Utilizing sequential layer-by-layer (LBL) coating and subsequent photopolymerization, we developed circular-polarizing and free-standing mirrors with a broad reflection bandwidth. Photopolymerizable cholesteric liquid crystal (CLC) paints were first prepared by considering the intrinsic chirality and the coating viscoelasticity. The polymer-stabilized nanostructures had finely tuned helical pitches that selectively reflected light over the entire visible wavelength range. The CLC films exhibited excellent thermomechanical properties and chemical stabilities, which enabled the preparation of patterned optical objects at macroscopic dimensions. The LBL coating and photopolymerization of the CLC paints demonstrated here can provide a simple solution for manufacturing flexible photonic devices with large areas at low cost.
The structural color and light control of photonic crystals have been the subject of intensive research1. Because incident light encounters multiple thin layers or helicoidally stacked nanostructures in photonic crystals, it is strongly reflected by the constructive interference between the reflections from the array of transparent materials2. When the periodic modulation due to the alternating high and low refractive indices is proportional to the visible wavelength region, the partial photonic bandgap is opened3. This light is completely reflected in the photonic crystal, and a selective wavelength with an iridescent color is observed4. Grubbs et al.5 prepared highly ordered reflectors via the nanophase separation of block copolymers. Thomas et al.6 fabricated color-tunable films by manipulating the face-centered cubic structure of nanoparticles. Self-organized periodic structures found in nature inspire the design and synthesis of new photonic elements7.
In this research, a cholesteric liquid crystal (CLC) that is paintable and polymerizable is used to prepare a flexible broadband mirror8,9. The CLC is a chiral version of a nematic mesophase10. It exhibits a Bragg reflection with the relationship λ0 = n × P0, where λ0 = notch position, n = average refractive index, and P0 = pitch length. The bandwidth (Δλ) of the CLC is determined by the birefringence of the LC and the length of the helical pitch (P), Δλ = Δn × P. The birefringence (Δn) is defined as (ne − no), where ne and no are the extraordinary and ordinary refractive indices, respectively. Due to the helicoidal superstructure, the selective reflection of the CLC is circularly polarized11. When unpolarized light is incident on a CLC, a maximum of 50% of the light is reflected (matching the circular handedness), and 50% of the light is transmitted.
This unique optical activity is derived from a helicoidally self-assembled feature of the CLC12. Generally, the addition of a chiral dopant to an achiral LC medium produces a helical nanostructure13. Because this method for achieving photonic materials is simple, many studies have focused on manipulating the reflection bandgap14. Earlier efforts to achieve broadband reflectors involved physically overlapping individual optical cells filled with CLCs with different P values15,16. Because CLCs respond to external stimuli, a broadband reflector can be fabricated by thermal diffusion to obtain a pitch gradient17,18. In some cases, a CLC containing a light-driven molecular switch is utilized because the helical twisting power (HTP) can be gradually changed along the film thickness direction by a noncontact method19. However, this method requires a large number of optical cells, and the device is difficult to manufacture due to its weight and the complexity of the electrical design20. Additionally, this type of low-molecular-weight system is disadvantageous because it cannot withstand a certain degree of mechanical deformation due to a lack of sufficient structural integrity21.
When photonic materials with free-standing character can be obtained, they can open routes to new applications, such as flexible devices22,23. In this respect, cholesteric polymers have been widely discussed because they exhibit both the orientational order of LC molecules and the elastic behaviors of polymeric networks24. Most studies of cholesteric polymers involve ultraviolet (UV) light-induced polymerization25. Broer et al.26 reported broadband reflectors with a distribution of P values, which arose due to the presence of asymmetric polymer networks that extended from the top to the bottom of the optical cell. However, another series of work was based on the diffusion-controlled phase separation of a reactive mesogen (RM)27. Thus, the polymerization rate should be precisely engineered to achieve the optimal effects by considering the intensity of the UV light, the concentration of the absorption dye, and the thickness of the substrate gap28.
Here the ability to fabricate flexible broadband mirrors by directly coating CLC paints consisting of chiral and achiral RM mixtures is explored. These new photonic materials exhibit excellent coating properties for both hard and flexible substrates that are flat and curved. The helical axis (HA) of the CLC paint is controlled by applying a shear force with a brush and applicator, which enables the discovery of brilliant reflection color in the visible range. Fast in situ photopolymerization of the CLC paints then freezes the helicoidal arrangement of the anisotropic molecules. Compared to the initial monomer state of the CLC paint, the thermomechanical stability of the polymer form in the crosslinked CLC film is significantly higher. Additionally, because phase separation is suppressed by the identical reactivities in the completely polymerizable system, the CLC film exhibits the same selective reflection of light as the CLC paint. In this work, the free-standing character and pitch-broadening of the CLC films are demonstrated. By applying continuous layer-by-layer (LBL) coatings of the CLC paints and subsequently photopolymerizing them in situ, three layers of red, green, and blue CLC films can be vertically stacked without the need for high-temperature curing for layer alignment, a mixture-filling process in the optical cell, and an adhesive lamination method for obtaining a single heterostructure.
