Octahedral molecular sieves (OMS) are built of transition metal-oxygen octahedra that delimit sub-nanoscale cavities. Compared to other microporous solids, OMS exhibit larger versatility in properties, provided by various redox states and magnetic behaviors of transition metals. Hence, OMS offer opportunities in electrochemical energy harnessing devices, including batteries, electrochemical capacitors and electrochromic systems, provided two conditions are met: fast exchange of ions in the micropores and stability upon exchange. Here we unveil a novel OMS hexagonal polymorph of tungsten oxide called h’-WO3, built of (WO6)6 tunnel cavities. h’-WO3 is prepared by a one-step soft chemistry aqueous route leading to the hydrogen bronze h’-H0.07WO3. Gentle heating results in h’-WO3 with framework retention. The material exhibits an unusual combination of 1-dimensional crystal structure and 2-dimensional nanostructure that enhances and fastens proton (de)insertion for stable electrochromic devices. This discovery paves the way to a new family of mixed valence functional materials with tunable behaviors.
Molecular sieves (MS) are microporous solids involved since decades in industrial processes such as purification, separation, and petroleum refining, among others1. Although most MS including microporous carbons and zeolites are based on the arrangement of four-coordinated C, Al, and Si tetrahedral units, scarcer inorganic solids arise from the organization of MO6 octahedra. These materials were coined as octahedral MS (OMS) by S. L. Suib2. Because the six-coordinated cation M is a transition metal, typically manganese2,3,4 and less frequently vanadium5,6, tungsten7,8, titanium9, or niobium10, OMS possess greater versatility than common tetrahedra-based microporous solids in terms of redox3, magnetic11 properties and substitution11,12,13 abilities, which open a realm of opportunities in catalysis3,12,13, energy storage3,14, sensing15, information technologies15, and smart systems16. Very often, OMS rely on ternary or more complex compositions including guest cations (proton, alkali, and alkali earth ions) or water molecules into micropores. These species act as templates that cannot be totally eliminated without collapsing the structure2,3,4,5,6. Tungsten OMS are special in this respect since the W-O framework of h-WO37 or pyrochlore-WO38 is maintained after removal of guests and concomitant oxidation of charge compensating WV into WVI, yielding stoichiometric WO3 compounds with micropores, contrary to the other WO3 polymorphs17. In this article, we expand the WO3 family by using aqueous chemistry to unveil a new tungsten hydrogen bronze h’-H0.07WO3 with a novel W-O framework and promising electrochemical properties. Protons can be reversibly extracted to yield a novel guest-free, OMS stoichiometric binary tungsten oxide h’-WO3, with high chemical and thermal stability.
Many of the properties of tungsten oxides for gas sensors17,18, electrochromic devices19,20,21, supercapacitors22, batteries23,24,25,26,27,28, photocatalysts29, water splitting devices30, and solar cells31 rely on the ability of WO3 compounds to insert cations and therefore to form bronzes AxWO3 (A being a cation such as proton, alkali ion, or ammonium), concomitant with partial reduction of WVI centers to WV.
We show hereafter that a chimie douce route yields anisotropic two-dimensional nanostructures of the new h’-WO3 framework that result in preferential orientation of the micropores for easy and fast ion insertion/deinsertion, thus leading to a stable and efficient electrochromic material in aqueous medium.
Results and discussion
The new tungsten oxide powder was prepared in water under soft conditions. Briefly, the pH of a Na2WO4·2H2O and hydrazine N2H4 solution was adjusted to a value of 0.6, close to the isoelectric point of tungsten oxides (~ 1.5)32 and hydrous tungsten oxides (~ 0.5)33 leading to a beige amorphous precipitate. The suspension was aged at room temperature for 14 h and then at 95 °C for 3 days or at 120 °C under autogenic pressure for 12 h. A deep-blue powder characteristic of mixed valence WV/WVI tungsten oxides17 was recovered after washing and drying at 40 °C under vacuum.
Crystal structure and nanostructure
Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) (Fig. 1a, b) show that the powder is exclusively made of thin nanoplatelets with diameter between 20 and 80 nm and thickness of 3–10 nm (Fig. 1b, statistical measurements in Supplementary Figure 1). High-resolution TEM (HRTEM) and selected area electron diffraction (SAED) (Fig. 1b) reveal a hexagonal tiling with a characteristic distance of 8.7 Å, which could not be attributed to any of the known tungsten oxides or bronzes. As HRTEM images and SAED patterns, the powder X-ray diffraction (XRD) pattern (Supplementary Figure 2) cannot be indexed according to known phases and supports the discovery of a new W-O-based structure.
