it is essential to design the rational heterostructures through the combined regulation of architectural morphology and heterostructures, engineering active sites, optimizing energy adsorption, and accelerating water splitting kinetics towards large-scale electrolysis.
Herein, three-dimensional (3D) NiMoOx/NiMoS heterostructure array is fabricated by surface reconfiguration strategy through oxygen plasma as oxidation treatment and subsequent hydrogenation regulation by use of NiMoS architecture as the precursor, interacting two-dimensional (2D) MoOx/MoS2 nanosheets attached to one-dimensional (1D) NiOx/Ni3S2 nanorods array. As-synthesized NiMoOx/NiMoS array presents the remarkable electrocatalytic performance, achieving the low overpotentials of 38, 89, 174, and 236 mV for HER and 186, 225, 278, and 334 mV for OER at 10, 100, 500, and 1000 mA cm−2, even surviving at large current densities of 100 and 500 mA cm−2 with long-term stability. The remarkable electrocatalytic performance of transition bimetal oxides/sulfides heterostructure array as the industrially promising electrocatalyst is ascribed to not only the simultaneous modulation of component and geometric structure, but also the systematic optimization of charge transfer, abundant electrocatalytic active sites, and exceptionally synergistic effect of the heterostructure interfaces. The turnover frequency (TOF) of NiMoOx/NiMoS array at the overpotential of 100 mV is ~45 times higher than that of NiMoS array. Density functional theory calculations reveal that the coupling interface between NiMoOx and NiMoS optimizes adsorption energies and accelerates water splitting kinetics, thus promoting the electrocatalytic performance. Especially, the assembled two-electrode cell by use of NiMoOx/NiMoS array delivers the industrially required current densities of 500 and 1000 mA cm−2 at the low cell voltages of 1.60 and 1.66 V, along with excellent durability, thus holding great promise for industrial water splitting application.
Results
Synthesis and characterization
The hierarchical NiMoOx/NiMoS array was fabricated by oxidation/hydrogenation-induced surface reconfiguration strategy by use of NiMoS precursor, assembling as two-electrode cell towards industrially electrocatalytic water splitting (Fig. 1 and Supplementary Fig. 1). To determine the crystal structure, X-ray diffraction (XRD) patterns of NiMoS-based arrays are showed (Supplementary Fig. 2). Based on the hydrothermal reaction, the representative peaks of the precursors can be assigned to the planes of MoS2 phase (JCPDS No. 37-1492) and Ni3S2 phase (JCPDS No. 44-1418), confirming the formation of individual MoS2 and Ni3S2 as well as MoS2/Ni3S2 heterostructure as the precursors (Supplementary Fig. 2a). After oxygen plasma as oxidation treatment and subsequent hydrogenation regulation, several MoO3 (JCPDS No.47-1320), MoO2 (JCPDS No. 50-0739), and NiO (JCPDS No.44-1159) phases as well as the mixed MoO3/MoO2/NiO/Ni phases are observed in MoS2, Ni3S2, and MoS2/Ni3S2 (Supplementary Fig. 2b). Thus, all above-mentioned results demonstrate the successful formation of NiOx/Ni3S2, MoOx/MoS2, and NiMoOx/NiMoS heterostructure arrays.
To confirm the geometric morphologies of individual arrays by scanning electron microscope (SEM), as shown in Fig. 2a, d, MoS2 nanosheets as the precursor with an average size over 1 μm are homogeneously supported on the conductive substrate. While the rough surface of Ni3S2 array as the precursor is observed (Supplementary Fig. 3). Interestingly, two-dimensional (2D) MoS2 nanosheets with an average size below 1 μm are attached to one-dimensional (1D) Ni3S2 nanorods array on 3D foam substrate, resulting into the formation of hierarchical MoS2/Ni3S2 (denoted as NiMoS) heterostructure array (Fig. 2b, e). After the oxidation/hydrogenation treatment of NiMoS array, there is no obvious change upon the main morphology for 3D NiMoOx/NiMoS heterostructure array. However, the small size and rough surface of MoS2 nanosheets in NiMoOx/NiMoS array are observed in comparison of MoS2 in NiMoS array (Fig. 2cf). Meanwhile, the energy-dispersive X-ray (EDX) spectra and elemental mapping (Fig. 2 and Supplementary Fig. 4) indicate the molar content of MoOx/MoS2 about 6.1% and the homogeneous element distribution in NiMoOx/NiMoS array. Thus, the above-mentioned analysis indicates the formation of NiMoOx/NiMoS array as 3D integrated architectures.
To check the details of the morphology, transition electron microscope (TEM) and high-resolution TEM observations verify the architectures of NiMoS and NiMoOx/NiMoS heterostructure arrays, indicating that MoS2 and MoOx/MoS2 nanosheets are attached to Ni3S2 and NiOx/Ni3S2 nanorods arrays, respectively (Fig. 3). Compared to MoS2 and Ni3S2 in NiMoS nanostructures, the characteristic lattice fringes of 0.62, 0.33, and 0.246 nm can be assigned to the (002) plane of MoS2, (011) plane of MoO3, and (100) plane of MoO2 and even more, the (101) plane of Ni3S2 and the (112) plane of NiOx can be proven by the lattice fringes of 0.41 and 0.113 nm in NiMoOx/NiMoS heterostructures. Typically, the arrangements of MoOx and NiOx layers are observed on the surface of MoS2 and Ni3S2, indicating the formation of NiMoOx/NiMoS heterostructure array. Moreover, the elemental mappings by high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) confirm the uniform distribution of Ni, Mo, S, and O (Fig. 3 and Supplementary Fig. 5). Therefore, the whole results of SEM and TEM analysis confirm the formation of 3D NiMoOx/NiMoS heterostructure array as the integrated architectures.
