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Butyralization of poly(vinyl alcohol) under supercritical carbon dioxide for a humidity-resistant adhesive to glass substrates

Polymer Journal volume 52, pages 1349–1356 (2020)Cite this article

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Abstract

Poly(vinyl butyral) (PVB) is widely accepted as an adhesive for glass substrates within the automobile windows. In this work, we suggested and performed butyralization of poly(vinyl alcohol) (PVA) under supercritical carbon dioxide (sc-CO2) and investigated not only the structure and mechanical properties of the obtained PVB but also its adhesion properties under various conditions, comparing this PVA with other PVBs prepared in the solution and swollen states. The conversion ratio of butyralization under sc-CO2 was larger than that in the swollen state and lower than that in the solution state and exhibited a sufficient material performance as the adhesive for glass substrates. The Young’s modulus and tensile strength of PVB under sc-CO2 were higher than those of the other PVBs. The mechanical properties of the PVB prepared under sc-CO2 have no correlation to the modification ratios because sc-CO2 penetrated into the amorphous region of the PVA and preferentially modified its hydroxyl groups. Furthermore, the adhesive strengths of all the obtained PVBs increased, and under a high-humidity atmosphere, the adhesive strength of the PVB prepared under sc-CO2 was the largest. The humidity resistance of the PVB adhesive prepared under sc-CO2 was proven.

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Acknowledgements

This work was supported by JSPS KAKENHI Grant Number JP12345678.

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Authors and Affiliations

  1. Department of Chemical Science and Engineering, Graduate School of Engineering, Kobe University Rokko, Nada, Kobe, 657-8501, Japan

    Takuya Matsumoto, Miyabi Yorifuji, Yuya Sugiyama & Takashi Nishino

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  1. Takuya Matsumoto
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  2. Miyabi Yorifuji
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  3. Yuya Sugiyama
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Correspondence to Takashi Nishino.

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Matsumoto, T., Yorifuji, M., Sugiyama, Y. et al. Butyralization of poly(vinyl alcohol) under supercritical carbon dioxide for a humidity-resistant adhesive to glass substrates. Polym J 52, 1349–1356 (2020). https://doi.org/10.1038/s41428-020-00402-w

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