Abstract
The miscibility between partially methoxylated poly(4-hydroystyrene) with poly(vinyl acetate), poly(methyl acrylate), and poly(ethyl acrylate) was assessed based on glass transition temperature over the entire composition range. Quantitative analyses of the fraction of hydrogen bonded carbonyl groups were made by FT-IR spectroscopy for all systems. Good correlation between thermal behavior and infrared results was observed. The results are discussed considering the influence of two factors on miscibility, decrease of —OH---C=O hydrogen bonds in the blend and autoassociation as a function of methoxylation degree.
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Sanchis, A., Prolongo, M., Rubio, R. et al. Hydrogen-Bonded Polymer Blends. Blends Containing Poly(4-hydroxystyrene-co-4-methoxystyrene) Copolymers. Polym J 27, 10–20 (1995). https://doi.org/10.1295/polymj.27.10
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DOI: https://doi.org/10.1295/polymj.27.10