Efficient generation of hydrogen from water-splitting is an underpinning chemistry to realize the hydrogen economy. Low cost, transition metals such as nickel and iron-based oxides/hydroxides have been regarded as promising catalysts for the oxygen evolution reaction in alkaline media with overpotentials as low as ~200 mV to achieve 10 mA cm−2, however, they are generally unsuitable for the hydrogen evolution reaction. Herein, we show a Janus nanoparticle catalyst with a nickel–iron oxide interface and multi-site functionality for a highly efficient hydrogen evolution reaction with a comparable performance to the benchmark platinum on carbon catalyst. Density functional theory calculations reveal that the hydrogen evolution reaction catalytic activity of the nanoparticle is induced by the strong electronic coupling effect between the iron oxide and the nickel at the interface. Remarkably, the catalyst also exhibits extraordinary oxygen evolution reaction activity, enabling an active and stable bi-functional catalyst for whole cell water-splitting with, to the best of our knowledge, the highest energy efficiency (83.7%) reported to date.
Electrochemical water-splitting has been considered as one of the most promising approaches to store renewable electricity in the form of hydrogen fuel1. Hydrogen can be generated in a water electrolyzer consisting of a hydrogen evolution reaction (HER) cathode and an oxygen evolution reaction (OER) anode2,3. However, due to the distinctly different catalytic mechanisms, active HER catalysts are often found to be poor OER catalysts, and vice versa4,5. The current benchmark electrolyzer utilizes Pt-based cathode and RuO2/IrO2 anodes to expedite HER and OER, respectively6,7. From a commercialization point-of-view, it is not only the significant cost of noble metal elements that creates economic pressure but also the additional cost generated due to the complications of producing different cathode–anode materials and possible cross-contaminations8. Hence the development of a universally active water-splitting catalyst based on Earth-abundant materials is of key interest and a significant innovation9.
Recent progress in the development of Earth-abundant-based electrode materials for OER has revealed that Ni and Fe mixed oxides/hydroxides system is inherently active in alkaline media, comparable to that of RuO2/IrO2-based electrocatalysts10,11,12. To this end, several strategies such as nanosizing, heteroatoms-doping, surface engineering, vacancy engineering, and carbon nanomaterials coupling have been demonstrated to improve the OER catalytic performance11,13,14,15,16. However, Ni–Fe-based alloys and oxide/hydroxide are not good cathode catalysts for HER, exhibiting sluggish kinetics at the oxides surface17,18. It is known that most of the Earth-abundant transition metals (M=Ni, Co, Fe, Mo, etc.) bind to H+ either too strongly or too weakly which results in poor HER activities19. As a result, Pt-based catalysts (e.g. Pt/C) remain the primary cathode material option to achieve extremely low overpotentials and large current densities20.
Significant recent effort has been made in the development of Earth-abundant transition metal chalcogenides and pnictogenides that exhibit bi-functional activity towards both HER and OER21,22,23,24,25,26. It is established that the modification of transition metal with electronegative chalcogens/pnictogens (X=N, P, S, and Se) can generate localized negative charges within the M–X surface structures which favors the initial adsorption of H+ (acidic) or H2O (alkaline), and near-surface electronic structure modulation, resulting in weakened M–H bond and lowered HER energy barriers27,28,29,30. However, OER at these materials normally occurs at the high valence metal active sites formed in operando during anodic polarization31,32. This anodic process inevitably leads to oxidative corrosion and restructuring of the M–X materials32,33,34. Concomitantly, the HER catalytic activity of the M–X materials degrades eventually due to the corrosion-induced compositional and structural changes. This issue is exacerbated if the electrolyzer is powered by intermittent renewable energy such as solar or wind, where electrode degradation is accelerated as a result of depolarization and reversed current induced by frequent power interruptions and shut-downs35.
Hence, the development of low cost and robust catalysts with intrinsic active sites that are capable of catalyzing distinctly different HER and OER processes is highly challenging but imperative to realize efficient and sustained intermittent water-splitting. A common method of achieving bi-functional catalyst is through the design of catalysts that exhibit multiple active sites or multi-site functionalities. One approach is the adoption of Janus particle design, a term coined Casagrande et al. in ref. 36, to describe an asymmetric particle which surface exhibit distinct composition/physical properties and therefore exhibits a distinct interface. Furthermore, it is also widely accepted that the creation of strongly coupled interface could benefits electrocatalysis due to the modulated electronic structure of the material37.
Herein, we show a Janus Ni–Fe nanoparticle (denoted Ni–Fe NP) exhibiting a Ni metal domain interconnected to a γ-Fe2O3, creating a heterojunction/interface (Fig. 1). Density functional theory (DFT) calculations indicate that the Ni–O–Fe bridge at Ni-γ-Fe2O3 interface modifies the Gibbs free energy of the adsorption of the intermediate H atoms (ΔGH*), thereby further promoting the performance of HER catalysis. As a result, the Ni–Fe NPs exhibit extraordinary HER catalytic activity, comparable to that of the benchmark Pt/C catalyst. Intriguingly, the overpotential for OER is also lowered due to the multi-site functionalities created at the interface as previously proposed by Nørskov and co-workers38. Through the combination of physical and electrochemical characterization methods, we have demonstrated that the Ni–Fe NPs exhibit extraordinary physical and electrochemical stability for both HER and OER processes.
Important to this catalyst design is the synthesis of monodispersed Ni–Fe nanoparticles with controlled composition and very small size so that iron oxides (γ-Fe2O3) are formed adjacent to metallic Ni, and abundant and stable interfaces are available for catalyzing water-splitting processes. In this study, Ni–Fe NPs were prepared by initially synthesizing Ni, Fe ion-oleate metal-surfactant complexes. Subsequently, micelle formation by the complexes was induced by the use of non-polar solvent (n-hexane), serving as templates for nanoparticle formation during the thermal reduction process as illustrated in Supplementary Fig. 1. This approach is scalable and enables precise control over the composition and size of the nanoparticles (details in Methods)39.