To conduct the chemical valences of the heterostructures, X-ray photoelectron spectroscopy (XPS) spectrum has been tested in Fig. 4. With regard to Mo 3d regions, the main peak could be split into two distinct peaks of Mo 3d5/2 (229.1 eV) and Mo 3d3/2 (232.4 eV), indicating the dominance of Mo4+ in NiMoS (Supplementary Fig. 6)8,42. The peaks at 855.2, 861.5, 872.9 and 879.5 eV can be indexed to Ni 2p3/2 and Ni 2p1/2 orbitals as well as two satellites in NiMoS (Supplementary Fig. 6)25. However, the signals at 229.3, 232.4, and 235.5 eV can be indexed to Mo4+ 3d5/2, Mo4+/6+ 3d3/2, and Mo6+ 3d3/2 orbitals, confirming the existence of Mo4+ and Mo6+ in NiMoOx/NiMoS owe to the formation of MoOx26. For Ni 2p orbitals, there is a shift upon the peak positions and the two new peaks at 854.6 and 852.6 eV, demonstrating the existence of Ni–O bonds and metallic Ni0 and the formation of NiOx species in NiMoOx/NiMoS8,25. Typically, the signals at 529.5 and 531.5 eV for O 1s belong to typical metal-oxygen bonds and oxygen vacancies in NiMoOx/NiMoS heterostructure8. With regard to S 2p peaks, the negative shift is observed in NiMoOx/NiMoS with the increasing temperature of thermal treatment, demonstrating the loss of S and the formation of S vacancies43. The similar phenomenon of O 1s and S 2p is observed in MoOx/MoS2 and NiOx/Ni3S2 heterostructures (Supplementary Fig. 7–8). Thus, the combined analysis demonstrates the successful synthesis of hierarchical transition bimetal oxides/sulfides heterostructure array.
Electrocatalytic HER performance
The electrocatalytic performance of various arrays in the three-electrode system was conducted through a linear scan voltammogram (LSV) in 1 M KOH solution at 25 °C. The polarization curves of NiMoOx/NiMoS, MoOx/MoS2, NiOx/Ni3S2, and NiMoS heterostructure arrays are presented in Fig. 5a, together with commercial Pt/C and Ni foam (Supplementary Fig. 9). In comparison of NiMoS (219, 392, and 611 mV), MoOx/MoS2 (163, 282, and 430 mV), NiOx/Ni3S2 (67, 175, and 307 mV), NiMoOx/NiMoS array delivers the current densities of 10, 100, and 500 mA cm−2 at the low overpotentials of 38, 89 and 174 mV, respectively, even requiring a low overpotential of 236 mV at a large current density of 1000 mA cm−2 towards HER (Fig. 5b). It is worth mentioning that NiMoOx/NiMoS array could surpass commercial Pt/C catalyst at the high overpotentials while comparable HER activity at the low potentials. Compared to most reported HER catalysts (Supplementary Table 1), the overpotential of NiMoOx/NiMoS array at a current density of 10 mA cm−2 is smaller than those of MoS2 (170 mV)44, CoFeZr oxides (104 mV)6, CoS-Co(OH)2@MoS2+x (140 mV)26, MoS2/Fe5Ni4S8 (120 mV)27, MoS2/Ni3S2 (110 mV)28, MoS2/Co9S8/Ni3S2 (113 mV)30, and O-CoMoS (97 mV)42, etc. To regulate the capacities of charge transfer and active sites of NiMoS, it is interesting to determine the precise condition of plasma oxidation and hydrogenation treatment (Supplementary Fig. 10), indicating the best oxygen plasma power of 100 W and appropriate hydrogenation temperature of 400 °C of NiMoOx/NiMoS array. To conduct HER kinetic mechanism, the lowest Tafel slope (Fig. 5c), 38 mV per decade of NiMoOx/NiMoS array is obtained in comparison of NiOx/Ni3S2 (65 mV dec−1), MoOx/MoS2 (98 mV dec−1), NiMoS (169 mV dec−1), indicating the rapid HER kinetics of NiMoOx/NiMoS array owe to the advantages of the construction of 3D heterostructured architectures and the introduction of the defects. After the analysis of electrochemical impedance spectroscopy (EIS), the lowest charge transfer resistance of NiMoOx/NiMoS array due to the generation of defective species and metallic Ni is obtained in comparison of NiOx/Ni3S2, MoOx/MoS2, and NiMoS (Supplementary Fig. 10). To explore the intrinsic electrocatalytic performance of each active sites, the turnover frequency (TOF) is calculated (Supplementary Table 2–3). The TOF value of NiMoOx/NiMoS array (1.97 s−1) at the overpotential of 100 mV is ~45 times higher than that of NiMoS array (0.0435 s−1). Moreover, mass activity, 436 A g−1 of NiMoOx/NiMoS array is calculated at the overpotential of 200 mV (Supplementary Fig. 11), which is better than other non-nobel metal electrocatalysts (Supplementary Table 4). Generally, the electrochemically active surface area (ECSA) is regarded as an estimation of active sites and is proportional to the double-layer capacitance (Cdl)45,46,47. The highest Cdl values of NiMoOx/NiMoS array among all catalysts implies the maximum electroactive area (Supplementary Fig. 12). Moreover, the current of NiMoOx/NiMoS and commercial Pt/C supported on Ni plate was normalized to ECSA (Supplementary Figs. 13–16), demonstrating a higher instrinsic activity of NiMoOx/NiMoS catalyst in comparison of commercial Pt/C. Owe to the stability as pivot criterion for practical application, the time-dependent current density curves confirm that there is no obvious change upon the current densities of 100 and 500 mA cm−2 at 0.089 and 0.174 V vs. RHE over 50 h (Fig. 5d). Afterwards, the amount of hydrogen evolution of NiMoOx/NiMoS array is measured in comparison of theoretical quantity (Supplementary Fig. 17), presenting a promising Faradaic efficiency of 99.6 ± 0.3% towards real water splitting into hydrogen. Based on the above-mentioned analysis, the synergistic action of morphology and heterostructure engineering upon NiMoOx/NiMoS array can modulate the unique architectures, optimize the charge transfer and catalytic active sites, and thus improve HER performance.
