Abstract
The amphiphilic hyperbranched poly(dimethylsiloxane) (HPDMS) bearing dimethylamine groups on the terminal position was synthesized and characterized. The obtained polymer exhibited low viscosity, and good solubility in ether, THF, and acidic aqueous solution. In the acidic aqueous polymer solution, UV-vis absorption and photo luminescence of water-insoluble chromic compounds such as diphenylhexatriene were measured in order to investigate solvating power of hyperbranched poly(dimethylsiloxane)s. It has turned out from the UV absorbance data that a HPDMS solubilized about five molecules of 1,6-diphenylhexatriene.
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Kim, KM., Jikei, M. & Kakimoto, Ma. Synthesis and Properties of Amphiphilic Hyperbranched Poly(dimethylsiloxane) Possessing Hydrophilic Terminal Group. Polym J 34, 755–760 (2002). https://doi.org/10.1295/polymj.34.755
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DOI: https://doi.org/10.1295/polymj.34.755
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