Abstract
Simultaneous polymerization and formation of poly(propargyl alcohol) (POHP) films by [Pd(C≡CCH2OH)2(PPh3)2](Pd–C) catalyst in CH2Cl2–CCl4 mixed solvent system have been investigated. Some features and kinetic behavior for the OHP polymerization are described and discussed. The overall polymerization activation energy was found to be 76.4 k J mol−1 and the rate equation can be expressed as Rp=kp[OHP][Pd–C], where kp=1.32×10−3 L mol−1s−1 (58°C). The POHP polymer obtained is a black sheeny film stable in air and chlorinated by CH2Cl2–CCl4 mixed solvent. Its conducting properties were investigated.
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Yang, M., Sun, H. & Chen, W. Simultaneous Polymerization and Formation of Poly(propargyl alcohol) Films by a Novel Palladium Catalyst. Polym J 27, 928–933 (1995). https://doi.org/10.1295/polymj.27.928
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DOI: https://doi.org/10.1295/polymj.27.928
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