Electrocatalytic OER performance
In general, the efficiency is always limited by OER as major barrier for overall water splitting. In our system, NiMoOx/NiMoS array exhibits the best OER performance among all arrays, together with commercial IrO2 catalyst and Ni foam (Fig. 6a and Supplementary Fig. 18). In comparison of NiMoS (370, 437, and 526 mV), MoOx/MoS2 (266, 332, and 438 mV), NiOx/Ni3S2 (214, 267, and 366 mV), as-synthesized NiMoOx/NiMoS array presents the low overpotentials of 186, 225, and 278 mV at current densities of 10, 100, and 500 mA cm−2, and delivers a large current density of 1000 mA cm−2 at 334 mV towards OER (Fig. 6b), satisfying the requirements for commercial electrocatalytic application (for example, j ≥ 500 mA cm−2 at η ≤ 300 mV)48,49,50,51. Compared to most reported OER catalysts (Supplementary Table 5), the overpotential of NiMoOx/NiMoS array at 10 mA cm−2 is still lower than those of O-CoMoS (272 mV)42, CoS-Co(OH)2@MoS2+x (380 mV)26, MoS2/Fe5Ni4S8 (204 mV)27, MoS2/Ni3S2 (218 mV)28, and iron-substrate-derived electrocatalyst (269 mV)48, etc. Especially, the influence of oxygen plasma power and hydrogenation temperature upon the OER performance of NiMoOx/NiMoS array is determined (Supplementary Fig. 19), confirming the best plasma power of 100 W and thermal treatment temperature at 400 °C of NiMoOx/NiMoS array. To in-depth understand the OER kinetic mechanism, the lowest Tafel slope, 34 mV per decade of NiMoOx/NiMoS is achieved in comparison of NiOx/Ni3S2 (56 mV dec−1), MoOx/MoS2 (62 mV dec−1), NiMoS (74 mV dec−1), demonstrating the fast OER kinetics of NiMoOx/NiMoS (Fig. 6c). Remarkably, the largest Cdl value of 21.5 mF cm–2 of NiMoOx/NiMoS is obtained by the evaluation of ECSA among all arrays (Supplementary Fig. 20), indicating the production of abundant active sites in NiMoOx/NiMoS array. Especially, the high ECSA of NiMoOx/NiMoS array confirms the advantages of the exposured component and geometric structures of sufficient electrocatalytic active sites. Interestingly, the high-valence Mo and Ni species are obtained in NiMoOx/NiMoS array during the OER process (Supplementary Fig. 24), indicating the possible generation of hydroxyl oxides as the actual surface active sites and thus enhancing the OER activities owe to the synergistic action of 3D architectures and the heterostructures. In particular, NiMoOx/NiMoS array can preserve OER activities at 100 and 500 mA cm−2 with the potentials of 1.455 and 1.508 V vs. RHE over 50 h (Fig. 6d), indicating the fascinating OER stability. Typically, the amount of oxygen evolution of NiMoOx/NiMoS array is measured in comparison of theoretical quantity (Supplementary Fig. 21), presenting OER Faradaic efficiency of 97.5 ± 0.4% owe to the synergistic effect of the morphology and heterostructure engineering.
Electrocatalytic performance for overall water splitting
Inspired by excellent HER and OER performance, NiMoOx/NiMoS array was assembled as cathode and anode in the two-electrode system. Impressively, the robust catalytic performance is achieved by as-synthesized NiMoOx/NiMoS||NiMoOx/NiMoS electrode (Fig. 7a), requiring the low cell voltages of 1.46, 1.62, 1.75, and 1.82 V at 10, 100, 500, and 1000 mA cm−2 in 1 M KOH at 25 °C. In comparison of Ni–Fe–MoN52, Fe0.09Co0.13-NiSe253, NC/CoCu/CoCuOx20, MoS2/Co9S8/Ni3S230, Pt-CoS247, NC/NiCu/NiCuN25, NC/NiMo/NiMoOx8, MoS2/NiS254, O-CoMoS42, N-NiMoO4/NiS215, MoS2/NiS55, P-Co3O456, Ni/Mo2C57, CoNi(OH)x | NiNx58, NiCo2S459, FeOOH60, Ni5P461, NiCo/NiCoOx62, Fe-Ni@NC-CNT63, CoxPO4/CoP64, and commercial Pt/C||IrO2 electrodes (Fig. 7c and Supplementary Table 6), the lower voltage at 10 mA cm−2 is obtained for NiMoOx/NiMoS array. Owe to excellent electrocatalytic performance, the two-electrode cell can also be evaluated by a 1.5 V AAA battery (Supplementary Fig. 22). Based on the analysis of the superaerophobicity by bubble contact tests (Supplementary Fig. 23), the superior bubble contact angle, 151.2° of NiMoOx/NiMoS is obtained, demonstrating that this typical architecture could facilitate the release of the evolved gas bubbles and thus avoid the block of the catalyst active site. To be interesting, the hydrogen and oxygen bubbles escape effectively from the surface of NiMoOx/NiMoS array (Supplementary Movie). Moreover, the industrial environment is employed to explore the potential for industrialization applications. Typically, the record low voltages of 1.60 and 1.66 V of the two-electrode system in 6 M KOH solution at 60 °C are achieved for the industrial current densities of 500 and 1000 mA cm−2, respectively, and it is still better than that of Pt/C||IrO2 couple (Fig. 7b and Supplementary Tabel 7). Compared to the reported electrocatalysts with the large current densities (e.g., 500 and 1000 mA cm−2), such as NiMoN@NiFeN65, nickel-cobalt complexes hybridized MoS266, Ni-P-B/paper49, NiVIr-LDH ||NiVRu-LDH50, phosphorus-doped Fe3O451, graphdiyne-sandwiched layered double-hydroxide nanosheets67, N,S-coordinated Ir nanoclusters embedded on N,S-doped graphene68, Co3Mo/Cu69, and FeP/Ni2P hybrid70, all aforementioned analysis confirm that as-prepared NiMoOx/NiMoS array could be served as promising industrial candidate for overall water splitting. With regard to the operating stability as important metric, this typical two-electrode cell can maintain the excellent electrocatalytic activity at a large current density of 500 mA cm−2 at the voltage of 1.75 V over 500 h without obvious degradation in 1 M KOH solution at 25 °C (Fig. 7d). After HER, there is no obvious change upon the binding energies of various metal ions (Supplementary Fig. 24). However, the positive shift of two peaks located at 856.3 and 874.1 eV is observed in the XPS of Ni 2p, demonstrating that the oxidation of Ni2+ to high valence state of Ni3+, alone with the existence of new peak at 869.05 eV (Supplementary Fig. 24), thus indicating the formation of hydroxides and oxyhydroxides as the real active sites during OER process30,31,32,33,34. Although the hydroxides and oxyhydroxides are formed on the surface of NiMoOx/NiMoS array, there is no apparent change upon the morphology of the heterostructures (Supplementary Fig. 25), indicating the superior stability. Based on the above analysis, it is proven that NiMoOx/NiMoS array is excellent and stable system for overall water splitting, presenting the industrial hope.
