Abstract
Polysilsesquioxane having phenyl and mercapto groups (PMPSQ) was prepared from (3-mercaptopropyl)trimethoxysilane (MTMS) and phenyltrimethoxysilane (PTMS) by co-condensation under basic conditions. The polymerization utilizing mercapto groups on PMPSQ with dimethylacrylamide (DMAA) under UV irradiation was shown to be a simple and convenient procedure for the formation of the graft polymer (PMPSQ-g-PDMAA). In the photo-initiated radical polymerization, no gelation was observed. The introduction of hydrophilic graft chain was effective to transform the hydrophobic polysilsesquioxane PTMS into the amphiphilic PMPSQ-g-PDMAA, which was evaluated by the measurements of contact angle.
Similar content being viewed by others
Article PDF
References
O. Moriya, S. Yamamoto, T. Kumon, T. Kageyama, A. Kimura, and T. Sugizaki, Chem. Lett., 33, 224 (2004).
R. H. Baney and X. Cao, in “Silicon-Containing Polymers,” R. G.Johns, W. Ando, and J. Chojnowski, Ed., Kluwer, Dordrecht, 2000.
C.-L. Chang and C.-C. M. Ma, J. Polym. Sci., Part A: Polym. Chem., 41, 1371 (2003).
K. Bridget and B. Vincent, Eur. Polym. J., 16, 1017 (1980).
B. M. Novak, Adv. Mater., 12, 675 (1993).
A. P. Alivisatos, Science, 271, 933 (1996).
C. Bartholome, E. Beyou, E. Bourgeat-Lami, P. Chaumont, and N. Zydowicz, Macromolecules, 36, 7946 (2003).
H. Zhao, S. D. Argoti, B. P. Farrell, and D. A. Shipp, J. Polym. Sci., Part A: Polym. Chem., 42, 918 (2004).
D. Xiano and M. J. Wirth, Macromolecules, 35, 2919 (2002).
V. M. Litvinov, H. Barthel, and J. Weis, Macromolecules, 36, 4356 (2003).
J. Pyun, K. Matyjaszewski, J. Wu, G.-M. Kim, S. B. Chun, and P. T. Mather, Polymer, 44, 2739 (2003).
S. C. Hong, J.-F. Lutz, Y. Inoue, C. Strissel, O. Nuyken, and K. Matyjaszewski, Macromolecules, 36, 1075 (2003).
J. Bay, K.-U. Qiu, and Y. Wen, Polym. Int., 52, 853 (2003).
R. P. Steer and A. R. Knight, J. Phys. Chem., 72, 2145 (1968).
L. Lecamp, F. Houllier, B. Youssef, and C. Bunnel, Polymer, 42, 2727 (2001).
M. Horio, Y. Nishijima, T. Fujimoto, K. Ozawa, C. Kujirai, Y. Nakamura, and T. Kondo, Appl. Polym. Symp., 1971, 513.
M.-Y. Huang, R. Wu, and L.-R. Jiang, Polym. Bull., 9, 5 (1983).
N. Tsubokawa, T. Kimoto, and K. Koyama, Colloid Polym. Sci., 271, 940 (1993).
P. Xia, H. Cheng, and D. Van, J. Appl. Polym. Sci., 45, 579 (1992).
M. Anthonietti, S. Förster, J. Hartmann, and S. Oestreich, Macromolecules, 29, 3800 (1996).
M. Sciborek, N. K. Gladkova, and J. Chojnowski, Polym. Bull., 44, 377 (2000).
Y. Matsubara, W. Konishi, T. Sugizaki, and O. Moriya, J. Polym. Sci., Part A: Polym. Chem., 39, 2125 (2001).
O. Moriya, M. Fukushima, T. Sugizaki, Y. Nakamura, and T. Endo, J. Polym. Sci., Part A: Polym. Chem., 40, 286 (2002).
E. F. S. Vieira, J. de A. Simoni, and C. Airoldi, J. Mater. Sci., 7, 2249 (1997).
I. M. El-Nahhal, J. J. Yang, I.-S. Chuang, and G. E. Maciel, J. Non-Cryst. Solids, 208, 105 (1996).
L. Mercier and T. J. Pinnavaia, Adv. Mater., 9, 500 (1997).
C. Ma and Y. Kimura, Polym. J., 34, 709 (2002).
E. Lippma, M. Magi, A. Samonson, G. Engelhardt, and A. G. Grimmer, J. Polym. Sci., Part A: Polym. Chem., 37, 1017 (1999).
N. Takamura, T. Gunji, H. Hatano, and Y. Abe, J. Polym. Sci., Part A: Polym. Chem., 37, 1017 (1999).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Yamamoto, Si., Shimada, T., Kimura, A. et al. Graft Polymerization of Dimethylacrylamide onto Polysilsesquioxane Containing Mercapto Groups. Polym J 36, 761–768 (2004). https://doi.org/10.1295/polymj.36.761
Published:
Issue Date:
DOI: https://doi.org/10.1295/polymj.36.761
Keywords
This article is cited by
-
Thiol-Ene photopolymerization of well-defined hybrid graft polymers from a ladder-like polysilsesquioxane
Macromolecular Research (2015)