The XRD pattern has been indexed in a hexagonal cell (space group P6/mmm) with lattice parameters a = 9.997 Å and c = 3.921 Å (Supplementary Table 1, crystallographic information file (CIF) and CheckCIF file as Supplementary Data 1, Supplementary Data 2, respectively). The c value corresponds to one WO6 octahedron layer, already observed in the classical h-WO3 structure. The cell volume of 339.3 Å3 can accommodate six WO3 formula units with a theoretical density of 6.81 in the range of those for known WO3 polymorphs and bronzes, especially h-WO3 (6.49)7. The anisotropy of the single crystal particles and the presence of stacking faults discussed below were taken into account for Rietveld refinement (Fig. 1e and SI)34. Projections of the new hexagonal structure along the c axis and in the  direction are shown in Figs. 1f, g, respectively. The structure is based on an arrangement of WO6 octahedra sharing corners in (WO6)6 wheels, which are stacked along the c axis to yield tunnels. These tunnels exhibit an internal diameter after subtraction of oxygen radii of ca. 4.8 Å, typical of OMS solids. The tunnels are connected together by octahedra corners, which open additional (WO6)4 and (WO6)3 tunnels. Further investigation of the structure was performed by scanning TEM. Because the sample is very sensitive to beam damage, STEM imaging was performed in an aberration-corrected microscope enabling operation at low acceleration voltages (80 kV) and low dose with high spatial resolution. Both high angle annular dark field (HAADF) and annular bright field (ABF) detections were used (Fig. 1), with sensitivity to heavy and light elements, respectively. The structure derived from powder XRD is consistent with STEM data (Fig. 1c, inset).
The nearly perfect superimposition of the XRD-resolved structure over the atomically resolved HAADF-STEM micrograph (Fig. 1c) confirms the accuracy of our refinement. However, a range of crystal defects is observed by STEM (Fig. 2a), which encompasses (1) 30°-rotation of (WO6)6 wheels around the c axis (Fig. 2b, d, e), (2) antiphase boundaries (Fig. 2c), and (3) five-membered rings (Fig. 2a) where one WO6 unit has been stripped off (WO6)6 wheels. 30°-rotations result in strong electron density residuals on the Fourier-difference maps when Rietveld refinement is performed only with the ideal structure. Hence, these rotations have been taken into account for structure refinement by considering a solid solution of the regular structure and the faulted one (see SI). The reliability was significantly improved and reached a satisfactory level (SI). The proportion of 30°-rotation defects according to Rietveld refinement corresponds to 14% of the six-members tunnels, in agreement with TEM observations (ca. 10%). The size of the six-members cavity is slightly reduced in the presence of the 30°-rotations (internal diameter after subtraction of oxygen radii changing from 4.8 Å to 4.5 Å in the ideal and rotated wheels, respectively).
The resolved W-O skeleton exhibits little electron density residues in the hexagonal cavities, which reveal the presence of additional atoms. Indeed, the blue hue and the band gap measured by UV-vis spectroscopy of about 2.9 eV are consistent with other WO3 bronzes17 and are typical of mixed valence W oxides that exhibit WV/WVI intervalence transitions at wavelengths above 400 nm (Supplementary Figure 3)19. The mixed valence is confirmed by electron spin resonance (ESR, Supplementary Figures 4-8). Note that ESR suggests important spin coupling that is currently under investigation (Supplementary Figures 6-7). Small cations are inserted in the WO3 framework to ensure charge balance. According to the synthesis protocol, H+, Na+ from the tungstate salt and NH4+ from hydrazine are the only candidates. NH4+ is absent because nitrogen is not observed by energy dispersive X-ray spectroscopy (EDS) and replacement of hydrazine with amine-free glucose or sodium ascorbate yields the same solid. Exchange of the inserted ions by an excess of Na+ in water (see Methods) yields fast acidification. Accordingly, the H+/W ratio is evaluated to 8 at. %. The additional presence of Na+ is unlikely as sodium could not be detected by EDS (Supplementary Figure 9). This is confirmed by X-ray photoelectron spectroscopy (XPS, Supplementary Figure 10) that yields a W5+/W ratio of ca. 7 ± 3 at. %, in agreement with the proton content. Hence, sodium ions do not participate to charge balance and the bronze obtained after aqueous synthesis is a hydrogen bronze of overall composition h’-H0.07 ± 0.03WO3. The presence of protons in the tunnels is confirmed by the STEM-ABF images (Figs. 1d and 2e) that show a dark contrast in all the (WO6)6 tunnels (Fig. 1d, inset), whereas HAADF (Fig. 1c) does not exhibit such features, thus evidencing a light element: hydrogen atoms35. Note that some of the (WO6)4 channels show also a dark contrast in ABF detection (Supplementary Figure 11), which would suggest that some protons also occupy part of these four-members tunnels. Calcination of this h’-H0.07WO3 bronze under air at 100 °C readily yields a white, fully oxidized, material with identical XRD pattern (Fig. 3a, equation 1). Thus, the new W-O framework is maintained, yielding a stoichiometric white oxide we note h’-WO3. Charge compensating cations present in the bronze can then be eliminated through a topotactic reaction by soft annealing, which supports the presence of protons that can evolve as water molecules. Hence, the as-obtained solid h’-H0.07WO3 is a hydrogen bronze of h’-WO3. Thermal gravimetric analysis (TGA) combined with differential temperature analysis (DTA) and temperature-dependent XRD (Fig. 3) shows that the structure is preserved up to 425 °C under air. Such a thermal stability is higher than classical h-WO3 transforming at 300 °C and interesting for many applications. The transition from the bronze to the stoichiometric oxide is reversible (Fig. 3a, equation 2): upon exposure to air and light at room temperature for about 10 min, the material recovers its initial blue color. Interestingly, under air but in the dark, the white stoichiometric h’-WO3 is stable, thus highlighting the photosensitivity of this new solid.