The transmission electron microscopy (TEM) images (Supplementary Fig. 5) display the structure and size distribution of the as-synthesized Ni–Fe NPs, which exhibit a Gaussian profile with the majority of particles having diameters of 5–8 nm. Supplementary Figure 5a also reveals that the ion-oleate surfactants are carbonized to form conductive carbon network that may facilitate facile electron transfer between the nanoparticle and the support8. Utilizing a high angle annular dark-field (HAADF) STEM technique, Fig. 1b reveals the presence of interfaces which divide the Ni–Fe NP into two phases with distinctly different crystal structures and electron densities. The phase with higher electron density appears brighter in Fig. 1b, which reveals a closely packed Ni crystal structure. The darker phase exhibits a more sparsely packed, less-dense crystal structure filled with smaller oxygen atoms consistent with the γ-Fe2O3 structure, which was verified with the EDS line-scan elemental profiling shown in Fig. 1b. The EDS line scan indicates a distinct cross-over between the Ni and Fe elemental counts, confirming the presence of the Ni-γ-Fe2O3 heterojunction. The slightly increased Ni counts within the Fe-rich phase could be ascribed to the presence of another Ni-rich phase or overlapping nanoparticle. Lower-magnification EDS elemental mapping shows that the asymmetric distribution of Ni and Fe are also commonly observed in other particles. Importantly, the HR-STEM imaging reveals the formation of Ni–O–Fe bridge at the interface as highlighted in Supplementary Fig. 6. The selected area electron diffraction (SAED) of Ni–Fe NPs in Fig. 1c displays two clear diffraction rings with radius of 2.51 and 2.10 Å, indexed for (311) and (111) in γ-Fe2O3 and Ni crystal lattices, respectively. To understand the Ni–Fe NP formation mechanism, Ni- and Fe-based nanoparticles (denoted as Ni NPs and Fe NPs) were also synthesized via the identical method. The micrograph in Supplementary Fig. 7 shows that the Fe NPs are evenly distributed, exhibiting average particle diameters of 6–7 nm, similar to Ni–Fe NPs. On the other hand, the Ni NPs display an uneven distribution of large nanoparticles (~50 nm diameter, Supplementary Fig. 8). The nanoparticle size difference suggests that the thermal nucleation of Fe NPs occurs at lower temperatures (~70 °C) and is instantaneous, while the Ni NPs nucleate at higher temperature following a progressive mechanism40,41. These results suggest that the Ni–Fe NPs are formed by growth of Ni on the pre-formed Fe NP, rather than simultaneous nucleation.
X-ray diffraction (XRD) analysis shown in Fig. 2a also reveals the unique features of Ni–Fe NPs. XRD pattern of Ni NP indicates the formation of core-shell structure of Ni/NiO as identified by the presence of peaks correspond to both Ni and NiO (ICDD: 04-001-3331; 04-011-9039), as a result of instantaneous formation of passivating NiO outer shell42. The XRD of Fe NP indicates that γ-Fe2O3 (ICDD: 01-078-6916) was formed. In contrast, the nickel oxide diffraction peak was not observed in all the Ni–Fe NP samples and the strong peak at 44.5° corresponds to the (111) facet of metallic Ni, consistent to the STEM characterizations. Furthermore, the presence of γ-Fe2O3 in the Ni–Fe NP sample was confirmed by the identification of a set of diffraction peaks that match the Fe NP control material.
The oxidation states of Ni and Fe in Ni–Fe NPs were further analyzed by X-ray photoelectron spectroscopy (XPS). Two main peaks related to Ni 2p exist at ~855.2 eV (Ni 2p3/2) and 873.0 eV (Ni 2p1/2) in Ni–Fe NPs as shown in Fig. 2b are related to the unintended formation of large Ni/NiO NP (~50 nm in diameter) present in the Ni–Fe NP samples, as shown in Supplementary Fig. 10a. Further quantification based on area analysis of Supplementary Fig. 10b reveals that there are approximately 17% of NiO NP present in the Ni–Fe NP sample. The Ni 2p3/2 peak at 852.9 eV that corresponds to Ni0 (ref. 43) is observed only for the Ni–Fe NPs but not for the Ni NPs (Supplementary Fig. 11), in which clear Ni 2p3/2 multiplet-splitting were observed at ~855.2 and 873.1 eV, indicating the presence of Ni oxides. The significantly larger proportion of Ni 2p peaks for Ni2+ compared to that for Ni0 in the Ni–Fe NP sample can be attributed to the presence of the significantly larger NiO NP, which can be detected relatively easily by XPS compared to the smaller Ni–Fe NP (~5–8 nm) that are well embedded in the carbon fiber substrate. Additionally, the presence of Fe2O3 in the Ni–Fe NP sample is validated by the deconvolution of the high-resolution Fe 2p scan which reveals peaks for both Fe3+ and Fe2+ (Fig. 2c), giving an Fe3+/Fe2+ ratio of less than 2, corresponding to the high Fe oxidation state in maghemite (γ-Fe2O3)11,44. It is worth noting that the binding energy of Fe 2p3/2 in the Ni–Fe NPs is higher than that in both Fe2O3 and Fe NPs (Supplementary Fig. 12), despite sharing an identical crystal XRD pattern (Fig. 2a), indicating modifications to its electronic structure. The presence of Fe2O3 was also consistent to the observation of a metal bound O 1s peak at 530.6 eV (Fig. 2d). The asymmetric oxidation of the Fe-rich domain in the Janus Ni–Fe NP structure can be ascribed to the oxygen scavenging property and lower electronegativity of Fe (Pauling scale, Fe = 1.83, Ni = 1.91). Additionally, the presence of interface enables partial charge transfer from the Fe-rich domain to Ni-rich domain across the interface due to the electronegativity asymmetry. Hence due to the higher electronegativity of Ni, electron from Fe domain is partially transferred into the Ni-rich domain, protecting the Ni-rich domain from oxidation.
Further investigation of the Ni–Fe NP structure was carried out with X-ray absorption spectroscopy (XAS). Supplementary Figure 13 shows the Ni XANES data collected on the materials compared to key reference materials. The physical mixture of Ni NP and Fe NP (Ni/Fe NP) is a well fit by a combination of 80% metallic nickel and 20% NiO, consistent with previous characterizations (XRD and TEM), indicating the formation of core-shell Ni/NiO NP. On the other hand, the Ni XANES of Ni–Fe NP shift to lower energy consistent with the presence of interface between the γ-Fe2O3 phase and metallic nickel. This change is not well described by the Ni reference materials (blue arrow) indicating that it has properties that are distinct from any of them. By correlation with the TEM (Fig. 1b) the most plausible explanation is the formation of an interface between Ni and γ-Fe2O3. The EXAFS data at the Ni edge (Supplementary Fig. 14) are dominated by metallic nickel are substantially dampened probably due to structural disorder. The Fe XAS spectra of the same set of materials are presented in Supplementary Fig. 15. The XANES taken at the Fe edge show a shift to lower energy from the nanoparticle with interface (Ni–Fe NP). This is consistent with the contribution of a reduced Fe phase at the interface between Fe and Ni and is consistent with the XPS. This would be consistent with what was expected from the formation of an interface between metallic nickel and γ-Fe2O3 interface as observed in the TEM. The EXAFS of these materials are dominated by that of γ-Fe2O3, which is expected as the majority of the Fe in the sample are in the form of γ-Fe2O3.
