Abstract
Background
Pyrotechnic displays often lead to significant increases in poor air quality. The widespread environmental fate—involving air, water, and spatial-temporal analyses—of fireworks-produced pollutants has seldom been investigated.
Objective
This study examined the environmental fate of pollutants from the largest fireworks event in the U.S.: Macy’s Fourth of July Fireworks show in New York City (NYC).
Methods
Real-time PM2.5 and gravimetric PM2.5 and PM10 were collected at locations along the East River of NYC. Airborne particles were assayed for trace elements (X-ray fluorescence) and organic and elemental carbon (OC/EC). River water samples were evaluated by ICP-MS for heavy-metal water contamination. Spatial-temporal analyses were created using PM2.5 concentrations reported by both EPA and PurpleAir monitoring networks for NYC and 5 other major metropolitan areas.
Results
The fireworks event resulted in large increases in PM2.5 mass concentrations at the river-adjacent sampling locations. While background control PM2.5 was 10–15 µg/m3, peak real-time PM2.5 levels exceeded 3000 µg/m3 at one site and 1000 µg/m3 at two other locations. The integrated gravimetric PM2.5 and PM10 concentrations during the fireworks event ranged from 162 to 240 µg/m3 and 252 to 589 µg/m3, respectively. Zn, Pb, Sb, and Cu more than doubled in river water samples taken after the event, while S, K, Ba, Cu, Mg, Fe, Sr, Ti, and Zn increased in airborne PM2.5 from the fireworks. Data from hyperlocal monitoring networks for NYC and other metropolitan areas yielded similar, but generally smaller, increases in PM2.5 levels.
Impact
Fireworks shows have been associated with environmental contamination. This comprehensive analysis considers the fate of pollutants from the largest annual U.S. pyrotechnic show through air, water, and hyperlocal temporal characterization.
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Data availability
The datasets generated during and/or analyzed during the current study are available from the corresponding author upon reasonable request.
References
Vaziri, A Taylor Swift Eras Tour: Santa Clara fines fireworks company after curfew-breaking shows. San Francisco Chronicle. 2023. https://www.sfchronicle.com/entertainment/article/taylor-swift-santa-clara-curfew-18277831.php.
American Pyrotechnics Association. U.S. Fireworks Industry Revenue Figures Breakdown by Industry Segment 2000–2022. Southport. 2023.
Consumer Product Safety Commission. Fireworks Annual Report. 2022. Retrieved from https://www.cpsc.gov/s3fs-public/2022-Fireworks-Annual-Report.pdf.
Attri AK, Kumar U, Jain VK. Formation of ozone by fireworks. Nature. 2001;411:1015–1015. https://doi.org/10.1038/35082634.
Licudine JA, Yee H, Chang WL, Whelen AC. Hazardous metals in ambient air due to new year fireworks during 2004–2011 celebrations in Pearl City, Hawaii. Public Health Rep. 2012;127:440–50. https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3366381/.
Jia C, Xue Z, Fu X, Sultana F, Smith LJ, Zhang Y, et al. Impacts of Independence Day fireworks on pollution levels of atmospheric polycyclic aromatic hydrocarbons (PAHs) in the U.S. Sci Total Environ. 2020;743:140774 https://doi.org/10.1016/j.scitotenv.2020.140774.
Liu Y, Ma W, Yin S, Li C, Xu K, Zhang C, et al. Quantification of enhanced VOC emissions from fireworks. Environ Pollut. 2022;315:120389 https://doi.org/10.1016/j.envpol.2022.120389.
Yu W, Xu R, Ye T, Abramson MJ, Morawska L, Jalaludin B, et al. Estimates of global mortality burden associated with short-term exposure to fine particulate matter (PM2·5). Lancet Planet Health. 2024;8:e146–e155. https://doi.org/10.1016/S2542-5196(24)00003-2.
Rajagopalan S, Al-Kindi SG, Brook RD. Air pollution and cardiovascular disease. J Am Coll Cardiol. 2018;72:2054–70. https://doi.org/10.1016/j.jacc.2018.07.099.
Gouder C, Montefort S. Potential impact of fireworks on respiratory health. Lung India. 2014;31:375–9.
Lall R, Ito K, Thurston GD. Distributed lag analyses of daily hospital admissions and source-apportioned fine particle air pollution. Environ Health Perspect. 2011;119:455–60. https://doi.org/10.1289/ehp.1002638.
What’s in fireworks, and what produces those colorful explosions? Chemical & Engineering News. 2017. Retrieved 19 Dec 2023, from https://cendevqa.acs.org/articles/95/i27/s-fireworks-produces-those-colorful.html.
