Abstract
Alteration of the solubility of 4,4′-Hexafluoroisopropylidene diphtalic anhydride-4,4-oxydianline polyimide was investigated through experimental (the solubility experiments and equilibrium swelling) and theoretical (group contribution method by Fedors). In solubility experiments, total solubility obtained by a two dimensional representation (δv vs. δh diagram) was 21.23 (J cm-3)1/2. The range of total solubility determined from the equilibrium swelling method was between 22.71 and 22.99 (J cm-3)1/2. The total solubility of 6FDA-4, 4′ODA polyimide calculated from the group contributions was 22.22 (J cm-3)1/2. The difference of solubility is slightly existed between experimental and theoretical method, but showed very good agreement
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Chun, KY., Park, JH., Jang, SH. et al. Alteration of the Solubility of 4,4′-Hexafluoroisopropylidene Diphtalic Anhydride-4,4-Oxydianline Polyimide by Experimental and Theoretical Methods. Polym J 32, 406–410 (2000). https://doi.org/10.1295/polymj.32.406
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DOI: https://doi.org/10.1295/polymj.32.406
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