Figure 3a shows the HER activity of Ni–Fe NP supported on carbon fiber paper (CFP) obtained in 1.0 M KOH by using linear sweep voltammetry (LSV) at a scan rate (v) of 5 mV s−1. CFP was chosen for HER activity evaluation due to its negligible HER activity. The catalyst mass loading and mole ratio of Ni to Fe were optimized based on the HER performance (Supplementary Figs. 16 and 17), and the best ratio of 5:1 was chosen for HER testing. Shown in Fig. 3a, the Ni–Fe NP exhibits an HER onset potential of −0.18 V vs. RHE (as determined by baseline extrapolation method (Supplementary Fig. 4), accompanied by visual detection of H2-gas bubbles formation on the electrode surface. Additionally, the Ni–Fe NPs exhibit a very low HER overpotential (ɳ) of 100 mV (without iR-corrections) to achieve a current density (j) of 10 mA cm−2. Only 46 mV is required after the iR-correction (Supplementary Fig. 18). This HER performance is comparable to the benchmark Pt catalyst (20% Pt/C) supported on CFP at the same catalyst loading, and outperforms most, if not all, non-precious metal-oxides, -chalcogenides, -nitrides, and -phosphides-based HER catalysts in similar alkaline media (Supplementary Table 2). In contrast, significantly higher HER overpotentials are required for Ni NPs (260 mV) and Fe NPs (410 mV) to achieve 10 mA cm−2, suggesting the distinct HER catalytic activity of the Ni–Fe NPs. Consistent trend in performance is also observed in Supplementary Fig. 22a where LSV curves are normalized against the electrochemical active surface area (ECSA) determined from double layer capacitance measurements (Supplementary Figs. 2 and 3). Ni–Fe NP exhibits the lowest ɳ of 200 mV for jECSA = −10 mA cm−2. The stability of catalyst was also tested under a high current condition (Supplementary Fig. 19a); the test was configured at jHER = −100 mA cm−2. Shown by the E–t trace (Supplementary Fig. 19b), it is revealed that Ni–Fe NP remains stable at relatively low η of 180 mV for an extended period of 10 h at a constant current (−10 mA cm−2). Additionally, based on Supplementary Fig. 19d, assuming that all Ni and Fe in the Ni–Fe NP participate in HER catalysis, the turn over frequency (TOF) of Ni–Fe NP at ɳ = 200 mV is 0.056 s−1 (Supplementary Information for details), an order of magnitude lower than that of Pt (0.9 s−1) but comparable to other state-of-the-art metal chalcogenide/phosphide and metal alloy, catalysts such as MoS2 (0.02 s−1), Ni5P4 (0.06 s−1), and Ni–Mo catalyst (0.05 s−1)45,46,47,48.
Furthermore, the physical stability of Ni–Fe NP was also verified with inductively coupled plasma-mass spectrometry (ICP-MS) measurement of Ni and Fe in the electrolyte (Supplementary Table 3) during a 10 h constant current electrolysis at −50 mA cm−2. As shown in Supplementary Table 3, no metal dissolution was observed in the first hour of electrolysis. After 10 h of electrolysis, trace amount of Fe (70 μg L−1) was detected in the electrolyte which corresponds to only 1.5 wt% of Fe in the fresh electrode. Additionally, Supplementary Fig. 19d shows the loss of HER activity is minimal, which is validated by the LSVs obtained before and after the stability testing. The stability is also confirmed by HAADF-STEM (Supplementary Fig. 19c), showing insignificant changes in the physical features of Ni–Fe NP. The crystal structure of the Ni–Fe NPs is also preserved after the stability test, as confirmed by XRD (Supplementary Fig. 27a).
To investigate the HER reaction kinetics, Tafel plots were derived from the LSVs and shown in Fig. 3b. The Ni–Fe NP exhibits a much smaller slope of 58 mV dec−1 than Ni NP (167 mV dec−1), Fe NP (186 mV dec−1), and Ni/Fe NP (212 mV dec−1), and an extremely large exchange current density of 1.58 × 10−3 A cm−2 which even matches with Pt/C catalyst in acidic media49,50. This slope value is also distinctly different from the previously reported Ni–Fe-based catalysts, which typically exhibit Tafel slopes above 80 mV dec−1 51,52 and approaches 20% Pt/C-CFP (Tafel slope: 50 mV dec−1), suggesting the HER at the Ni–Fe NP follows a Volmer–Heyrovsky HER mechanism50.
To understand the role of the interface between Ni and γ-Fe2O3 for HER, a physical mixture of Ni NPs and Fe NPs (denoted as Ni/Fe NPs) and an Ni–Fe alloy mixture (Supplementary Fig. 9, denoted as Ni–Fe alloy NP) were prepared at a molar ratio of 5 to 1, and their HER activities were evaluated. The physically mixed Ni/Fe NP was produced by drop-casting Ni(oleate)2 and Fe(oleate)2 at different stages, instead of the standard pre-mixing procedure of Ni2+ and Fe2+ with the oleate anion prior to the micellization step (Supplementary Fig. 1). The Ni–Fe alloy NP were prepared by annealing the precursor of Ni–Fe NP in high temperature H2 atmosphere to achieve better alloying. Shown in Fig. 3c, the Ni/Fe NP and Ni–Fe alloy NP require overpotentials of 112 and 307 mV, respectively, to achieve 10 mA cm−2, which are significantly higher than that required for Ni–Fe NP. Importantly, it is noted that the Fe3+ reduction peaks at 0 and −0.2 V observed in both Ni/Fe NPs (Fig. 3c) and Fe NPs (Supplementary Fig. 20) are not present in the LSV of Ni–Fe NPs, suggesting the redox behavior of the interconnected γ-Fe2O3 is altered as a result of the formation of Ni-γ-Fe2O3 interface.
