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  • Original Article
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Reusable dismantlable adhesion interfaces induced by photodimerization and thermo/photocleavage reactions


Controlling adhesion strength during and after the use of bonded materials is crucial. Dismantlable adhesives play important roles in material recycling. However, typical dismantlable adhesives rely on the bulk properties of the adhesive, and specific control of dismantling behavior is challenging. Here, we successfully demonstrated the reusability of a dismantlable adhesion interface system, in which a cleavable molecular layer forms at the adhesion interface through reversible dimerization and cleavage reactions of anthracene. The adhesion peel test was conducted repeatedly by forming a cleavable layer on the substrate surface of the specimens. Strong bonding in the initial state and easy dismantling after stimulation were achieved even in the reused layer. Our strategy for constructing a dismantlable adhesion interface holds promise in material recycling.

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This work was supported by JSPS KAKENHI under grant number JP23K13808 and JST PRESTO under grant number JPMJPR21N1. This work was performed under the research programs “Dynamic Alliance for Open Innovation Bridging Human, Environment and Materials” and “Crossover Alliance to Create the Future with People, Intelligence and Materials” in the “Network Joint Research Center for Materials and Devices.”

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Correspondence to Miho Aizawa or Yoko Matsuzawa.

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Aizawa, M., Akiyama, H., Matsuzawa, Y. et al. Reusable dismantlable adhesion interfaces induced by photodimerization and thermo/photocleavage reactions. Polym J 56, 401–408 (2024).

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