First-principles calculations
To explore the original relationship between the intrinsically catalytic activity and the electronic and atomic structures of the interface of NiMoOx/NiMoS, density functional theory calculations were performed to conduct the Gibbs free energies of every step in HER and OER (Supplementary Fig. 26–33). The hydrogen absorption energy (ΔGH*) is generally considered as the key descriptor for evaluating the performance of HER71. The sulfur sites of NiOx/Ni3S2 and MoOx/MoS2 exhibit much lower ΔGH* relative to that of Ni3S2 and MoS2 (Fig. 8a and Supplementary Fig. 29–32), indicating that the integration of the oxides and sulfides enables the favorable H* adsorption and the tremendous decrement of thermodynamic barriers for hydrogen production. Especially, the oxidation/hydrogenation-induced surface reconfiguration results into the fabrication of NiMoOx/NiMoS heterostructure. The sulfur species serve as the distinctive active sites for the optimized hydrogen adsorption with nearly zero ΔGH* (0.003 eV), in comparison of NiOx/Ni3S2 (ΔGH* = 0.074 eV) and MoOx/MoS2 (ΔGH* = 0.422 eV). Since oxygen-free NiMoS shows much more negative ΔGH* (–0.284 eV) comparing to NiMoOx/NiMoS, it is hypothesized that the oxide species of the unique multi-interfaces may avoid the excessively strong adsorption of H* and bring about the facile intermediates desorption. Theoretically, water oxidation in alkaline medium involves four concerted proton-electron transfer steps72. The absorption configurations and calculated free energy profiles of OER steps are presented (Figs. 8b-8d). Obviously, the potential rate-determining step (PDS) of NiMoS heterostructures is the third electrochemical step from *O to *OOH with an energy barrier of 1.80 eV. The *OOH species on NiMoOx/NiMoS heterostructures are greatly stabilized and overpotential is largely reduced to 0.85 V with the PDS of forming molecule O2. In comparison of NiMoOx/NiMoS, it is of noted that the oxide species in NiOx/Ni3S2 and MoOx/MoS2 heterointerfaces have small evident impact on the decrement of overpotential (Supplementary Fig. 29–32). Therefore, the multi-interfaces of bimetal oxides/sulfides heterostructures are indispensible for the favorable stabilization of intermediates and accelerated electrochemical kinetics. In order to undestand the charge transfer between the NiMoOx/NiMoS interface, charge density difference was performed (Supplementary Fig. 33). It is clear that a remarkable charge transfer across the interface, facilitates the fast electron transfer during the electrocatalytic process. Overall, the theory simulations and experiments demonstrate that the excellent OER and HER activities are facilitated by the synergetic effect of the oxidation/hydrogenation-induced surface reconfiguration.
In this case, the robust electrocatalytic activity is firstly ascribed to 3D hierarchical heterostructures of NiMoOx/NiMoS array owe to the excellent mass transport and gas permeability. Secondly, the constructed interfaces among various heterostructures not only produce together the activities of different materials, but also facilitate the charge transfer and brings exceptionally synergistic effect of typical catalysts by oxidation/hydrogenation-induced surface reconfiguration strategy. Thirdly, the generation of defective species in hierarchical heterostructures could optimize electric conductivity and generate abundant active sites, confirming by low resistances and large ECSAs. Finally, the synergistic effect of the morphology and heterostructure engineering in NiMoOx/NiMoS array promotes the generation of abundant active sites by engineering active sites, optimizing adsorption energies, and accelerating water splitting kinetics. All advantages promote the robust catalytic performance of NiMoOx/NiMoS array as a typical catalyst, offering a prospective solution of hierarchical electrocatalysts for practical water splitting applications.
Discussion
In summary, hierarchical transition bimetal oxides/sulfides array was fabricated by oxidation/hydrogenation-induced surface reconfiguration strategy by use of NiMoS architectures as the precursor, interacting two-dimensional MoOx/MoS2 nanosheets attached to one-dimensional NiOx/Ni3S2 nanorods array. To optimize the electrocatalytic performance, the influence of oxygen plasma power and hydrogenation temperature upon HER and OER performance of NiMoOx/NiMoS array was explored, confirming the best plasma power of 100 W and appropriate thermal treatment temperature at 400 °C. Benefiting from heterostructure engineering, as-synthesized NiMoOx/NiMoS array presents the remarkable electrocatalytic performance, achieving low overpotentials of 38, 89, 174, and 236 mV for HER and 186, 225, 278, and 334 mV for OER at 10, 100, 500 and 1000 mA cm−2, even surviving at large current density of 100 and 500 mA cm−2 with long-term stability. The extraordinarily enhanced electrocatalytic performance of transition bimetal oxides/sulfides heterostructure array as the typical model is ascribed to not only the simultaneous modulation of component and geometric structure, but also the systematic optimization of charge transfer, abundant electrocatalytic active sites and exceptionally synergistic effect of heterostructure interfaces. Density functional theory calculations reveal that the coupling interface between NiMoOx and NiMoS optimizes adsorption energies and accelerates water splitting kinetics, thus promoting the catalytic performance. Especially, the assembled two-electrode cell by use of NiMoOx/NiMoS array delivers the industrially required current densities of 500 and 1000 mA cm−2 at record low cell voltages of 1.60 and 1.66 V, along with excellent durability, outperforming most of transition metal-based bifunctional electrocatalysts reported to date. Given hierarchical transition heterostructures array as typical model, this work could open up the avenues to the development of excellent electrocatalysts by engineering active sites for large-scale energy conversion applications.