Intriguingly, the Ni–Fe NP also exhibits extraordinary activity towards OER. We further examined the OER performance of the Ni–Fe NPs supported on nickel foam substrate (NF, Fig. 3d) and CFP (Supplementary Fig. 21). Nickel foam was used as substrate due to its excellent electrochemical properties, e.g. corrosion resistance against OER, electrical conductivity, 3-D porous structure, and robust mechanical strength11,22,52. The state-of-the-art NiFe layered double hydroxide (NiFe-LDH) electrocatalysts were also synthesized according to the established method to provide comparison14. Figure 3d shows that OER process catalyzed by Ni–Fe NP reaches a current density of 10 mA cm−2 at a low overpotential of 210 mV. Higher current densities of 20 mA and 100 mA cm−2 were achieved at η of 230 and 270 mV, respectively. These values outperform 20% Ir/C (Fig. 3d) as well as most reported transition metal oxides, chalcogenides, phosphides, and nitrides electrocatalysts (Supplementary Table 4). The TOF at η of 350 mV, by assuming all Ni and Fe in Ni–Fe NP participate in catalysis, is calculated to be 0.052 s−1 (Supplementary Information for details), which is comparable to benchmark 20% Ir/C (0.027 s−1) and electrodeposited NiFe/NF (0.075 s−1) at η of 400 mV, respectively11. It is worth noting that due to the small proportion of Ni–Fe interfaces on the Ni–Fe NP surface, the amount of Ni–O–Fe active sites are far less than the loaded amount of Ni and Fe, and therefore the actual TOF should be higher than the calculated values. Additionally, the LSVs were also normalized against ECSA (Supplementary Fig. 22b). Consistent with Fig. 3d, Supplementary Fig. 22b shows that Ni–Fe NP exhibits the highest OER performance with jECSA = 10 mA cm−2 achieved at η of 300 mV, which is also higher than electrodeposited NiFe/NF11. These comparisons indicate the crucial role of Ni-γ-Fe2O3 interface present in the Ni–Fe NP for OER electrocatalysis.
Supplementary Figure 23 shows that the Tafel slope of Ni–Fe NP is lower than that of NiFe-LDH and the linearity of the plot is also maintained at high j, indicating fast electron transfer and mass transport properties of the catalyst12,53. Supplementary Figure 24 shows chronopotentiometric response of Ni–Fe NP for OER with j increasing gradually from 50 mA to 500 mA cm−2 in nine-equal current steps of 50 mA cm−2. The potential response was observed to level off quickly on each stepping with high consistency, suggesting excellent mass transport properties as well as physical stability11. Excellent stability of the Ni–Fe NP for prolonged OER is illustrated in Supplementary Fig. 25a, b. Further, ICP-MS, HAADF-STEM, LSVs, and XRD analyses of Ni–Fe NP following OER stability tests also show negligible dissolution of the catalyst during OER (Supplementary Table 5), and no significant change to structure and OER activity (Supplementary Figs. 25c–d and 27b), compared to fresh Ni–Fe NP electrode.
Importantly, Fig. 3d shows the Ni oxidation peak prior to the onset of OER is greatly suppressed in the Ni–Fe NP configuration (Supplementary Fig. 26 for greater magnification of the Ni peak). The oxidation peak corresponds to the oxidation of Ni from low valence states (Ni0, Ni2+) to high valence states (Ni3+ or Ni4+), the latter are believed to be the active sites for OER54,55. The greatly reduced Ni oxidation peak, compared to that observed for Ni NP, Ni/Fe NP, and Ni–Fe alloy NPs (Fig. 3d), suggests that OER active sites already exist in the Ni–Fe NP, rather in operando formed. Compared to the structures and electrochemical results obtained for Ni NP, Ni/Fe NP, and Ni–Fe alloy NPs, where no Ni/Fe2O3 interface present, it is clear that the Ni-γ-Fe2O3 interface play a major role as the OER active site. Similar behavior is observed for HER, where the Fe reduction peaks prior to the onset of HER currents are observed for Ni/Fe NP (Fig. 3c) and Fe NP (Supplementary Fig. 20) but not for Ni–Fe NP, suggesting that the HER active sites in Ni–Fe NP are also present at the start of HER. Collectively, these results suggest that both OER and HER occur at the similar sites at the interface of Ni–Fe NP. It is also important to note that the presence of metallic Ni enables fast electron transport within the nanoparticle that is required for efficient electrocatalysis.
Further, Ni–Fe NP was used as both the anode and cathode in a whole cell water electrolyzer (details in Methods). The polarization curve of the Ni–Fe NP cell is recorded and compared to the cell constructed using benchmark noble metal catalysts, 20% Ir/C (OER) and 20% Pt/C (HER). Shown in Fig. 3e, the Ni–Fe NP cell exhibits superior performance to the Ir/C || Pt/C cell. The cell potential required for Ni–Fe NP cell to achieve 10 mA cm−2 is only 1.47 V (1.55 V without iR-correction; Supplementary Fig. 28), which is among the lowest bi-functional water-splitting catalysts reported recently (Supplementary Table 6). Based on the calculated HER and OER Faradaic efficiency of approximately ~100% at j = 10 mA cm−2 (Supplementary Fig. 31), the energy efficiency of the Ni–Fe NP cell is calculated to be 83.7% with iR-correction (79.4% without iR- correction). The Ni–Fe NP cell also shows excellent stability during the 24 h bulk water electrolysis at j = 10 and 20 mA cm−2 (Fig. 3f). In comparison, the Ir/C || Pt/C cell requires a cell voltage of 1.62 V to achieve 10 mA cm−2 and the performance was observed to deteriorate after 2 h, which is consistent to previous report4. In addition, to further demonstrate the Ni–Fe NP electrochemical stability against power interruptions, an accelerated degradation test (ADT) was performed by alternating the polarity of the electrode repeatedly. In this experiment, the electrolysis current is switched between 100 mA cm−2 (OER) and −100 mA cm−2 (HER), and the Ni–Fe NP electrode is subjected to anodic oxidation for OER for 600 s before switching to HER, and vice versa. Supplementary Figure 29 displays the stable potential response throughout the 4200 s duration of the ADT, confirming the exceptional stability of Ni–Fe NP as a reversible, bi-functional catalyst for water electrolysis under intermittent conditions.