Optical and electronic properties
The wide UV-visible absorption band for the bronze h’-HxWO3 at wavelengths above 400 nm (Supplementary Figure 3) is related to intervalence transitions between W5+ and W6+ that correspond to optically activated electron transfer associated with the presence of polarons19,36. According to previous reports on other WO3 polymorphs, the x value of ca. 0.07 should be too low to enable overlapping of the polaronic wave functions and the emergence of a metallic state36,37,38. Hence, the bronze is expected as a semiconductor and the band gap evaluated by UV-visible spectroscopy from the lower wavelength region should be similar in the oxidized state. To get deeper insight into the electronic properties, the density of states (DOS) of h’-WO3 was calculated by first principle density functional theory (DFT). In order to take into account the influence of the 30°-(WO6)6 rotation defects, we have also assessed the electronic structure of a phase in which all (WO6)6 wheels are rotated (denominated rotated h’ hereafter, Fig. 4). For comparison, the DOS of already known hexagonal h-WO3 and monoclinic m-WO3 polymorphs have been also calculated (Fig. 4). h-WO3 also contains (WO6)6 and (WO6)3 tunnels, but does not exhibit (WO6)4 tunnels.
The new h’ phase and its derivate show similar total, O 2p and W 5d-projected DOS that are also close to those of different WO3 polymorphs (Fig. 4). All phases are semiconductors, with valence and conduction bands dominated by O 2p and W 5d orbitals, respectively, which is commonly reported for WO339,40,41 and WO3 hydrate phases42. The band gaps evaluated by DFT are 0.59, 0.65, 0.52, and 1.22 eV for the h’, rotated h’, h, and m polymorphs. These values are consistent with previous reports on h-WO3 and m-WO3 using DFT-PBE (Perdew-Burke-Ernzerhof) calculations39,40,41 that commonly underestimate band gaps (see SI). Hence, the calculated values are lower than the experimental ones reported for the h and m polymorphs (2.5–3.0 eV)17 and measured above for the h’ bronze (2.9 eV). The contribution of each h’ and rotated h’ networks to the actual total DOS was roughly estimated from the proportion of each network obtained from XRD-based structure refinement (Supplementary Figure 12). The band gap is dictated by the smaller gap network h’. From the total energies of the four polytypes calculated, the relative stability order is rotated h’-WO3 < h-WO3 < h’-WO3 < m-WO3. As expected from the literature, the most stable phase at low temperature is the monoclinic one. If h’-WO3 is slightly more stable than the standard hexagonal phase, the rotated h’ network is less stable, which might explain its smaller (∼15 %) contribution to the title compound.
We have then introduced hydrogen in the (WO6)6 channels of our model in two different configurations (Supplementary Figures 13 and 14): either in the center of the tunnels or in the vicinity of oxygen at the edge of the channels. Protons are probably located into the (WO6)6 channels, but may also be present in the (WO6)4 channels, as already reported for lithium in the (WO6)4 openings of h-WO343. More extensive calculations would be needed to examine the precise position that is favored by protons, but the conclusions drawn from our simple models should still be qualitatively valid. DFT (GGA-PBE) study of the H inserted h’-WO3 model with OH moieties in the tunnels led to an electronic structure with close features to similar calculations on other polymorphs44 and hydroxides (see SI). N. Bondarenko et al.45 reported in detail, with DFT + U approach, various configurations/sites of localized charge in the polaron model that give rise to light absorption in Li-doped γ-WO3 and γ-WO3-x. The coloration mechanism of h’-WO3 upon proton insertion most probably relies on similar effects.