Materials and methods
A chiral RM (cRM) with a helical twisting power of 22 μm−1 was synthesized according to a previously reported method29. The achiral RMs mRM and dRM were used as received without further purification. Irgacure 651 was used as the photoinitiator. The cRM, mRM, and dRM were homogeneously blended at 80 °C using a vortex mixer (WiseMix VM10) to give the CLC paints. The CLC films were prepared by performing a bar-coating (Elcometer 3580) method on bare glass at 25 °C. The thickness of CLC films was controlled to 10 μm by changing the height of the casting knife. The thickness was measured using digital micrometer calipers (Mitutoyo Absolute). For the photopolymerization, the samples were irradiated with an UV source (Ushio SP9) with a light intensity of 20 mW cm−2 for 10 min.
The optical textures of the cholesteric mesophases were studied by polarized optical microscopy (POM, Nikon Eclipse E600). The transmittance spectra were detected by an UV and visible spectrophotometer (Jasco Arsn733) to measure the reflection property. The conversion rate from the CLC paints to the CLC films was evaluated by Fourier transform infrared spectroscopy (FTIR, Jasco 300E). The thermal behaviors were determined by thermogravimetric analysis (TGA, TA Q50) and differential scanning calorimetry (DSC, TA Q20) at a heating rate of 10 °C min−1. The storage modulus (E′) and loss tangent (tan δ) of the CLC films were measured by dynamic mechanical analysis (TA Q800) with operating cantilevers of 10 mm × 5 mm × 10 μm. The mechanical stability was analyzed by a field adhesion test (ASTM D3359) and pencil-scratch test (ASTM D3363). One-dimensional (1D) wide-angle X-ray diffraction (WAXD) experiments were conducted with a Rigaku generator (Cu Kα 12 kW). The diffraction peak positions were calibrated with silicon crystals. For the scanning electron microscopy (SEM, Carl Zeiss 40VP) observations, the CLC films were completely frozen in liquid nitrogen for 15 min and then rapidly cut with a razor blade. The macroscopic photographs were obtained using a digital camera (Canon EOS 5D).
To achieve broadband photonic elements, CLC paints are first prepared using an optimized composition for coating. A cRM with a photopolymerizable methacrylate group is a core component of the CLC paints, as shown in Fig. 1a. Due to the presence of an R-configured naphthyl group, simply adjusting the concentration of the cRM in the nematic liquid crystal (NLC) medium enables the formation of cholesteric mesophases. In this study, a monoacrylate monomer (mRM) and a diacrylate monomer (dRM) are purposely used not only as the NLC host but also as chemical crosslinkers30. Based on the HTP of the cRM, the CLC paints are formulated with cRM:mRM:dRM weight percent ratios of 12:25:63, 10:25:65, and 8:25:67. Although the cholesteric mesophase of the CLC paints is only composed of the cRM and dRM, the mRM is also added to prevent the crystallization of the mixture (Fig. 1b). For the CLC paints obtained with the cRM and dRM, the growth of a needle-like texture is observed in the POM microphotographs after a few minutes (Figure S1 in the Supporting Information). However, the CLC paints with the mRM maintain their ordered structure without any phase separation, which results in their dramatically enhanced processability, even at the room temperature (Figure S2 in the Supporting Information). In the planar anchoring condition, the molecules lie down on the surface and the HA of self-assembled helical nanostructure is parallel to the surface normal. Therefore, the mRM and dRM mixtures doped with 12, 10, and 8 wt% cRM clearly exhibit the selective reflection of blue, green, and red light, respectively (insets in Fig. 1b).