To offer insights into the superior HER and OER performance of the Ni–Fe NP, the first-principles DFT calculations were conducted (more details in Supplementary Information). The interface model between the γ-Fe2O3 (311) and Ni (111) surfaces (Fig. 4a) was built based on the experimentally observed STEM-HAADF image of a single Ni–Fe NP (Fig. 1b). The Fe and Ni atoms are coupled via the bridge O atoms at the interface as highlighted in Supplementary Fig. 6. The strong interaction between Ni and O at the interface can be further confirmed by their overlapped O 2p and Ni 3d states around the Fermi energy level (Supplementary Fig. 31).
The ΔGH* is a key descriptor for evaluating the performance of HER electrocatalysts56. The DFT results reveal that the H atom can either adsorb on the top site of O atoms in γ-Fe2O3 (311) or the fcc site of Ni(111) with the ΔGH* of −0.62 and −0.31 eV, respectively. It is worth noting that our ΔGH* value on the Ni(111) surface is almost identical to that calculated by Nørskov et al.56. The negative ΔGH* values suggest that the activity of both surfaces are too high for HER. At the interface of the Ni–Fe NP, however, both the interfacial O and Ni atoms have more optimal activity to the HER as demonstrated by corresponding ΔGH* of −0.27 and −0.14 eV, respectively (Fig. 4b). It suggests that both the activities of the interfacial Ni and O atoms are reduced due to the formation of Ni–O bond and thereafter the charge transfer, which is beneficial to the HERs, as observed in experiments (Fig. 3a).
To understand the OER activities, the change of the Gibbs free energies, ΔGn (n = 1, 4), for the four fundamental OER steps were calculated since the magnitude of ɳ has been demonstrated to be the difference of the practical potential (maximum ΔGn over the charge e) and the standard Nernstian potential (1.23 V vs. SHE). Thus, the ΔGn values of intermediates need to reach the minimal difference between each other to reduce the ɳ. The calculated ΔGn on the γ-Fe2O3(311), Ni(111), and heterojunction are shown in Fig. 4b–d. The theoretical results indicate that the γ-Fe2O3 itself is a good OER electrocatalysts with the theoretical ɳ of 0.55 eV. The rate-determination step is the formation of O*, in which the binding strength of Fe and O* is considerably weak. As a comparison, the Ni metal possess large ɳ of 2.05 V with the rate-determination step for the formation of OOH* intermediate. This is largely due to much stronger binding between the surface Ni atom and the O* intermediate (Supplementary Table 8). At the interface of Ni–Fe NPs, the binding energy of O* is optimized since it adsorbs at the bridge site between Fe and Ni. As such, the smallest theoretical ɳ of 0.28 V is attained among three systems, which greatly matches the experimental observation (Fig. 3d). Our theoretical studies, therefore, demonstrate that only the interface of the Ni–Fe NPs has the superior OER performance (Supplementary Fig. 32).
The unusually high electrocatalytic HER activity of the Ni–Fe NP can be ascribed to the electronic coupling effect arising from the interface due to the asymmetrical distribution of Ni and Fe2O3 in the nanoparticle. Based on the Bader charge analysis result (Supplementary Table 7), Ni atoms at the interface are slightly oxidized due to the direct interaction with O anions (Fig. 4a). The ΔGH* of −0.30 eV on the Ni(111) indicates that the surface Ni atoms bind H* too strongly. Consequently, relatively large overpotential is required for the formation and desorption of H2 product. The slight oxidation of surface Ni atoms at the interface can reduce their activity, which can optimize the ΔGH* value to approach the optimal value of 0.0 eV. Moreover, the presence of metallic Ni provides metallic-type electron conduction which warrants facile electron transport towards the active HER sites at the interface as revealed by both experimental and computational results. Concomitantly, the HER onset of Ni–Fe NP is markedly lowered to RHE potential comparable to that of Pt/C due to the significantly lowered energy barrier for the initial Volmer step57 that is determined by electron transfer kinetic (Eq. 1):
The following H2 evolution was then promoted by the unique Ni–O–Fe configuration at the interface (Fig. 4a). Experimentally, this is manifested in distinctly different Tafel slope in the order of 20% Pt/C ~Ni–Fe NP ≪ Ni NP < Fe NP, suggesting a significantly altered secondary H2 evolving step, in contrast to Ni NP and Fe NP.
Intriguingly, the synergy between Ni and Fe2O3 at the interface of their NPs can also benefit the OER process. Based on the analyses of Gibbs free energy diagrams, the Fe3+ cation and Ni0 atom possess too weak or too strong activities to the OER, respectively. The spontaneous interaction of the OER intermediates formed at the bridge site between Ni and Fe can greatly optimize their Gibbs free energies, improving the OER performance as evidenced by the theoretically optimized atomic structures shown in Fig. 4c. Moreover, the unique Ni–O–Fe configuration at the interface as indicated in Fig. 4a provides a great platform to achieve multi-site functionality for the electrocatalysts. The multi-site functionalization can offer several active sites to stabilize one adsorbed state or transition state without stabilizing others, which can, therefore, break the limit of energy scaling relations of OER to lower the overpotential58. Previous studies reveals that the ΔG2 + ΔG3 values are within 3.2 ± 0.2 eV range due to their scaling relation among reactive intermediates38. Our ΔG2 + ΔG3 values on the γ-Fe2O3(311) and Ni(111) surfaces are 3.32 and 3.25 eV, respectively, which are the examples of this scaling relations. At the interface of Ni–Fe NPs, the OOH* intermediate is stabilized through the formation of hydrogen bonding between its H atom and neighboring interfacial O atom (Supplementary Fig. 33). Consequently, the energy scaling relations are circumvented with a reduced ΔG2 + ΔG3 value of 2.79 eV and smallest theoretical ɳ of 0.28 V. This multi-site functionalization mechanism found in our system can also explain other Ni–Fe-based OER electrocatalysts with the overpotential lower than the theoretical limit (~0.3 V) due to the scaling relation, such as LDH, metal organic framework, or amorphous mixture11,14,57,59.
