Abstract
Comb-like polymers (CP) based on modified alternating methyl vinyl ether/maleic anhydride copolymer with oligo-oxyethylene side chains of the type -O(CH2CH2O)nCH3 have been synthesized and characterized, and complexed with lithium salts to form amorphous polymer electrolytes. CP/salt complexes showed conductivity up to 10−5 S cm−1 at room temperature. The temperature dependence of ionic conductivity suggests that the ion transport is controlled by segmental motion of the polymer, shown by linear curves obtained in Vogel-Tammann-Fulcher plots. The ionic conductivity maximum moves to a higher salt concentration as the temperature increases. IR results indicate that the ester in CP might decompose at 140°C and reproduce the maleic anhydride ring.
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Ding, L., Shi, J., Yang, C. et al. Ionic Conductivity of Solid Polymer Electrolytes Based on Modified Alternating Maleic Anhydride Copolymer with Oligo(oxyethylene) Side Chains. Polym J 29, 410–416 (1997). https://doi.org/10.1295/polymj.29.410
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DOI: https://doi.org/10.1295/polymj.29.410
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