Abstract
We have synthesized the poly(β-hydroxy ketone)s 1 and poly(β-hydroxy ester)s 2 by means of a novel polyaddition reaction of bis(triethylsilyl enol ether) 5 and bis(triethylsilyl ketene acetal) 7 with various dialdehydes 8–10, respectively. When chirally modified Lewis acids were used as catalyst for the polyaddition, optically active polymers were obtained.
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Komura, K., Nishitani, N. & Itsuno, S. A Novel Approach to the Synthesis of Optically Active Poly(β-hydroxy carbonyl)s by Aldol Polymerization Based on Mukaiyama Aldol Reaction. Polym J 31, 1045–1050 (1999). https://doi.org/10.1295/polymj.31.1045
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DOI: https://doi.org/10.1295/polymj.31.1045