The nanostructure of these new phases h’-WO3 and h’-H0.07WO3 is peculiar in the sense that it is obtained as two-dimensional (2D) nanostructures with (001) basal faces, which are perpendicular to the six-membered channels. Such a crystal habit is unusual for tunnel-based OMS solids, which grow preferentially as nanorods or nanowires along the tunnels axis46,47. In the case of h-WO3 and its bronzes, additives are necessary to obtain platelets37,48,49 and to our knowledge, the particles’ short dimension was never reported along the c axis. If the origin of this preferential growth mode requires further investigations, the consequence is that h’-WO3 and its bronze show a new structure but also an original structure–morphology relationship. The 2D nanostructure is combined with an original crystallographic orientation that provides optimal access to the tunnels and consequently to the microporosity of the material with short diffusion lengths for the insertion of foreign cations. N2 sorption revealed a specific surface area of 55 m² g−1 consistent with the dimensions deduced from microscopy (Supplementary Figure 15). This value is among the highest surface areas reported for pure WO3 and bronzes, especially mesoporous c-WO3-x and t-WO322. A priori, h’-WO3 with additional four-members tunnels features a more open structure than known W-O-based compounds. It also exhibits a novel texture with easy access to the tunnels, combined with nanostructuration for extensive exchange with the neighboring medium. This unprecedented combination pleads in favor of fast insertion and diffusion of cations in the structure. Swift insertion/deinsertion can be combined with the white-to-blue color change upon evolution from the stoichiometric oxide to the bronze and with the high stability of the h’-WO3 framework in acidic electrolytes, in order to build swift electrochromic systems. Tungsten oxides are efficient electrochromic materials17,21,50,51, but due to its crystal structure and texture, h’-WO3 and its proton bronze might yield even faster switch than known WO3 polymorphs16,17,19,20,21,43,47,52,53,54,55. This prompted us to build transparent electrodes for evaluation of aqueous electrochromic devices. The nanoscaled platelets were readily processed as transparent films by spin coating on conductive fluorine-doped tin oxide (FTO) substrates (Fig. 5a, b, SI). The film thickness was evaluated to 80–100 nm (Supplementary Figure 16), which corresponds to approximately 8–20 stacked nanoplatelets. For comparison, films made of classical h-WO3 nanoparticles (Supplementary Figure 17) with specific surface area similar to h’-WO3 were deposited. The electrochromic properties were then evaluated by using a standard three-electrodes cell. Because of the high stability of h’-WO3, we have focused on an acidic (H2SO4 0.1 mol L−1) aqueous electrolyte that imposes stringent requirements vs. possible dissolution of the electrode materials and in which electrochromic tungsten oxides usually show limited stability17. The electrochemical potentials used for coloration/discoloration switch were chosen to ensure reduction and oxidation reactions according to the cyclic voltammograms (Supplementary Figure 18). First, color switching was qualitatively evidenced by applying a square function between 0.8 and −0.8 V vs. AgCl/Ag (Fig. 5a, b) at high frequency of 0.2 Hz. Reversible oscillations between deep-blue and colorless states are observed for h’-WO3 (Supplementary Movie 1). These color changes suggest that the amount of protons into the h’-HxWO3 bronze can be controlled by electrochemical (de)insertion. Color variations with classical h-WO3 are less pronounced. Bronzes of h-WO3 with the same particle size give results similar to h-WO3. According to the I(t) curves (Fig. 5a, b), near-equilibrium conditions are reached upon bleaching (positive bias for oxidation) for both compounds and upon coloration (negative bias for reduction) for classical h-WO3. On the contrary, the equilibrium state is not reached in colored h’-WO3 but proton insertion is already sufficient to ensure important absorbance switch. Quantitative assessment was then performed. Electrochemical measurements were coupled with in situ UV-visible measurements at a wavelength of 700 nm (Supplementary Figure 19) by using as reference similar FTO electrodes, without deposited tungsten oxide. Conditions closer to equilibrium were sought by applying smaller voltage steps and lower frequency of ±0.2 V vs. AgCl/Ag and 0.009 Hz, respectively (Fig. 5c). For comparison, a h-WO3 film was studied in the same way (Fig. 5d, e). After an induction period of two cycles, absorbance changes are stabilized (Fig. 5c–e). I(t) (Fig. 5c, d, top) and absorbance (t) (Fig. 5c, d, bottom) curves show that steady-states are reached at each potential plateau. The transmittance of the h’-WO3 film shows strong changes compared with h-WO3, varying from 95% (absorbance of 0.05 in the bleached state) to 74% (absorbance of 0.26 in the colored state) within 13 s. This represents a much larger magnitude than for h-WO3 in the same time (from 91 to 88% in 13 s) and other tungsten oxides in the same electrolyte and redox conditions17. One can also expect a much deeper and faster switch if higher voltage steps are applied17,42. In our electrochemical conditions, the coloration efficiency (CE) at the fourth cycle was evaluated at 53 cm2 C−1 and 11 cm2 C−1 for h’-WO3 and h-WO3, respectively. The relatively high CE value compared with those reported in the literature17,42 for H+ intercalation and the large switching rates highlight the superior optical switch of the new hexagonal framework. Besides, the cycling stability over 150 cycles (16,500 s, Fig. 5e and Supplementary Figures 20 and 21) is excellent. The superior performances of the h’-WO3 framework vs. classical h-WO3 in terms of response time and extent of coloration, hence of proton (de)insertion, may be ascribed to two features. First, additional four-members (WO6)4 tunnels in the h’ phase can accommodate protons as suggested by STEM-ABF images (Supplementary Figure 11) and contribute to an increase in the coloration. Second, the original crystallographic orientation of the nanoplatelets provides optimal access to the tunnels of the h’ phase, whereas the channels of h-WO3 are accessible only from the tips of the nanorods (Supplementary Figure 17), with longer diffusion lengths for H+ (de)insertion, hence smaller (de)insertion rate. Overall, the novel WO3 polymorph h’-WO3 appears as an excellent candidate for the design of fast electrochromic devices.