In summary, this work demonstrates that the introduction of asymmetry in an electrocatalyst structure could induce unprecedented synergistic effect for electrocatalysis. Through this approach, we have overcome the practical limitation of Ni–Fe mixed oxides for overall water electrolysis due to the poor HER activity. Additionally, having similar active sites for both OER and HER results in the preservation of catalyst structure and activity against electrode corrosion induced by power interruptions, which is ideal for a water electrolyzer powered by intermittent renewable energy sources. Beyond, it is also our hope that this multi-site functionality catalyst design can help to expedite the conception-to-commercialization process of other multi-metallic nanoparticle electrocatalysts with different compositions and structures that exhibit distinct interfaces for various electrolytic applications such as CO2 reduction reactions and nitrogen reduction reactions.
Nanoparticles and electrodes preparation
To prepare Ni–Fe NP, initially 5 mmol of Ni(NO3)2.6H2O (UNIVAR grade, Ajax Finechem, Australia) and 1 mmol Fe(Cl)2.4H2O (Sigma-Aldrich, USA) were dissolved into a mixture of 2 mL of de-ionized water and 1 mL of ethanol. Four grams of Na(oleate) (TCI, Japan) was dissolved into a separate mixture of 4 mL de-ionized water and 3 mL of ethanol. The two mixtures were then mixed in a round-bottomed flask to yield thick and waxy green-yellow substances, and into the mixture, 14 mL of hexane was added. Upon the addition of hexane, immediate transfer of the colored metallic elements into the hexane phase was observed (Supplementary Fig. 1); the mixture was then stirred at 400 r.p.m. for 60 min. Two well-separated layers of water (colorless/opaque) and colored hexane layer (dark-green) were obtained at the end of stirring. Other oleate complexes with different Ni and Fe ratios were made by the same method by adjusting the mole ratio between Ni and Fe salts precursors to yield metal-oleate complex solution with a concentration of 0.43 mmol(metal) mL−1 (6 mmol of metals in 14 mL of hexane).
Electrodes were prepared by employing substrate materials such as CFP (FuelCell Store, Spectracarb 2050A-1535, USA) and nickel foam (NF, thickness: 1.6 mm, bulk density: 0.45 g cm−3, Goodfellow, UK). The substrates were modified with metal-oleate complexes dissolved hexane solution via the drop-casting method. For the preparation of Ni NP, Fe NP, and Ni–Fe NP on CFP, 180 μL of the corresponding metal/metals oleate complex in hexane was drop casted onto 3 cm2 of CFP. In case of NF, 300 μL (7.5 mg of metal) were drop casted onto 0.22 g of NF (GSA = 3 cm2, Supplementary Information for conversion calculation). For the preparation of Ni/Fe NP onto CFP electrode, 150 μL of Ni(oleate)2 was drop casted onto a 3 cm2 CFP, followed by 30 μL of Fe(oleate)2. The substrate was then dried under bench-top condition until the remaining hexane was evaporated and a waxy film was formed at the electrode surface. The modified substrates were subsequently annealed in Ar-protected horizontal tube furnace at 350 °C for 2 h at a ramp rate of 10 °C min−1 with an Ar-flow rate of 5 mL min−1. Upon completion, the annealing chamber was allowed to cool down naturally to room temperature. For the preparation of Ni–Fe alloy NP, following the micellization step (Supplementary Fig. 1), the Ni–Fe oleate complex were further incubated at 70 °C for 7 h to allow further equilibration of Ni2+ and Fe2+ distribution within the micellar metal complex8, then following immobilization step the modified substrates were annealed under in H2 atmosphere at 700 °C for 2 h at a ramp rate of 10 °C min−1 with a gas flow rate of 5 mL min−1. The annealed electrodes were washed ultrasonically with Milli-Q water to remove the loosely bound nanoparticles for 5 min. Catalyst mass loadings (ml) of CFP and NF modified with metal nanoparticles were 1.5 and 2.5 mg cm−2, respectively, and these values were determined according to the calculations shown in the Supplementary Information, unless otherwise stated. To verify the mass loading nanoparticles on CFP, thermogravimetric (TGA) measurement was carried out on 0.5 cm × 0.5 cm of Ni–Fe NP/CFP and the result is shown in Supplementary Fig. 30. TGA measurement was carried out with a temperature ramp rate of 10 °C min−1 with a measurement range of 100–1000 °C in air to remove all of the non-metal components of the electrode. It is shown that at the end of the measurement 0.41 mg of residual weight was observed, corresponding to ml of 1.64 mg cm−2. The slight discrepancy can be attributed to the weight gains from the formation of metal oxides.
The noble metal modified electrodes were prepared through drop-casting method. An ink of 20% Pt/C was prepared by the addition 10 mg of 20% Pt/C or 20% Ir/C (Premetek, USA) into 1.96 mL of 50% ethanol solution containing 0.04 mL 5% Nafion binder solution (Sigma-Aldrich, USA). The ink was then loaded onto substrate and dried under vacuum at 40 °C, resulting in catalyst mass loading of 3.0 mg cm−2.
All electrochemical measurements were carried out with a CHI 760 electrochemical workstation (CH Instruments, USA). Electrochemical measurements were performed with a standard three-electrode cell configuration composed of working electrode, graphite rod counter electrode, and standard calomel electrode (SCE) as the reference electrode, unless otherwise stated. The potential of the SCE reference electrodes were routinely calibrated before and after experiments against a SCE that is conserved in saturated KCl solution. For all electrochemical measurement, the recorded SCE potential was converted into RHE using the following formula, ERHE = ESCE + 0.241 + 0.059 × pH. OER and HER polarization curves were recorded at the scan rate of 5 mV s−1, in 1 M KOH at 25 °C with 95% iR-corrections using the automated iR-correction function of the potentiostat60. Two-electrode water electrolysis cell was constructed from two NF electrodes modified with Ni–Fe NP with mass loading of 2.5 mg cm−2 in 1 M KOH. Energy efficiency of the cell was calculated using the following equation:
where Ef,o = 1.23 V; Ve,i is the input voltage required to drive the electrolysis at the current density of interest. The energy efficiency calculated in this study was obtained at j = 10 mA cm−2.
The data that support the plots within this paper and other findings of this study are available from the corresponding author on request.
Hydrogen on the rise. Nat. Energy 1, 16127 (2016).
Roger, I., Shipman, M. A. & Symes, M. D. Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting. Nat. Rev. Chem. 1, 0003 (2017).
Mallouk, T. E. Divide and conquer. Nat. Chem. 5, 362 (2013).