CLC paints with unique optical properties and a suitable viscoelasticity can be used for various applications, such as architectural coatings, colorimetric sensors, and information displays31. In this work, the CLC paints are applied to artificial nails, evenly brushed in one direction and then irradiated with UV light to stabilize the ordered structure through the formation of a polymer network. As shown in Fig. 2a, the pinky, ring, and middle fingers covered with the CLC films are red, green, and blue, respectively. The ability to localize the presence and color of the CLC paints is further described. The artificial nails on the thumb and index fingers illustrate prototypical symbols of the cholesteric character. When the CLC paints described above are cast on a glass substrate, a free-standing and circular-polarizing photonic material with macroscopic dimensions can be fabricated. The cast sample is evenly sheared with a bar coater. Then, the in situ photopolymerization of the coated sample is performed to obtain a robust optical film. The photoinitiated polymerization is induced by exposure to 365 nm UV light for 10 min. Based on a field adhesion method (ASTM D3359), the CLC films exhibit better mechanical properties than the CLC paints (Figure S3 in the Supporting Information)32. For the CLC paints, approximately 80% of the crosshatch pattern is removed by the tape peel action. The adhesion grade of the CLC paints on the glass substrate is estimated to be 0 A. However, the crosshatch zone is undamaged for the CLC films on plastic (polyethylene terephthalate), glass (bare substrate), and metal (stainless steel) substrates. After the tape peel action, no debris is detected on the tested tape side. Therefore, the CLC films can be rated 4 A in terms of the adhesion strength. It is possible to fabricate the optically active layer directly on the substrate, which provides flexibility for designing optoelectronic devices.
The polymeric stabilization of the CLC paints can be easily handled with a tweezer (Fig. 2b). The thickness of the CLC films is controlled to 10 μm. The colors of the CLC films observed by the naked eye are nearly the same as those of the CLC paints. The proposed fully reactive cholesteric system is intentionally designed to minimize phase separation during photopolymerization33. The acrylate-functionalized chiral and achiral molecules exhibit identical reactivities. Therefore, the fast photopolymerization freezes the helical nanostructure. The photonic materials fabricated with 12, 10, and 8 wt% cRM have red (FR), green (FG), and blue (FB) colors, respectively. The corresponding characteristic light reflections are λmax = 435, 525, and 630 nm, respectively (Fig. 2c). These results also indicate good dimensional stability. The nearly identical positions of the reflection notches of the CLC paints and films indicate that the P value is not affected by the photopolymerization (Figure S4 in the Supporting Information). The thermomechanical properties of the CLC films are examined by a dynamic mechanical analyzer (DMA). In the example at the top, the FB sample exhibits good flexibility. It has a glass transition temperature (Tg) of 85 °C (obtained from the peak value of the tan δ curve) and a storage modulus (E′) of 1.2 GPa at room temperature (Fig. 2d). The thermomechanical properties determined by DMA are in good agreement with those measured by DSC, which confirms that Tg = 85 °C (Figure S5 in the Supporting Information). Under these conditions, the conversion of the chiral and achiral RMs is calculated by monitoring the change in the transmittance area of the FTIR peak at 810 cm−1, which is the out-of-plane bending vibration peak of the acrylate group34. Figure 2e shows that the conversion is 81%.
After the copolymerization of the chiral and achiral RMs, the CLC films are stable to chemical attack. The chemical stability of the CLC paints is first tested by dropping various solvents on them. The helical nanostructures of the CLC paints are damaged by the attack of organic solvents. For example, the CLC paints are fully dissolved and completely lose their reflection colors when exposed to chloroform. The ordered structure is disrupted by the penetration of the solvent molecules. However, the CLC films can withstand common organic solvents, as shown by the summarized results in Figure S6 in the Supporting Information. Based on the chemical stability tests, it is concluded that the construction of the crosslinked helical nanostructure is an effective method for obtaining robust photonic materials. Furthermore, it should be noted that it is possible to fabricate a patterned optical object if a photomask is applied35. Accordingly, washing the CLC films with chloroform safely removes only the unpolymerized regions. This result is illustrated in Fig. 3a. The butterfly-shaped object is free-standing (Fig. 3b). Due to the properties of the cholesteric mesophase, it retains the blue reflection and the notch at approximately 435 nm when probed with right-handed (RH) circularly polarized light (CPL). However, left-handed (LH) CPL is transmitted, and no reflection color is observed (Fig. 3c)36. The butterfly-shaped object is optically clear under irradiation with LH CPL. This optical property is further characterized in Fig. 3d.