Specificities of h’-WO3 and its proton bronze
A new polymorph of WO3, h’-WO3, and its proton bronze h’-H0.07WO3 have been discovered through a chimie douce pathway leading to the precipitation of the bronze, which could be oxidized in the stoichiometric framework by smooth thermal treatment. The new structure relies on an original hexagonal structure sharing three- and six-octahedra tunnels with the classical hexagonal h-WO3 structure, and containing additional four-octahedra channels. Besides the novelty of the crystal structure, the nanotexture is original and consists in 5 nm-thick nanoplatelets with the tunnels oriented perpendicularly to the basal face. The combination of microporosity with oriented nanostructure and high thermal and chemical stability is particularly suited to processes involving ions and molecules exchange and/or insertion. Among the large range of applications that can be foreseen, we have designed fast switching aqueous electrochromic devices by focusing on the ease and the rate of proton insertion. Compared with all previously known tungsten oxides, the new phase exhibits strong enhancement of the CE and coloration/decoloration cycling rate. Besides fast and stable electrochromics, this compound and its bronzes represent a realm of possibilities for water purification, separation, catalysis, electrocatalysis, energy conversion, and storage. These fields are currently under study. Finally, the stability of the novel W-O framework paves the way to a whole new family of compounds inspired from classical WO3 phases, including alkali and ammonium bronzes. Isovalent and aliovalent tungsten substitutions are also under investigation and might open the road to original nanomaterials with additional or improved functionalities.
The hydrogen bronze of h’-WO3 was prepared in hydrothermal conditions, as follows: sodium tungstate dihydrate, Na2WO4·2H2O (Sigma) was dissolved in Milli-Q water to obtain a 0.15 mol L−1 aqueous solution. 0.5 molar equivalents of hydrazine (molar ratio between hydrazine and W species) were added and the mixture was stirred for 1 h. Then the pH of the solution was adjusted to 0.6 with concentrated HCl (12 mol L−1). Starting at pH 7, a white amorphous compound is formed and becomes beige below pH 1. The solution is then stirred at room temperature (or in a bath regulated between 25 and 30 °C) overnight to let the amorphous compound evolve. After that step, the reaction medium is heated at 120 °C in a closed borosilicate vial for 12 h. After 12 h, the reaction flask is cooled down to room temperature, the colorless supernatant is disposed of and the deep-blue powder is washed by centrifugation until the supernatant pH is neutral. A whitish deposit, corresponding to classical h-WO3 pollution is observed on the lining and must not be taken with the blue powder. Otherwise, it can be removed by centrifugated separation at 1000 rpm for 30 min. The sample is then dried at 40 °C under vacuum before grinding for further characterization. The hydrogen bronze of h’-WO3 can also be obtained at 95 °C, by increasing the heating dwell time to 3 days.
XRD and structure resolution
The XRD patterns were recorded on a PanAlytical X’Pert Pro diffractometer equipped with a monochromator and using Cu Kα radiation. Details of the structure resolution are given in Supplementary information subsection “Structure resolution”. The XRD reflections for the orthorhombic WO3 structure were indexed along the ICDD file 04–007–2425.
SEM FESEM pictures were obtained using a Hitachi S3400-N operating at 5 kV. TEM images were recorded with a Tecnai spirit G2 apparatus operating at 120 kV. Atomic resolution characterization was performed on a JEOL JEMARM200cF electron microscope (Cold Emission Gun) operating at 80 kV provided with a spherical aberration corrector in probe (current emission density ∼0.7 × 10−12 A cm−2 and probe size ∼0.08 nm), a GIF-QuantumER spectrometer and an Oxford INCA-350 detector. Atomic resolution STEM-HAADF and STEM-ABF images were acquired using inner and outer collection semiangles of 68 and 280 mrad, respectively, for HAADF and 11 and 22 mrad, respectively, for ABF with a nominal camera length of 60 mm. The presence of sodium and nitrogen was evaluated by recording EDS spectra in areas of 2–5 nm2, with 50 s of total acquisition time.
UV-visible-near infrared reflectance spectroscopy
Absorption spectra between 200 and 2000 nm were calculated from total reflectance measurements on the compacted powder. These measurements were performed using a UV/Vis/NIR Perkin Elmer Lambda 900 with an integration sphere.
X-ray photoelectron spectroscopy
XPS has been performed at the Institut des Matériaux de Paris Centre on an OMicron apparatus operating at the incident energy of 1486.7 eV (Al K). Charge effects were minimized using a low energy electron beam. Powders were deposited on an indium substrate. Photoelectrons were collected with an angle of 90° with the sample surface. Measures were carried out with steps of 100 eV for the general spectra and 20 eV for the high-resolution spectra. The energy calibration was performed on the C 1-s peak, which possesses the lower energy (285 eV). The composition was then calculated using the Scofield photoemission effective section.
Electron spin resonance spectroscopy
The ESR and ferromagnetic resonance experiments were performed with a Bruker X-band spectrometer equipped with a SHQ resonator. The ESR spectra were lock-in detected with a modulation of the applied magnetic field at a frequency of 100 kHz and with a 10 Gauss modulation amplitude. The field offset of the electromagnet was measured with a Gaussmeter and the frequency was measured with microwave frequency counter. The samples were contained in quartz tubes. They were cooled down in a helium flow cryostat, which allowed varying the temperature between 4 K and 300 K. The samples could be photoexcited in situ with the unfiltered light from a HBO lamp or monochromatic light from an Ar ion laser.