Antimony trisulfide. American Chemical Society. 2006. Retrieved September 14, 2023, from https://www.acs.org/molecule-of-the-week/archive/a/antimony-trisulfide.html.
Juan CA, Pérez De La Lastra JM, Plou FJ, Pérez-Lebeña E. The chemistry of reactive oxygen species (ROS) revisited: outlining their role in biological macromolecules (DNA, lipids and proteins) and induced pathologies. Int J Mol Sci. 2021;22:4642 https://doi.org/10.3390/ijms22094642.
Zhang Z, Weichenthal S, Kwong JC, Burnett RT, Hatzopoulou M, Jerrett M, et al. A population-based cohort study of respiratory disease and long-term exposure to iron and copper in fine particulate air pollution and their combined impact on reactive oxygen species generation in human lungs. Environ Sci Technol. 2021;55:3807–18. https://doi.org/10.1021/acs.est.0c05931.
Lakey PSJ, Berkemeier T, Tong H, Arangio AM, Lucas K, Pöschl U, et al. Chemical exposure-response relationship between air pollutants and reactive oxygen species in the human respiratory tract. Sci Rep. 2016;6:32916 https://doi.org/10.1038/srep32916.
Sun J, Yu J, Shen Z, Niu X, Wang D, Wang X, et al. Oxidative stress-inducing effects of various urban PM2.5 road dust on human lung epithelial cells among 10 Chinese megacities. Ecotoxicol Environ Saf. 2021;224:112680 https://doi.org/10.1016/j.ecoenv.2021.112680.
Hickey C, Gordon C, Galdanes K, Blaustein M, Horton L, Chillrud S, et al. Toxicity of particles emitted by fireworks. Part Fibre Toxicol. 2020;17:28 https://doi.org/10.1186/s12989-020-00360-4.
Skalny AV, Lima TRR, Ke T, Zhou J-C, Bornhorst J, Alekseenko SI, et al. Toxic metal exposure as a possible risk factor for COVID-19 and other respiratory infectious diseases. Food Chem Toxicol. 2020;146:111809 https://doi.org/10.1016/j.fct.2020.111809.
Potter NA, Meltzer GY, Avenbuan ON, Raja A, Zelikoff JT. Particulate matter and associated metals: a link with neurotoxicity and mental health. Atmosphere. 2021;12:425 https://doi.org/10.3390/atmos12040425.
Zheng K, Zeng Z, Tian Q, Huang J, Zhong Q, Huo X. Epidemiological evidence for the effect of environmental heavy metal exposure on the immune system in children. Sci Total Environ. 2023;868:161691 https://doi.org/10.1016/j.scitotenv.2023.161691.
Arinola G, Dutta A, Oluwole O, Olopade C. Household air pollution, levels of micronutrients and heavy metals in cord and maternal blood, and pregnancy outcomes. Int J Environ Res Public Health. 2018;15:2891 https://doi.org/10.3390/ijerph15122891.
United States. 2011. Federal Hazardous Substances Act, 15 U.S.C. §§ 1261–1278.
Yerramsetti VS, Sharma AR, Gauravarapu Navlur N, Rapolu V, Dhulipala NSKC, Sinha PR. The impact assessment of Diwali fireworks emissions on the air quality of a tropical urban site, Hyderabad, India, during three consecutive years. Environ Monit Assess. 2013;185:7309–25. https://doi.org/10.1007/s10661-013-3102-x.
Han G, Gong W, Quan JH, Li J, Zhang M. Spatial and temporal distributions of contaminants emitted because of Chinese New Year’s Eve celebrations in Wuhan. Environ Sci: Process Impacts. 2014;16:916–23. https://doi.org/10.1039/C3EM00588G.
Camilleri R, Vella AJ. Effect of fireworks on ambient air quality in Malta. Atmos Environ. 2010;44:4521–7. https://doi.org/10.1016/j.atmosenv.2010.07.057.
Sijimol MR, Mohan M. Environmental impacts of perchlorate with special reference to fireworks—a review. Environ Monit Assess. 2014;186:7203–10. https://doi.org/10.1007/s10661-014-3921-4.
https://www.macys.com/s/fireworks/by-the-numbers/?lid=fireworks_cta-bythenumbers Macy’s Fourth of July fireworks 2023 - by the numbers. Macy’s Fourth of July Fireworks 2023—by the numbers. (n.d.)
Luglio DG, Katsigeorgis M, Hess J, Kim R, Adragna J, Raja A, et al. PM2.5 concentration and composition in subway systems in the Northeastern United States. Environ Health Perspect. 2021;129:027001 https://doi.org/10.1289/EHP7202.
