Abstract
The hydrolytic co-condensation of hydrophobic phenyltriethoxysilane (PTES) and hydrophilic γ-aminopropyltriethoxysilane (APS) under basic catalysis in the presence of sodium dodecyl sulfate (SDS) was investigated. Copolymer particles were influenced significantly by APS/PTES molar ratios, total monomer and SDS concentration. Amino group content of the copolymer was determined by element analysis and back titration. Scanning electron micrographs revealed the morphologies of the copolymer particles. FT-IR, solid state 29Si NMR and TGA were used to characterize the copolymer.
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R. H. Baney, M. Itoh, A. Sakakibara, and T. Suzuki, Chem. Rev., 95, 1409 (1995).
K. M. Kim, T. Ogoshi, and Y. Chujo, J. Polym. Sci., Part A: Polym. Chem., 43, 473 (2005).
M. C. Gravel, C. Zhang, M. Dinderman, and R. M. Laine, Appl. Organomet. Chem., 13, 329 (1999).
Y. Kaneko, N. Iyi, T. Matsumoto, K. Fujii, K. Kurashima, and T. Fujita, J. Mater. Chem., 13, 2058 (2003).
F. J. Feher and K. D. Wyndham, Chem. Commun., 3, 323 (1998).
D. R. Bujalski, H. P. Chen, G. A. Zank, and K. Suo, Macromolecules, 36, 3529 (2003).
A. Matsuda, T. Tanaka, K. Tadanaga, T. Minami, and M. Tatsumisago, J. Mater. Sci., 39, 903 (2004).
S. E. Tunney, G. A. Rakes, and B. K. Coltrain, U.S. Patent 5 384 376 (1995).
S. E. Tunney, G. A. Rakes, and B. K. Coltrain, Chem. Abstr. 123, P145607w (1995).
S. M. Liu, X. M. Lang, H. Ye, S. J. Zhang, and J. Q. Zhao, Eur. Polym. J., 41, 996 (2005).
C. Ma and Y. Kimura, Polym. J., 34, 709 (2002).
C. Ma, I. Taniguchi, M. Miyamoto, and Y. Kimura, Polym. J., 35, 270 (2003).
N. Tsubokawa, T. Iida, and T. Takayama, J. Appl. Polym. Sci., 75, 515 (2000).
R. M. Ottenbrite, J. S. Wall, and J. A. Siddiqui, J. Am. Ceram. Soc., 83, 3214 (2000).
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Liu, S., Ye, H., Zhou, Y. et al. Hydrolytic Co-condensation of Phenyltriethoxysilane with γ-Aminopropyltriethoxysilane in the Presence of Sodium Dodecyl Sulfate. Polym J 38, 220–225 (2006). https://doi.org/10.1295/polymj.38.220
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DOI: https://doi.org/10.1295/polymj.38.220
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