34 mg of as-obtained powder were dispersed in 10 mL of a 1 mol L−1 NaCl solution prepared with MilliQ water previously saturated with nitrogen by bubbling for 30 min. The suspension was kept under nitrogen flow. The pH then dropped quickly and stabilized after 15 min at a value of 2.9. This value was used to evaluate the amount of protons released and then the H+/W ratio.
TGA/TDA experiments were performed on a Mettler LF1600 apparatus, under air and with a gas sweep of 30 mL min−1. The temperature increase was controlled at 10 °C min−1 between 25 and 1000 °C. Powder XRD patterns were recorded thanks to a thermal treatment chamber under air.
N2-sorption for specific surface area measurements was performed on a BEL Belsorp Max apparatus. Prior to measurements, the powders were dried at 120 °C under vacuum overnight using a BEL Belprep II apparatus. The specific surface area was evaluated by using the Brunauer, Emmett, and Teller model.
DFT calculations were performed with the Vienna ab initio simulation package (VASP)56 using the Projected Augmented Wave Method (PAW)57,58 applying the generalized gradient approximation (GGA). The GGA potential was developed using the PBE functional59. In a first step, all structural models were fully optimized using a plane wave energy cutoff of 550 eV. For h’-WO3, h-WO3, h’-WO3 faulted, and monoclinic WO3, we used respectively, 24, 12, 24, and 30 k points in the irreducible Brillouin zone. All optimizations converged with residual Hellman–Feynman forces on the atoms smaller than 0.03 eV/Å and led to reasonable structures in comparison with experimental ones. Then, the optimized structures were used for accurate electronic structure calculations employing a plane wave energy cutoff of 550 eV and an energy convergence criterion of 10−6 eV. Here, for h’-WO3, h-WO3, h’-WO3 faulted, and monoclinic m-WO3, we used respectively 56, 90, 56, and 170 k points in the irreducible Brillouin zone.
A 10 g L−1 suspension of h’-HxWO3 in ethanol was prepared by sonication during 1 h. Ten microliters were then deposited on an FTO substrates, which was spin coated at 2000 rpm for 10 s. This process was repeated five times. The same process was used to deposit classical h-WO3 films from nanorods of 10–15 nm in diameter and 100 nm in length, with a specific surface area of 45 m2 g−1 similar to the h’-WO3 sample. A surface of 0.785 cm2 was selected by a scotch tape containing a hole tapped with a 5 mm diameter punch. In the photoelectrochemical experiments, the working electrode was immersed in the electrolyte with a surface of 1.1 cm2 for h’-WO3 and 1 cm2 for h-WO3. The transparent electrode was connected by copper tape and a wire to a three-electrode setup with saturated AgCl/Ag as reference and a Pt counter electrode. The electrolyte was H2SO4 0.1 mol L−1. A voltage square function was applied with a Solartron Modilab potentiostat between 0.8 and −0.8 V vs. AgCl/Ag or 0.2 and −0.2 V vs. AgCl/Ag, at a frequency of 0.1 or 0.009 Hz. The background and the reference for UV-visible measurements during cycling was a cell filled with the electrolyte and containing a FTO electrode without tungsten oxide film.
The data generated and analyzed during the current study are available from the corresponding author on reasonable request.
Haw, J. F., Song, W., Marcus, D. M. & Nicholas, J. B. The mechanism of methanol to hydrocarbon catalysis. Acc. Chem. Res. 36, 317–326 (2003).
Shen, Y. et al. Manganese oxide octahedral molecular sieves: preparation, characterization, and applications. Science 260, 511–515 (1993).
Suib, S. L. Structure, porosity, and redox in porous manganese oxide octahedral layer and molecular sieve materials. J. Mater. Chem. 18, 1623–1631 (2008).
Feng, Q., Kanoh, H. & Ooi, K. Manganese oxide porous crystals. J. Mater. Chem. 9, 319–333 (1999).
Kanke, Y., Takayama-Muromachi, E., Kato, K. & Kosuda, K. Synthesis and crystal structure of Priderite-type barium vanadium oxide BaxV8O16 (x = 1.09(1)). J. Solid State Chem. 115, 88–91 (1995).
Djerdj, I. et al. Oxygen self-doping in hollandite-type vanadium oxyhydroxide nanorods. J. Am. Chem. Soc. 130, 11364–11375 (2008).
Gerand, B., Nowogrocki, G., Guenot, J. & Figlarz, M. Structural study of a new hexagonal form of tungsten trioxide. J. Solid State Chem. 29, 429–434 (1979).
Coucou, A. & Figlarz, M. A new tungsten oxide with 3D tunnels: WO3 with the pyrochlore-type structure. Solid State Ion. 30, 1762–1765 (1988).
Anderson, M. W. & Klinowski, J. Layered titanate pillared with alumina. Inorg. Chem. 17, 3260–3263 (1990).
Pless, J. D. et al. Tunable conductivity of collapsed sandia octahedral molecular sieves. Chem. Mater. 19, 4855–4863 (2007).
Shen, X., Morey, A., Liu, J. & Ding, Y. Characterization of the Fe-doped mixed-valent tunnel structure manganese oxide KOMS-2. J. Phys. Chem. C. 115, 21610–21619 (2011).