U.S. EPA. Compendium Method IO-3.3, Determination of metals in ambient particulate matter using x-ray fluorescence (XRF) spectroscopy. 1999. EPA/625/R-96/010a.
https://www.cdc.gov/niosh/docs/2003-154/pdfs/5040.pdf National Institute for Occupational Safety and Health. (2003). Method 5040: Benzene. In NIOSH Manual of Analytical Methods (NMAM), Fourth Edition (pp. 1–9).
https://docs.airnowapi.org/ AirNow. (n.d.). AirNow API Documentation.
https://a816-dohbesp.nyc.gov/IndicatorPublic/beta/key-topics/airquality/realtime/ Real-Time Air Quality in NYC. (n.d.). Environment & Health Data Portal. Retrieved September 15, 2023.
U.S. EPA, O. (n.d.). PM 2.5 Policy and Guidance|Ambient Monitoring Technology Information Center|US EPA. Retrieved May 20, 2024, from https://www3.epa.gov/ttnamti1/pmpolgud.html.
https://www.R-project.org/ R Core Team (2022). R: A language and environment for statistical computing. R Foundation for Statistical Computing, Vienna, Austria
Personal Weather Station Dashboard | Weather Underground. (n.d.). Retrieved September 14, 2023, from https://www.wunderground.com/dashboard/pws/KNYNEWYO1130/table/2023-07-4/2023-07-4/daily.
Anastasiou E, Vilcassim MJR, Adragna J, Gill E, Tovar A, Thorpe LE, et al. Feasibility of low-cost particle sensor types in long-term indoor air pollution health studies after repeated calibration, 2019–2021. Sci Rep. 2022;12:14571 https://doi.org/10.1038/s41598-022-18200-0.
Barkjohn KK, Holder AL, Frederick SG, Clements AL. Correction and accuracy of PurpleAir PM2.5 measurements for extreme wildfire smoke. Sensors. 2022;22:9669 https://doi.org/10.3390/s22249669.
Delp WW, Singer BC. Wildfire smoke adjustment factors for low-cost and professional PM2.5 monitors with optical sensors. Sensors. 2020;20:3683 https://doi.org/10.3390/s20133683.
Mehadi A, Moosmüller H, Campbell DE, Ham W, Schweizer D, Tarnay L, et al. Laboratory and field evaluation of real-time and near real-time PM 2.5 smoke monitors. J Air Waste Manag Assoc. 2020;70:158–79. https://doi.org/10.1080/10962247.2019.1654036.
Darack E. weatherscapes: San Francisco Bay Area. Weatherwise. 2009;62:10–11. https://doi.org/10.3200/WEWI.62.1.10-11.
https://www.wunderground.com/history/daily/KSFO/date/2023-7-4 Personal Weather Station Dashboard | Weather Underground. (n.d.). Retrieved May 19, 2024
Agency for Toxic Substances and Disease Registry. Guidance for Inhalation Exposures to Particulate Matter. Atlanta, GA: U.S. Department of Health and Human Services, Public Health Service, 30 Sep 2020.
U.S. EPA. Integrated Science Assessment for Particulate Matter. Center for Public Health and Environmental Assessment Office of Research and Development U.S. Environmental Protection Agency Research Triangle Park, NC, 2019.
World Health Organization. WHO global air quality guidelines: particulate matter (PM2.5 and PM10), ozone, nitrogen dioxide, sulfur dioxide and carbon monoxide. World Health Organization. 2021. https://iris.who.int/handle/10665/345329.
Wang Y, Zhuang G, Xu C, An Z. The air pollution caused by the burning of fireworks during the lantern festival in Beijing. Atmos Environ. 2007;41:417–31. https://doi.org/10.1016/j.atmosenv.2006.07.043.
Vecchi R, Bernardoni V, Cricchio D, D’Alessandro A, Fermo P, Lucarelli F, et al. The impact of fireworks on airborne particles. Atmos Environ. 2008;42:1121–32. https://doi.org/10.1016/j.atmosenv.2007.10.047.
Wu G, Tian W, Zhang L, Yang H. The Chinese Spring Festival impact on air quality in china: a critical review. Int J Environ Res Public Health. 2022;19:9074 https://doi.org/10.3390/ijerph19159074. PMID: 35897443; PMCID: PMC9330068
Khan AA, Garsa K, Jindal P, Devara PCS. Effects of stubble burning and firecrackers on the air quality of Delhi. Environ Monit Assess. 2023;195:1170 https://doi.org/10.1007/s10661-023-11635-6.
