Abstract
Simulation of macromolecular reactions (intramolecular crosslinking and hydrolysis of poly(vinyl acetate)) having conformational effect was carried out, and the experimental data and the calculated data based on Monte-Carlo procedure were compared. The situation with rate constants data on polymer-analogous reactions described in the literature was critically reviewed by taking into account the ambiguity of the quantitative conclusions made, and a mathematical procedure to find correct data is proposed. The reverse tasks in polymer physics were analyzed on the example of the 1H NMR spectroscopy of polymeric thermotropic liquid crystals, and an original approach to derive valuable information on the orientational structure in a smectic polymer from its 1H NMR spectrum is proposed.
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Platé, N., Stroganov, L. & Noah, O. Simulation and Reverse Tasks in Macromolecular Reactions and Structure of Polymeric Liquid Crystals. Polym J 19, 613–622 (1987). https://doi.org/10.1295/polymj.19.613
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DOI: https://doi.org/10.1295/polymj.19.613