Chen, C.-H. et al. Structural distortion of molybdenum-doped manganese oxide octahedral molecular sieves for enhanced catalytic performance. Inorg. Chem. 54, 10163–10171 (2015).
Vasconcellos, C. M., Gonçalves, M. L. A., Pereira, M. M. & Carvalho, N. M. F. Iron doped manganese oxide octahedral molecular sieve as potential catalyst for SOx removal at FCC. Appl. Catal. A Gen. 498, 69–75 (2015).
Jin, L. et al. Titanium containing γ-MnO2 (TM) hollow spheres: one-step synthesis and catalytic activities in Li/Air batteries and oxidative chemical reactions. Adv. Funct. Mater. 20, 3373–3382 (2010).
Suib, S. L. Porous manganese sieves and octahedral layered materials. Acc. Chem. Res. 41, 479–487 (2008).
Xue, B. et al. High-contrast electrochromic multilayer films of molybdenum-doped hexagonal tungsten bronze (Mo0.05–HTB). J. Mater. Chem. 15, 4793–4798 (2005).
Zheng, H. et al. Nanostructured tungsten oxide - properties, synthesis, and applications. Adv. Funct. Mater. 21, 2175–2196 (2011).
Polleux, J., Gurlo, A. & Barsan, N. Template free synthesis and assembly of single crystalline tungsten oxide nanowires and their gas sensing properties. Angew. Chem. Int. Ed. 118, 267–271 (2006).
Deb, S. K. Opportunities and challenges in science and technology of WO3 for electrochromic and related applications. Sol. Energy Mater. Sol. Cells 92, 245–258 (2008).
Granqvist, C. Transparent conductive electrodes for electrochromic devices: a review. Appl. Phys. A Mater. Sci. Process. A 57, 19–24 (1993).
Livage, J. & Ganguli, D. Sol–gel electrochromic coatings and devices: a review. Sol. Energy Mater. Sol. Cells 68, 365–381 (2001).
Yoon, S., Kang, E., Kim, J. K., Lee, C. W. & Lee, J. Development of high-performance supercapacitor electrodes using novel ordered mesoporous tungsten oxide materials with high electrical conductivity. Chem. Commun. 47, 1021–1023 (2011).
Kumagai, N., Kumagai, N., Umetzu, Y., Tanno, K. & Pereira-Ramos, J. P. Synthesis of hexagonal form of tungsten trioxide and electrochemical lithium insertion into the trioxide. Solid State Ion. 86–88, 1443–1449 (1996).
Huang, K. et al. Controllable synthesis of hexagonal WO3 nanostructures and their application in lithium batteries. J. Phys. D. Appl. Phys. 41, 155417 (2008).
Aricò, A. S., Bruce, P., Scrosati, B., Tarascon, J.-M. & van Schalkwijk, W. Nanostructured materials for advanced energy conversion and storage devices. Nat. Mater. 4, 366–377 (2005).
Slade, R., West, B. & Hall, G. Chemical and electrochemical mixed alkali metal insertion chemistry of the hexagonal tungsten trioxide framework. Solid State Ion. 33, 154–161 (1989).
Cheng, K. & Whittingham, M. S. Lithium incorporation in tungsten oxides. Solid State Ion. 1, 151–161 (1980).
Zheng, M. et al. Tungsten-based materials for lithium-ion batteries. Adv. Funct. Mater. 28, 1707500 (2018).
Szilágyi, I. M. et al. WO3 photocatalysts: influence of structure and composition. J. Catal. 294, 119–127 (2012).
Zheng, T. et al. Conductive tungsten oxide nanosheets for highly efficient hydrogen evolution. Nano. Lett. 17, 7968–7973 (2017).
Grätzel, M. Photoelectrochemical cells. Nature 414, 338–344 (2001).
Kosmulski, M. Isoelectric points and points of zero charge of metal (hydr)oxides: 50 years after Parks’ review. Adv. Colloid Interface Sci. 238, 1–61 (2016).
Parks, G. A. The isoelectric points of solid oxides, solid hydroxides, and aqueous hydroxo complex systems. Chem. Rev. 65, 177–198 (1965).
Rodriguez-Carvajal, J. FULLPROF.2k: Rietveld, Profile Matching and Integrated Intensity Refinement of X-Ray and Neutron Data. Laboratoire Léon Brillouin, Saclay, France. (2001).
Ishikawa, R. et al. Direct imaging of hydrogen-atom columns in a crystal by annular bright-field electron microscopy. Nat. Mater. 10, 278–281 (2011).
Manthiram, K. & Alivisatos, A. P. Tunable localized surface plasmon resonances in tungsten oxide nanocrystals. J. Am. Chem. Soc. 134, 3995–3998 (2012).
Mattox, T. M., Bergerud, A., Agrawal, A. & Milliron, D. J. Influence of shape on the surface plasmon resonance of tungsten bronze nanocrystals. Chem. Mater. 26, 1779–1784 (2014).
Yan, J. et al. Tungsten oxide single crystal nanosheets for enhanced multichannel solar light harvesting. Adv. Mater. 27, 1580–1586 (2015).