Wang, H. et al. Bifunctional non-noble metal oxide nanoparticle electrocatalysts through lithium-induced conversion for overall water splitting. Nat. Commun. 6, 7261 (2015).
Hu, E. et al. Construction of hierarchical Ni-Co-P hollow nanobricks with oriented nanosheets for efficient overall water splitting. Energy Environ. Sci. 11, 872–880 (2018).
You, B. & Sun, Y. Innovative strategies for electrocatalytic water splitting. Acc. Chem. Res. 51, 1571–1580 (2018).
John, K. & Michael, G. Oxygen evolution from water via redox catalysis. Angew. Chem. Int. Ed. 17, 860–861 (1978).
Li, J. et al. Nanoparticle superlattices as efficient bifunctional electrocatalysts for water splitting. J. Am. Chem. Soc. 137, 14305–14312 (2015).
Fan, X. et al. Defect-enriched iron fluoride-oxide nanoporous thin films bifunctional catalyst for water splitting. Nat. Commun. 9, 1809 (2018).
Xia, L. et al. A strongly coupled graphene and FeNi double hydroxide hybrid as an excellent electrocatalyst for the oxygen evolution reaction. Angew. Chem. Int. Ed. 126, 7548–7588 (2014).
Lu, X. & Zhao, C. Electrodeposition of hierarchically structured three-dimensional nickel–iron electrodes for efficient oxygen evolution at high current densities. Nat. Commun. 6, 6616 (2015).
Wang, Y., Yan, D., El Hankari, S., Zou, Y. & Wang, S. Recent progress on layered double hydroxides and their derivatives for electrocatalytic water splitting. Adv. Sci. 5, 1800064 (2018).
Yu, X., Zhang, M., Yuan, W. & Shi, G. A high-performance three-dimensional Ni-Fe layered double hydroxide/graphene electrode for water oxidation. J. Mater. Chem. A 3, 6921–6928 (2015).
Gong, M. et al. An advanced Ni-Fe layered double hydroxide electrocatalyst for water oxidation. J. Am. Chem. Soc. 135, 8452–8455 (2013).
Chen, D. et al. Preferential cation vacancies in perovskite hydroxide for the oxygen evolution reaction. Angew. Chem. Int. Ed. 57, 8691–8696 (2018).
Wang, Y. et al. Tuning surface electronic configuration of NiFe LDHs nanosheets by introducing cation vacancies (Fe or Ni) as highly efficient electrocatalysts for oxygen evolution reaction. Small 14, 1800136 (2018).
Chatti, M. et al. Highly dispersed and disordered nickel–iron layered hydroxides and sulphides: robust and high-activity water oxidation catalysts Sust. Sust. Energy Fuels 2, 1561–1573 (2018).
Raj, I. A. & Vasu, K. I. Transition metal-based hydrogen electrodes in alkaline solution—electrocatalysis on nickel based binary alloy coatings. J. Appl. Electrochem. 20, 32–38 (1990).
Goryachev, A. et al. Stability of CoPx electrocatalysts in continuous and interrupted acidic electrolysis of water. ChemElectroChem 5, 1230–1239 (2018).
Zou, X. & Zhang, Y. Noble metal-free hydrogen evolution catalysts for water splitting. Chem. Soc. Rev. 44, 5148–5180 (2015).
Jiang, N. et al. Electrodeposited nickel-sulfide films as competent hydrogen evolution catalysts in neutral water. J. Mater. Chem. A 2, 19407–19414 (2014).
Feng, L.-L. et al. High-index faceted Ni3S2 nanosheet arrays as highly active and ultrastable electrocatalysts for water splitting. J. Am. Chem. Soc. 137, 14023–14026 (2015).
Li, H. et al. Activating and optimizing MoS2 basal planes for hydrogen evolution through the formation of strained sulphur vacancies. Nat. Mater. 15, 48–53 (2016).
Caban-Acevedo, M. et al. Efficient hydrogen evolution catalysis using ternary pyrite-type cobalt phosphosulphide. Nat. Mater. 14, 1245–1251 (2015).
Popczun, E. J. et al. Nanostructured nickel phosphide as an electrocatalyst for the hydrogen evolution reaction. J. Am. Chem. Soc. 135, 9267–9270 (2013).
Xiao, P. et al. Molybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reaction. Energy Environ. Sci. 7, 2624–2629 (2014).
Zhang, Y. et al. 3D porous hierarchical nickel–molybdenum nitrides synthesized by rf plasma as highly active and stable hydrogen evolution reaction electrocatalysts. Adv. Energy Mater. 6, 1600221 (2016).
Long, X. et al. Metallic iron–nickel sulfide ultrathin nanosheets as a highly active electrocatalyst for hydrogen evolution reaction in acidic media. J. Am. Chem. Soc. 137, 11900–11903 (2015).
Anantharaj, S. et al. Recent Trends and perspectives in electrochemical water splitting with an emphasis on sulfide, selenide, and phosphide catalysts of Fe, Co, and Ni: A review. ACS Catal. 6, 8069–8097 (2016).
Peng, X., Wei, C. & Xin, W. A review of phosphide-based materials for electrocatalytic hydrogen evolution. Adv. Energy Mater. 5, 1500985 (2015).
Zheng, X. et al. Theory-driven design of high-valence metal sites for water oxidation confirmed using in situ soft X-ray absorption. Nat. Chem. 10, 149 (2017).
Mabayoje, O., Shoola, A., Wygant, B. R. & Mullins, C. B. The role of anions in metal chalcogenide oxygen evolution catalysis: electrodeposited thin films of nickel sulfide as “pre-catalysts”. ACS Energy Lett. 1, 195–201 (2016).
Vij, V. et al. Nickel-based electrocatalysts for energy-related applications: oxygen reduction, oxygen evolution, and hydrogen evolution reactions. ACS Catal. 7, 7196–7225 (2017).
Yan, B. et al. Surface restructuring of nickel sulfide generates optimally coordinated active sites for oxygen reduction catalysis. Joule 1, 600–612 (2017).
Uchino, Y. et al. Relationship between the redox reactions on a bipolar plate and reverse current after alkaline water electrolysis. Electrocatal. 9, 67–74 (2018).
Casagrande, C., Fabre, P., Raphael, E. & Veyssié, M. “Janus beads”: realization and behaviour at water/oil interfaces. Europhys. Lett. 9, 251 (1989).
