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Design and structure of catalysts: syntheses of carbon dioxide-based copolymers with cyclic anhydrides and/or cyclic esters

Polymer Journal volume 53, pages 3–27 (2021)Cite this article

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Abstract

CO2-based poly(ester-co-carbonate)s synthesized through the copolymerization of epoxides and CO2 with cyclic anhydrides and/or cyclic esters have continuously received attention due to their tunable degradability and adjustable thermal and mechanical properties. A variety of catalysts have been developed for this methodology, including zinc, cobalt, and chromium complexes, which can provide well-defined polymers. In this review, we provide a thorough account of the catalysts used in the copolymerization of epoxides and CO2 with cyclic anhydrides and/or cyclic esters. The development direction and future perspectives of catalyst design are also discussed.

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Acknowledgements

The authors would like to thank the National Natural Science Foundation of China (Grant No. 51673131), and the Fundamental Research Funds for the Central Universities (171gjc37) for financial support of this work.

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  1. The Key Laboratory of Low-carbon Chemistry & Energy Conservation of Guangdong Province/State Key Laboratory of Optoelectronic Materials and Technologies, School of Materials Science and Engineering, Sun Yat-sen University, 510275, Guangzhou, PR China

    Jiaxin Liang, Shuxian Ye, Shuanjin Wang, Min Xiao & Yuezhong Meng

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  1. Jiaxin Liang
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  2. Shuxian Ye
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Liang, J., Ye, S., Wang, S. et al. Design and structure of catalysts: syntheses of carbon dioxide-based copolymers with cyclic anhydrides and/or cyclic esters. Polym J 53, 3–27 (2021). https://doi.org/10.1038/s41428-020-0374-1

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