Ingham, B., Hendy, S. C., Chong, S. V. & Tallon, J. L. Density-functional studies of tungsten trioxide, tungsten bronzes, and related systems. Phys. Rev. B - Condens. Matter Mater. Phys. 72, 3–6 (2005).
Song, H. et al. Synthesis of Fe-doped WO3 nanostructures with high visible-light-driven photocatalytic activities. Appl. Catal. B Environ. 166–167, 112–120 (2015).
Gerosa, M. et al. Electronic structure and phase stability of oxide semiconductors: performance of dielectric-dependent hybrid functional DFT, benchmarked against G W band structure calculations and experiments. Phys. Rev. B 91, 155201 (2015).
Liang, L. et al. High-performance flexible electrochromic device based on facile semiconductor-to-metal transition realized by WO3·2H2O ultrathin nanosheets. Sci. Rep. 3, 1936 (2013).
Balaji, S., Djaoued, Y. & Albert, A. Hexagonal tungsten oxide based electrochromic devices: spectroscopic evidence for the Li ion occupancy of four-coordinated square windows. Chem. Mater. 21, 1381–1389 (2009).
Ingham, B., Hendy, S. C., Chong, S. V. & Tallon, J. L. Density-functional studies of tungsten trioxide, tungsten bronzes, and related systems. Phys. Rev. B 72, 075109 (2005).
Bondarenko, N., Eriksson, O. & Skorodumova, N. V. Polaron mobility in oxygen-deficient and lithium-doped tungsten trioxide. Phys. Rev. B 92, 165119 (2015).
Portehault, D., Cassaignon, S., Baudrin, E. & Jolivet, J.-P. Morphology control of cryptomelane type MnO2 nanowires by soft chemistry. Growth mechanisms in aqueous medium. Chem. Mater. 19, 5410–5417 (2007).
Xiao, W., Liu, W., Mao, X., Zhu, H. & Wang, D. Na2SO4-assisted synthesis of hexagonal-phase WO3 nanosheet assemblies with applicable electrochromic and adsorption properties. J. Mater. Chem. A 1, 1261–1269 (2013).
Oaki, Y. & Imai, H. Room-temperature aqueous synthesis of highly luminescent BaWO4–polymer nanohybrids and their spontaneous conversion to hexagonal WO3 nanosheets. Adv. Mater. 18, 1807–1811 (2006).
Zhang, J., Wang, X. L., Xia, X. H., Gu, C. D. & Tu, J. P. Electrochromic behavior of WO3 nanotree films prepared by hydrothermal oxidation. Sol. Energy Mater. Sol. Cells 95, 2107–2112 (2011).
Granqvist, C. G. Electrochromic tungsten oxide: review of progress 1993-1998. Sol. Energy Mater. Sol. Cells 60, 201–262 (2000).
Niklasson, G. A. & Granqvist, C. G. Electrochromics for smart windows: thin films of tungsten oxide and nickel oxide, and devices based on these. J. Mater. Chem. 17, 127–156 (2007).
Joo, S., Raistrick, I. & Huggins, R. Rapid anisotropic diffusion of lithium in electrochromic thin films based on the hexagonal tungsten bronze structure. Solid State Ion. 17, 313–318 (1985).
Green, M., Smith, W. & Weiner, J. A thin film electrochromic display based on the tungsten bronzes. Thin. Solid. Films. 38, 89–100 (1976).
Judeinstein, P. & Livage, J. Electrochemical mechanisms of tungsten trioxide thin films. J. Chim. Phys. Phys.-Chim. Biol. 90, 137–147 (1993).
Kamal, H., Akl, A. A. & Abdel-Hady, K. Influence of proton insertion on the conductivity, structural and optical properties of amorphous and crystalline electrochromic WO3 films. Phys. B Condens. Matter 349, 192–205 (2004).
Kresse, G. & Furthmüller, J. Vienna Ab-initio Simulation Package (VASP). Institut für Materialphysik, Vienna. (2012).
Blöchl, P. E. Projector augmented-wave method. Phys. Rev. B 50, 17953–17979 (1994).
Kresse, G. & Joubert, D. From ultrasoft pseudopotentials to the projector augmented-wave method. Phys. Rev. B 59, 1758–1775 (1999).
Perdew, J. P., Burke, K. & Ernzerhof, M. Generalized gradient approximation made simple. Phys. Rev. Lett. 77, 3865–3868 (1996).
This work was financially supported by Solvay Company, CNRS, and Sorbonne Université. The authors acknowledge D. Montero and C. Calers from the Institut des Matériaux de Paris Centre for SEM and XPS, respectively. They also acknowledge Patricia Beaunier from Laboratoire de Réactivité de Surface for TEM. Financial support from Research Project MAT2014-54372-R (MINECO, Spain) is also acknowledged.
The authors declare no competing interests.
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Besnardiere, J., Ma, B., Torres-Pardo, A. et al. Structure and electrochromism of two-dimensional octahedral molecular sieve h’-WO3. Nat Commun 10, 327 (2019). https://doi.org/10.1038/s41467-018-07774-x
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