Table 2 Substrate scope for the enantioselective trap of carbazole-derived radicals

From: Enantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based EDA complex

  1. Reactions performed over 48 h at 35 °C on a 0.1 mmol scale using 1.5 equiv. of 4 under illumination by a single high-power (HP) LED (λmax = 420 nm)
  2. aYield and ee measured on the isolated 2 (average of two runs per substrate)
  3. bReaction time: 72 h
  4. cBenzoic acid (40 mol%) was used