Methods
Materials
Ni foam was purchased from Suzhou Jiashide Metal Foam Co. Ltd. Ni(NO3)2·6H2O, (NH4)Mo7O24·4H2O, thiourea and KOH was purchased from Aladdin. Pt/C (20 wt% Pt on Vulcan XC-72R) and Nafion (5 wt%) were purchased from Sigma-Aldrich. All chemicals were used as received without further purification. The water used throughout all experiments was purified through a Millipore system.
Fabrication of NiMoOx/NiMoS heterostructure array
0.07 M Ni(NO3)2·6H2O, 0.01 M (NH4)Mo7O24·4H2O and 0.30 M thiourea were dissolved into 15 mL deionized water and stirred for 10 min under room temperature. Then the solution was transferred to a 25 mL Teflon-lined steel autoclave with nickel foam. After hydrothermal reaction at 200 °C for 24 h, NiMoS precursor was obtained through washing with deionized water and then dried in an oven at 60 °C. As-obtained NiMoS precursors were irradiated by RF plasma under an oxygen flow (RF power, 50~150 W) for the oxidation treatment. Afterward the arrays were annealed up to 300–500 °C in H2/Ar (0.05/0.95) for the typical hydrogenation regulation, thus resulting into the synthesis of NiMoOx/NiMoS heterostructure array by oxidation/hydrogenation-induced surface reconfiguration strategy. In comparison, as-obtained NiOx/Ni3S2 and MoOx/MoS2 heterostructure arrays were synthesized in parallel by the same procedure as that of NiMoOx/NiMoS array expect for in absence of (NH4)Mo7O24·4H2O or Ni(NO3)2·6H2O in hydrothermal reaction.
Structural characterization
Powder XRD patterns of the products were tested with X-ray diffractometer (Japan Rigaku Rotaflex) by Cu Kα radiation (λ = 1.5418 nm, 40 kV, 40 mA) at room temperature. SEM images of the products were captured by a field-emission scanning electron microscope (SEM, FEI Nova Nano SEM 450). TEM images of the products were performed on transmission electron microscopy (TEM, FEI TF30). The chemical states of the samples were determined by XPS in a Thermo VG ESCALAB250 surface analysis system. The shift of binding energy due to relative surface charging was corrected using the C 1 s level at 284.6 eV as an internal standard.
Electrochemical measurements
The electrocatalytic HER and OER performance of different electrocatalysts (1 cm2) were evaluated using a typical three-electrode system in N2 and O2-saturated 1 M KOH electrolyte, respectively. All polarization curves at 1 mV s−1 were corrected with iR compensation. The mass loading of NiMoS-based electrocatalysts was tested according to the mass difference. Commercial IrO2 or 20 wt% Pt/C was dispersed in ethanol solution with Nafion and then the ink was dropped by a micropipettor on Ni foam. The EIS tests were measured by AC impedance spectroscopy at the frequency ranges 106 to 0.1 Hz. According to the Nernst equation (ERHE = EHg/HgO + 0.059 pH + 0.098), where ERHE was the potential vs. a reversible hydrogen potential, EHg/HgO was the potential vs. Hg/HgO electrode, and pH was the pH value of electrolyte. To determination of Faradaic efficiency, the Faradaic efficiency of HER or OER catalyst is defined as the ratio of the amount of experimentally determined hydrogen or oxygen to that of the theoretically expected hydrogen or oxygen from the HER or OER reaction in 1 M KOH aqueous solution by use of an online gas chromatography system (GC, Techcomp GC 7890 T, Ar carrier gas, Thermo Conductivity Detector). As for the theoretical value, we assumed that 100% current efficiency during the reaction, which means only the HER or OER process was occurring at the working electrode. The theoretically expected amount of hydrogen or oxygen was then calculated by applying the Faraday law, which states that the passage of 96485.4 C causes 1 equivalent of reaction.
First-principle calculations
Density functional theory calculations were carried out by the Vienna ab initio simulation package (VASP), using the planewave basis with an energy cutoff of 400 eV, the projector augmented wave pseudopotentials, and the generalized gradient approximation parameterized by Perdew, Burke, and Ernzerhof (GGA-PBE) for exchange-correlation functional73. The Brillouin zones of the supercells were sampled by 4 × 4 × 1 uniform k point mesh. With fixed cell parameters, the model structures were fully optimized using the convergence criteria of 10−5 eV for the electronic energy and 10−2 eV/Å for the forces on each atom. The supercells dimension in x and y was 11.598 Å and 12.243 Å, respectively. The vacuum region in the z direction was adopted large than 15 Å so that the spurious interactions of neighboring models are negligible. Then O atom was used to replace the S atom on the edge of MoS2 and the surface of Ni3S2 and the interface of MoS2 and Ni3S2, respectively74. To simulate the edge, the surface and interface incorporate with the oxides. Both spin-polarized and spin-unpolarized computations were performed. The computational results show that both NiMoS and NiMoOx/NiMoS are magnetic. In addition, we applied the DFT-D3 (BJ) method to evaluate the van der Waals (vdW) effect in all calculations.
The Gibbs free energy of the intermediates for HER and OER process, that is, H, OH, O, and OOH, can be calculated as75,76
where Eads is the adsorption energy of intermediate, ΔEZPE is the zero point energy difference between the adsorption state and gas state, T is the temperature, and ΔS is the entropy various between the adsorption and gas phase. For adsorbates, EZPE and S are obtained from vibrational frequencies calculations with harmonic approximation and contributions from the slabs are neglected, whereas for molecules these values are taken from NIST-JANAF thermochemical Tables77. The contributions are listed (Supplementary Table 8). Usually, the vibration entropy of hydrogen adsorption on the substrate is small, the entropy of hydrogen adsorption is ΔS ≈ −1/2S°, where S0 is the entropy of H2 in the gas phase at the standard conditions. The corrected for free energy equation was defined by
The intermediates adsorption energy Eads for *H, *OH, *O, and *OOH can be used as DFT ground state energy calculated as
The OER process in alkaline medium generally occur through the following steps:
where * denotes adsorption active site on the substrate.