Guo, X., Zhu, Y. & Ma, T. Lowering reaction temperature: Electrochemical ammonia synthesis by coupling various electrolytes and catalysts. J. Energy Chem. 26, 1107 (2017).
Seh, Z. W. et al. Combining theory and experiment in electrocatalysis: insights into materials design. Science 355, eaad4998 (2017).
Park, J. et al. Ultra-large-scale syntheses of monodisperse nanocrystals. Nat. Mater. 3, 891–895 (2004).
Bronstein, L. M. et al. Influence of iron oleate complex structure on iron oxide nanoparticle formation. Chem. Mater. 19, 3624–3632 (2007).
Ge, J.-M. et al. Constructing holey graphene monoliths via supramolecular assembly: enriching nitrogen heteroatoms up to the theoretical limit for hydrogen evolution reaction. Nano Energy 15, 567–575 (2015).
D’Alkaine, C. V. & Santanna, M. A. The passivating films on nickel in alkaline solutions I. General aspects of the Ni (II) region. J. Electroanal. Chem. 457, 5–12 (1998).
Grosvenor, A. P., Biesinger, M. C., Smart, R. S. C. & McIntyre, N. S. New interpretations of XPS spectra of nickel metal and oxides. Surf. Sci. 600, 1771–1779 (2006).
Akbar, A., Riaz, S., Bashir, M. & Naseem, S. Effect of Fe3+/Fe2+ ratio on superparamagnetic behavior of spin coated iron oxide thin films. IEEE Trans. Magn. 50, 1–4 (2014).
McKone, J. R., Sadtler, B. F., Werlang, C. A., Lewis, N. S. & Gray, H. B. Ni–Mo nanopowders for efficient electrochemical hydrogen evolution. ACS Catal. 3, 166–169 (2013).
Jaramillo, T. F. et al. Identification of active edge sites for electrochemical H2 evolution from MoS2 nanocatalysts. Science 317, 100–102 (2007).
Merki, D. & Hu, X. Recent developments of molybdenum and tungsten sulfides as hydrogen evolution catalysts. Energy Environ. Sci. 4, 3878–3888 (2011).
Laursen, A. B. et al. Nanocrystalline Ni5P4: a hydrogen evolution electrocatalyst of exceptional efficiency in both alkaline and acidic media. Energy Environ. Sci. 8, 1027–1034 (2015).
Chen, W.-F. et al. Hydrogen-evolution catalysts based on non-noble metal nickel–molybdenum nitride nanosheets. Angew. Chem. Int. Ed. 51, 6131–6135 (2012).
Sheng, W., Gasteiger, H. A. & Shao-Horn, Y. Hydrogen oxidation and evolution reaction kinetics on platinum: acid vs alkaline electrolytes. J. Electrochem. Soc. 157, B1529–B1536 (2010).
Zhang, X. et al. Facile synthesis of nickel–iron/nanocarbon hybrids as advanced electrocatalysts for efficient water splitting. ACS Catal. 6, 580–588 (2016).
De Carvalho, J., Tremiliosi Filho, G., Avaca, L. A. & Gonzalez, E. R. Electrodeposits of iron and nickel-iron for hydrogen evolution in alkaline solutions. Int. J. Hydrog. Energy 14, 161–165 (1989).
Suryanto, B. H. R. & Zhao, C. Surface-oxidized carbon black as a catalyst for the water oxidation and alcohol oxidation reactions. Chem. Commun. 52, 6439–6442 (2016).
Klaus, S., Cai, Y., Louie, M. W., Trotochaud, L. & Bell, A. T. Effects of Fe electrolyte impurities on Ni(OH)2/NiOOH structure and oxygen evolution activity. J. Phys. Chem. C. 119, 7243–7254 (2015).
Suryanto, B. H. R., Fang, T., Cheong, S., Tilley, R. D. & Zhao, C. From the inside-out: leached metal impurities in multiwall carbon nanotubes for purification or electrocatalysis. J. Mater. Chem. A 6, 4686–4694 (2018).
Nørskov, J. K. et al. Trends in the exchange current for hydrogen evolution. J. Electrochem. Soc. 152, J23–J26 (2005).
Duan, J., Chen, S. & Zhao, C. Ultrathin metal-organic framework array for efficient electrocatalytic water splitting. Nat. Commun. 8, 15341 (2017).
Wang, J., Deng, S., Liu, Z. & Liu, Z. The rare two-dimensional materials with Dirac cones. Natl Sci. Rev. 2, 22–39 (2015).
Luo, J. et al. Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts. Science 345, 1593–1596 (2014).
He, P. & Faulkner, L. R. Intelligent, automatic compensation of solution resistance. Anal. Chem. 58, 517–523 (1986).
The authors thank UNSW Mark Wainwright Analytical Centre (MWAC) for the access to all characterization instruments and Dr. Bin Gong for his assistance in XPS characterization. The authors also thank University of Wollongong Electron Microscopy Centre (EMC) and Dr. Gilberto C. Garcia for the access to their STEM unit. The DFT calculations were undertaken on the supercomputers in National Computational Infrastructure (NCI) in Canberra, Australia, which is supported by the Australian Commonwealth Government, and Pawsey Supercomputing Centre in Perth with the funding from the Australian government and the Government of Western Australia. We acknowledge the Australian Synchrotron (part of ANSTO) for providing access to the XAS beamline (project ID M11320). Dr. P. Kappen and B. Johannesson for support during XAS experiments. This study was financed by Australian Research Council (ARC), Discovery Grants (DP160103107, DP 170104834, FT170100224).
C.Z. and B.H.R.S. filed an Australian provisional patent (No. 2018900539) based on this work. The other authors declare no competing interests.
Peer review information Nature Communications thanks Xiujun Fan and the other, anonymous, reviewer(s) for their contribution to the peer review of this work.
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
About this article
Cite this article
Suryanto, B.H.R., Wang, Y., Hocking, R.K. et al. Overall electrochemical splitting of water at the heterogeneous interface of nickel and iron oxide. Nat Commun 10, 5599 (2019). https://doi.org/10.1038/s41467-019-13415-8
This article is cited by
Nature Communications (2023)
Monometallic interphasic synergy via nano-hetero-interfacing for hydrogen evolution in alkaline electrolytes
Nature Communications (2023)
Nature Communications (2023)
Topics in Catalysis (2023)