Due to the ease of processability derived from the composition used here, flexible broadband mirrors that simultaneously reflect all visible light from blue to green to red can be fabricated by the sequential processes of repetitive casting, coating, and photocuring. The sequential layering of the photonic element is illustrated in Fig. 4a. First, the CLC paint with 12 wt% cRM is cast on a glass substrate (10 μm thickness) by a bar-coating process and then photopolymerized by UV light irradiation. As expected, the first layer (denoted F1) exhibits the blue reflection color. The second layer with the green reflection is directly cast on the F1 layer and photopolymerized. To produce F3, a third layer with 8 wt% cRM is prepared on the F2 layer using the same procedure. Figure 4b illustrates the stepwise change in the optical properties as the photonic element is constructed. Ultimately, a broad bandwidth (Δλ = 390 nm) reflection spectrum, which is three times that of the F1 layer and covers the entire visible wavelength range, is achieved for F3 with RH CPL. The reflection spectrum of the F2 layer is only approximately twice that of the F1 layer. The thermal stability of F3 is evaluated by TGA. The CLC films are thermally stable at approximately 300 °C and start to degrade above that temperature. The silver reflection of F3 is stable up to 300 °C, as expected for a heavily crosslinked polymer network (Figure S7 in the Supporting Information). Next, the pencil-scratch method (ASTM D3363) is utilized to determine the mechanical robustness of the CLC films. Due to their liquid crystalline nature and low molecular weight, the CLC paints maintain their long-range orientational order and the molecular mobility of isotropic liquids. Therefore, they do not resist any mechanical force. However, F3 is resistant to scratching up to HB (Figure S8 in the Supporting Information). When the pencil hardness is increased to 2H, the surface begins to be damaged37. It can be concluded that crosslinking the helical nanostructures is a robust method for protecting the photonic material.
The mirror-like silver reflection of F3 is illustrated in Fig. 5a. A common illustration of the cholesteric mesophase is visible behind F3 (Fig. 5b). The microstructures of the CLC films are observed by 1D WAXD. A broad peak appears at approximately 2θ = 20.13°, indicating the existence of the cholesteric mesophase (Figure S9 in the Supporting Information). The peak at 0.44 nm originates from the liquid-like correlation of the anisotropic molecules. The strong birefringence and oily streaked texture detected by POM further support the successful transfer of the chiral property and helical information of the CLC paints to the corresponding films (Figure S10 in the Supporting Information). To visualize the distinct helical nanostructures within the broadband mirrors, SEM is employed. As shown in Fig. 5c, the cross-sectional SEM image of F3 has a 30 μm-thick layer (three stacked 10 μm layers of CLCs). The lengths of Pred = 420 nm, Pgreen = 350 nm, and Pblue = 290 nm are measured. The red, green, and blue layers of F3 have 24, 28, and 34 pitches, respectively. Note that only a single helical nanostructure constructed by the self-assembly of the CLC paints in the red, green, and blue layers of F3 is schematically illustrated in Fig. 5d.
The Jones and Berreman method (a numerical model of light transmission and reflection in CLCs) indicates a minimum of 10 pitches for the total reflection notch depth38. Therefore, the maximum notch depth in this broadband mirror is 100% with RH CPL39. It is unexpected that F3 prepared by the LBL method on a laboratory scale exhibits a relatively high reflection notch depth (~80%). When the CLC paint is coated on a glass substrate, the direction of the HA changes as a function of the temperature, viscosity, substrate, and shear rate. The fabrication conditions used for F3 (relatively slow shear rate and low viscosity of the CLC paint) can result in an HA perpendicular to the coating direction, instead of a completely planar or fingerprint texture. When the CLC paints are coated on a glass substrate, the CLC layer has an air interface, which can induce the homeotropic alignment of the top layer of the film40. The second and third layers have the same homeotropic layers and a less ordered HA normal to the film direction. To improve the alignment of the HA perpendicular to the substrate, further study of the fabrication conditions for the alignment of the CLC paints is needed.
To fabricate circular-polarizing reflective and flexible mirrors with a broad bandwidth, photopolymerizable CLC paints were first prepared by considering not only the intrinsic chirality but also the coating viscoelasticity. The helical pitch of the CLC paints were predictably controlled by the amount of the cRM in the mRM and dRM. The polymer-stabilized helical nanostructures exhibited good chemical, thermal and mechanical stabilities for fabricating patterned optical objects. The SEM observations and X-ray diffraction patterns combined with optical calculations clearly showed that the sequentially LBL-coated CLC films had finely tuned helical pitches that reflected light over the entire visible wavelength range. The continuous LBL coating and subsequent in situ photopolymerization described here provides a simple solution for manufacturing large-area platforms and full-color elements at low cost.
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This work was supported by the Basic Research Laboratory (2015042417, Korea) and Air Force Office of Scientific Research (FA2386-17-1-4078, USA). D.-Y.K. appreciates the support of the Basic Science Research Program and CBNU Fellowship Program.
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Kim, DY., Lee, K.M., White, T.J. et al. Cholesteric liquid crystal paints: in situ photopolymerization of helicoidally stacked multilayer nanostructures for flexible broadband mirrors. NPG Asia Mater 10, 1061–1068 (2018). https://doi.org/10.1038/s41427-018-0096-4
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