The overpotential η is defined as
Data availability
The data that support the findings of this work are available from the corresponding author upon reasonable request.
References
Jiao, Y. et al. Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions. Chem. Soc. Rev. 44, 2060–2086 (2015).
Xia, Z. & Guo, S. Strain engineering of metal-based nanomaterials for energy electrocatalysis. Chem. Soc. Rev. 48, 3265–3278 (2019).
Wei, C. et al. Approaches for measuring the surface areas of metal oxide electrocatalysts for determining their intrinsic electrocatalytic activity. Chem. Soc. Rev. 48, 2518–2534 (2019).
Zou, X. & Zhang, Y. Noble metal-free hydrogen evolution catalysts for water splitting. Chem. Soc. Rev. 44, 5148–5180 (2015).
Pi, Y. et al. Trimetallic oxyhydroxide coralloids for efficient oxygen evolution electrocatalysis. Angew. Chem. Int. Ed. 56, 4502–4506 (2017).
Huang, L. et al. Zirconium-regulation-induced bifunctionality in 3D cobalt-iron oxide nanosheets for overall water splitting. Adv. Mater. 31, 1901439 (2019).
Hao, S. et al. NiCoMo hydroxide nanosheet arrays synthesized via chloride corrosion for overall water splitting. ACS Energy Lett. 4, 952–959 (2019).
Hou, J. et al. Active sites intercalated ultrathin carbon sheath on nanowire arrays as integrated core-shell architecture: highly efficient and durable electrocatalysts for overall water splitting. Small 13, 1702018 (2017).
Yang, L. et al. Efficient oxygen evolution electrocatalysis in acid by a perovskite with face-sharing IrO6 octahedral dimmers. Nat. Commun. 9, 5236 (2018).
Chen, H. et al. Promoting subordinate, efficient ruthenium sites with interstitial silicon for Pt-Like electrocatalytic activity. Angew. Chem. Int. Ed. 58, 11409 (2019).
Liang, X. et al. Activating inert, nonprecious perovskites with iridium dopants for efficient oxygen evolution reaction under acidic conditions. Angew. Chem. Int. Ed. 58, 17631 (2019).
Huang, L. B. et al. Self-limited on-site conversion of MoO3 nanodots into vertically aligned ultrasmall monolayer MoS2 for efficient hydrogen evolution. Adv. Energy Mater. 8, 1800734 (2018).
Zhang, J. et al. Efficient hydrogen production on MoNi4 electrocatalysts with fast water dissociation kinetics. Nat. Commun. 8, 15437 (2017).
Chen, Y. Y. et al. Self-templated fabrication of MoNi4/MoO3-x nanorod arrays with dual active components for highly efficient hydrogen evolution. Adv. Mater. 29, 1703311 (2017).
An, L. et al. Epitaxial heterogeneous interfaces on N-NiMoO4/NiS2 nanowires/nanosheets to boost hydrogen and oxygen production for overall water splitting. Adv. Funct. Mater. 29, 1805298 (2019).
Zhang, X. et al. Co3O4/Fe0.33Co0.66P interface nanowire for enhancing water oxidation catalysis at high current density. Adv. Mater. 30, 1803551 (2018).
Liu, T. et al. Interfacial electron transfer of Ni2P-NiP2 polymorphs inducing enhanced electrochemical properties. Adv. Mater. 30, 1803590 (2018).
Niu, S. et al. Autogenous growth of hierarchical NiFe(OH)x/FeS nanosheet‐on‐microsheet arrays for synergistically enhanced high‐output water oxidation. Adv. Funct. Mater. 29, 1902180 (2019).
Peng, Y. W. et al. Polyoxometalate‐derived ultrasmall Pt2W/WO3 heterostructure outperforms platinum for large‐current‐density H2 evolution. Adv. Energy Mater. 9, 1900597 (2019).
Hou, J. et al. Promoting active sites in core-shell nanowire array as Mott-Schottky electrocatalysts for efficient and stable overall water splitting. Adv. Funct. Mater. 28, 1704447 (2018).
Feng, J. X. et al. Co(OH)2@PANI hybrid nanosheets with 3D networks as high-performance electrocatalysts for hydrogen evolution reaction. Adv. Mater. 27, 7051–7057 (2015).
Feng, J. X. et al. FeOOH/Co/FeOOH hybrid nanotube arrays as high-performance electrocatalysts for the oxygen evolution reaction. Angew. Chem. Int. Ed. 55, 3694–3698 (2016).
Lei, C. et al. Efficient alkaline hydrogen evolution on atomically dispersed Ni–Nx species anchored porous carbon with embedded Ni nanoparticles by accelerating water dissociation kinetics. Energy Environ. Sci. 12, 149–156 (2019).
Yan, H. et al. Anion-modulated HER and OER activities of 3D Ni-V-based interstitial compound heterojunctions for high-efficiency and stable overall water splitting. Adv. Mater. 31, 1901174 (2019).
Hou, J. et al. Electrical behavior and electron transfer modulation of nickel-copper nanoalloys confined in nickel-copper nitrides nanowires array encapsulated in nitrogen-doped carbon framework as robust bifunctional electrocatalyst for overall water splitting. Adv. Funct. Mater. 28, 1803278 (2018).
Yoon, T. & Kim, K. S. One-step synthesis of CoS-Doped β-Co(OH)2@amorphous MoS2+x hybrid catalyst grown on nickel foam for high-performance electrochemical overall water splitting. Adv. Funct. Mater. 26, 7386–7393 (2016).
Wu, Y. et al. Coupling interface constructions of MoS2/Fe5Ni4S8 heterostructures for efficient electrochemical water splitting. Adv. Mater. 30, 1803151 (2018).