Mukherjee T, Asutosh A, Pandey SK, Yang L, Gogoi PP, Panwar A, et al. Increasing potential for air pollution over megacity new delhi: a study based on 2016 Diwali episode. Aerosol Air Qual Res. 2018;18:2510–8. https://doi.org/10.4209/aaqr.2017.11.0440.
Rai P, Furger M, El Haddad I, Kumar V, Wang L, Singh A, et al. Real-time measurement and source apportionment of elements in Delhi’s atmosphere. Sci Total Environ. 2020;742:140332 https://doi.org/10.1016/j.scitotenv.2020.140332.
Shamsipur M, Pourmortazavi SM, Hajimirsadeghi SS. An investigation on decomposition kinetics and thermal properties of copper-fueled pyrotechnic compositions. Combust Sci Technol. 2011;183:575–87. https://doi.org/10.1080/00102202.2010.523032.
Pourmortazavi SM, Hajimirsadeghi SS, Kohsari I, Fathollahi M, Hosseini SG. Thermal decomposition of pyrotechnic mixtures containing either aluminum or magnesium powder as fuel. Fuel. 2008;87:244–51. https://doi.org/10.1016/j.fuel.2007.04.022.
Tchounwou PB, Yedjou CG, Patlolla AK, Sutton DJ. Heavy metals toxicity and the environment. EXS. 2012;101:133–64. https://doi.org/10.1007/978-3-7643-8340-4_6.
Sengul AB, Asmatulu E. Toxicity of metal and metal oxide nanoparticles: a review. Environ Chem Lett. 2020;18:1659–83. https://doi.org/10.1007/s10311-020-01033-6.
Stafoggia M, Oftedal B, Chen J, Rodopoulou S, Renzi M, Atkinson RW, et al. Long-term exposure to low ambient air pollution concentrations and mortality among 28 million people: results from seven large European cohorts within the ELAPSE project. Lancet Planet Health. 2022;6:e9–e18. https://doi.org/10.1016/S2542-5196(21)00277-1.
Brunekreef B, Strak M, Chen J, Andersen ZJ, Atkinson R, Bauwelinck M, et al. Mortality and morbidity effects of long-term exposure to low-level PM2.5, BC, NO2, and O3: an analysis of European cohorts in the ELAPSE Project. Res Rep. (Health Eff Inst). 2021;2021:1–127.
Caplow T, Schlosser P, Ho DT, Enriquez RC. Effect of tides on solute flushing from a strait: imaging flow and transport in the east river with SF 6. Environ Sci Technol. 2004;38:4562–71. https://doi.org/10.1021/es035248d.
Wilkin RT, Fine DD, Burnett NG. Perchlorate behavior in a municipal lake following fireworks displays. Environ Sci Technol. 2007;41:3966–71. https://doi.org/10.1021/es0700698.
Pyrotechnics For The Planet. (n.d.). Chemical & Engineering News. Retrieved January 10, 2024, from https://cen.acs.org/articles/86/i26/Pyrotechnics-Planet.html.
Steinhauser G, Klapötke TM. Green” pyrotechnics: a chemists’ challenge. Angew Chem (Int Ed Engl). 2008;47:3330–47. https://doi.org/10.1002/anie.200704510.
https://www.bbc.com/news/av/world-us-canada-66116286 Drone show displays light up the sky on Fourth of July. (n.d.). Retrieved 10 Jan. 2024
Acknowledgements
The authors would like to note the support of NYU’s NIEHS Training Grant T32E007324. We thank friends of the authors for providing rooftops on which to conduct the Fourth of July exposure assessment.
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AFS and DL assisted in conceiving and designing the analysis, collecting the data, performing the analysis, and were primary in writing the paper. TG conceived and designed the analysis, contributed data or analysis tools, and assisted in performing the analysis and writing the paper. BK, TH, and RK assisted in designing the analysis, collecting the data, performing the analysis, and in writing the paper. AR, KT, NCR, RG, and JG assisted in conceiving and designing the analysis, collecting the data, and performing the analysis. MK and RG assisted in conceiving and designing the analysis and collecting the data. TK and MC assisted in collecting the data and contributing data or analysis tools.
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Saporito, A.F., Gordon, T., Kim, B. et al. Skyrocketing pollution: assessing the environmental fate of July 4th fireworks in New York City. J Expo Sci Environ Epidemiol (2024). https://doi.org/10.1038/s41370-024-00701-x
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DOI: https://doi.org/10.1038/s41370-024-00701-x