Zhang, J. et al. Interface engineering of MoS2/Ni3S2 heterostructures for highly enhanced electrochemical overall-water-splitting activity. Angew. Chem. Int. Ed. 55, 6702–6707 (2016).
An, T. et al. Interlaced NiS2–MoS2 nanoflake-nanowires as efficient hydrogen evolution electrocatalysts in basic solutions. J. Mater. Chem. A 4, 13439–13443 (2016).
Yang, Y. et al. Hierarchical nanoassembly of MoS2/Co9S8/Ni3S2/Ni as a highly efficient electrocatalyst for overall water splitting in a wide pH range. J. Am. Chem. Soc. 141, 10417–10430 (2019).
Li, H. et al. Systematic design of superaerophobic nanotube-array electrode comprised of transition-metal sulfides for overall water splitting. Nat. Commun. 9, 2452 (2018).
Wang, X. et al. Single-atom vacancy defect to trigger high-efficiency hydrogen evolution of MoS2. J. Am. Chem. Soc. 142, 4298 (2020).
Luo, Z. et al. Reactant friendly hydrogen evolution interface based on di-anionic MoS2 surface. Nat. Commun. 11, 1116 (2020).
He, W. et al. Fluorine-anion-modulated electron structure of nickel sulfide nanosheet arrays for alkaline hydrogen evolution. ACS Energy Lett. 4, 2905 (2019).
Feng, L. et al. High-index faceted Ni3S2 nanosheet arrays as highly active and ultrastable electrocatalysts for water splitting. J. Am. Chem. Soc. 137, 14023 (2015).
Zhu, H. et al. When cubic cobalt sulfide meets layered molybdenum disulfide: A core–shell system toward synergetic electrocatalytic water splitting. Adv. Mater. 27, 4752 (2015).
Feng, J. et al. Efficient hydrogen evolution on Cu nanodots-decorated Ni3S2 nanotubes by optimizing atomic hydrogen adsorption and desorption. J. Am. Chem. Soc. 140, 610 (2018).
Chen, D. et al. Preferential cation vacancies in perovskite hydroxide for the oxygen evolution reaction. Angew. Chem. Int. Ed. 57, 8691–8696 (2018).
Xiao, Z. et al. Filling the oxygen vacancies in Co3O4 with phosphorus: an ultra-efficient electrocatalyst for overall water splitting. Energy Environ. Sci. 10, 2563–2569 (2017).
Wang, Y. et al. 3D carbon electrocatalysts in situ constructed by defect-rich nanosheets and polyhedrons from NaCl-sealed zeolitic imidazolate frameworks. Adv. Funct. Mater. 28, 1705356 (2018).
Smith, R. et al. Photochemical route for accessing amorphous metal oxide materials for water oxidation catalysis. Science 340, 60–63 (2013).
Hou, J. et al. Vertically aligned oxygenated-CoS2–MoS2 heteronanosheet architecture from polyoxometalate for efficient and stable overall water splitting. ACS Catal. 8, 4612–4621 (2018).
Meng, L. et al. Simultaneous manipulation of O-doping and metal vacancy in atomically thin Zn10In16S34 nanosheet arrays toward improved photoelectrochemical performance. Angew. Chem. Int. Ed. 57, 16882–16887 (2018).
Li, H. et al. Activating and optimizing MoS2 basal planes for hydrogen evolution through the formation of strained sulphur vacancies. Nat. Mater. 15, 48 (2015).
Kibsgaard, J. & Jaramillo, T. F. Molybdenum phosphosulfide: An active, acid-Stable, earth-abundant catalyst for the hydrogen evolution reaction. Angew. Chem. Int. Ed. 53, 14433 (2014).
Kibsgaard, J. et al. Designing an improved transition metal phosphide catalyst for hydrogen evolution using experimental and theoretical trends. Energy Environ. Sci. 8, 3022 (2015).
Han, X. et al. Ultrafine Pt nanoparticle-decorated pyrite-type CoS2 nanosheet arrays coated on carbon cloth as a bifunctional electrode for overall water splitting. Adv. Energy Mater. 8, 1800935 (2018).
Liu, Y. et al. Corrosion engineering towards efficient oxygen evolution electrodes with stable catalytic activity for over 6000 hours. Nat. Commun. 9, 2609 (2018).
Hao, W. et al. Fabrication of practical catalytic electrodes using insulating and eco-friendly substrates for overall water splitting. Energy Environ. Sci. 13, 102–110 (2020).
Wang, D. et al. Atomic and electronic modulation of self-supported nickel-vanadium layered double hydroxide to accelerate water splitting kinetics. Nat. Commun. 10, 3899 (2019).
Zhang, J. et al. Modulation of inverse spinel Fe3O4 by phosphorus doping as an industrially promising electrocatalyst for hydrogen evolution. Adv. Mater. 31, 1905107 (2019).
Zhu, C. et al. Fe-Ni-Mo nitride porous nanotubes for full water splitting and Zn-air batteries. Adv. Energy Mater. 8, 1802327 (2018).
Sun, Y. et al. Strong electronic interaction in dual-cation-incorporated NiSe2 nanosheets with lattice distortion for highly efficient overall water splitting. Adv. Mater. 30, 1802121 (2018).
Lin, J. et al. Defect-rich heterogeneous MoS2/NiS2 nanosheets electrocatalysts for efficient overall water splitting. Adv. Sci. 6, 1900246 (2019).
Zhai, Z. et al. Dimensional construction and morphological tuning of heterogeneous MoS2/NiS electrocatalysts for efficient overall water splitting. J. Mater. Chem. A 6, 9833–9838 (2018).
Wang, Z. et al. Phosphorus-doped Co3O4 nanowire array: a highly efficient bifunctional electrocatalyst for overall water splitting. ACS Catal. 8, 2236–2241 (2018).
Li, M. et al. Ni strongly coupled with Mo2C encapsulated in nitrogen-doped carbon nanofibers as robust bifunctional catalyst for overall water splitting. Adv. Energy Mater. 9, 1803185 (2019).
Li, S. et al. Co-Ni-based nanotubes/nanosheets as efficient water splitting electrocatalysts. Adv. Energy Mater. 6, 1501661 (2016).
Sivanantham, A., Ganesan, P. & Shanmugam, S. Hierarchical NiCo2S4 nanowire arrays supported on Ni foam: an efficient and durable bifunctional electrocatalyst for oxygen and hydrogen evolution reactions. Adv. Funct. Mater. 26, 4661–4672 (2016).
Liu, B. et al. Iron vacancies induced bifunctionality in ultrathin feroxyhyte nanosheets for overall water splitting. Adv. Mater. 30, 1803144 (2018).
Ledendecker, M. et al. The synthesis of nanostructured Ni5P4 films and their use as a non-noble bifunctional electrocatalyst for full water splitting. Angew. Chem. Int. Ed. 54, 12361–12365 (2015).
Yan, X. et al. From water oxidation to reduction: transformation from NixCo3-xO4 nanowires to NiCo/NiCoOx heterostructures. ACS Appl. Mater. Interfaces 8, 3208–3214 (2016).
Zhao, X. et al. Bifunctional electrocatalysts for overall water splitting from an iron/nickel-based bimetallic metal-organic framework/dicyandiamide composite. Angew. Chem. Int. Ed. 57, 8921–8926 (2018).
Yang, Y. et al. Porous cobalt-based thin film as a bifunctional catalyst for hydrogen generation and oxygen generation. Adv. Mater. 27, 3175–3180 (2015).
Yu, L. et al. Non-noble metal-nitride based electrocatalysts for high-performance alkaline seawater electrolysis. Nat. Commun. 10, 5106 (2019).
Li, H. et al. Amorphous nickel-cobalt complexes hybridized with 1T-phase molybdenum disulfide via hydrazineinduced phase transformation for water splitting. Nat. Commun. 8, 15377 (2019).
Hui, L. Overall water splitting by graphdiyne-exfoliated and -sandwiched layered double-hydroxide nanosheet arrays. Nat. Commun. 9, 5309 (2018).
Wang, Q. et al. Coordination engineering of iridium nanocluster bifunctional electrocatalyst for highly efficient and pH-universal overall water splitting. Nat. Commun. 11, 4246 (2020).
Shi, H. et al. Spontaneously separated intermetallic Co3Mo from nanoporous copper as versatile electrocatalysts for highly efficient water splitting. Nat. Commun. 11, 2940 (2020).
Yu, F. et al. High-performance bifunctional porous non-noble metal phosphide catalyst for overall water splitting. Nat. Commun. 9, 2551 (2018).
Nørskov, J. K. et al. Trends in the exchange current for hydrogen evolution. J. Electrochem. Soc. 152, J23–J26 (2005).
Koper, M. T. M. Theory of multiple proton–electron transfer reactions and its implications for electrocatalysis. Chem. Sci. 4, 2710–2723 (2013).
Perdew, J. P., Burke, K. & Ernzerhof, M. Generalized gradient approximation made simple. Phys. Rev. Lett. 77, 3865 (1996).
Peng, L. et al. Rationally design of monometallic NiO-Ni3S2/NF heteronanosheets as bifunctional electrocatalysts for overall water splitting. J. Catal. 369, 345–351 (2019).
Zhang, B. et al. Integrating Rh species with NiFe-layered double hydroxide for overall water splitting. Nano Lett. 20, 136–144 (2020).
Rossmeisl, J., Logadottir, A. & Nørskov, J. K. Electrolysis of water on (oxidized) metal surfaces. Chem. Phys. 319, 178–184 (2005).
NIST-JANAF Thermochemical Tables. https://janaf.nist.gov/.
Acknowledgements
This work was supported by National Natural Science Foundation of China (Nos. 21972015, 51672034), Young top talents project of Liaoning Province (No. XLYC1907147), Joint Research Fund Liaoning-Shenyang National Laboratory for Materials Science (No. 2019JH3/30100003), the Fundamental Research Funds for the Central Universities (No. DUT20TD06), the Swedish Research Council, and the K&A Wallenberg Foundation.
Author information
Authors and Affiliations
Contributions
J.H. supervised this study. J.H., P.Z., and Y.W. conceived the idea. P.Z. and Y.W. planned and carried out the experiments, collected, and analyzed the experimental data. S.C. performed SEM and TEM characterizations. Y.Z. and J.G. conducted theoretical calculations. P.Z., Y.W., and J.H. wrote the paper. All the authors have discussed the results and wrote the paper together.
Corresponding author
Ethics declarations
Competing interests
The authors declare no competing interests.
Additional information
Peer review information Nature Communications thanks Fangyi Cheng, Batyr Garlyyev, and other, anonymous, reviewers for their contributions to the peer review of this work. Peer review reports are available.
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary information
Rights and permissions
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
About this article
Cite this article
Zhai, P., Zhang, Y., Wu, Y. et al. Engineering active sites on hierarchical transition bimetal oxides/sulfides heterostructure array enabling robust overall water splitting. Nat Commun 11, 5462 (2020). https://doi.org/10.1038/s41467-020-19214-w
Received:
Accepted:
Published:
DOI: https://doi.org/10.1038/s41467-020-19214-w
This article is cited by
-
Designing multi-heterogeneous interfaces of Ni-MoS2@NiS2@Ni3S2 hybrid for hydrogen evolution
Nano Research (2024)
-
Synthesis and Characterization of NiMoS/TiMg and NiWS/TiMg Nanocatalysts and Their Application in the Hydrodesulfurization of Dibenzothiophene
Topics in Catalysis (2024)
-
Enhanced hydrogen evolution performance by 3D ordered macroporous Ru-CoP@NC electrocatalysts
Rare Metals (2024)
-
Modulated noble metal/2D MOF heterostructures for improved hydrogen storage of MgH2
Rare Metals (2024)
-
Understanding the sulphur-oxygen exchange process of metal sulphides prior to oxygen evolution reaction
Nature Communications (2023)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.