Abstract
Selective oxygen permeation through the films of p-(oligosiloxanylstyrene) was investigated, and the role of the oligosiloxane substituents is discussed based on a dissolution-diffusion mechanism. The oligosiloxane side chains were found to play an important role to enhance the diffusion of oxygen.
Similar content being viewed by others
Article PDF
References
Y. Kawakami, T. Aoki, H. Hisada, Y. Yamamura, and Y. Yamashita, Polym. Comm., 26, 133 (1985).
Y. Kawakami, H. Karasawa, T. Aoki, Y. Yamamura, H. Hisada, and Y. Yamashita, Polym. J., 17, 1159 (1985).
R. Adams and C. R. Noller, Org. Synth., Coll. Vol. I, 109 (1939).
Huang-Minlon, J. Am. Chem. Soc., 68, 2487 (1946).
Huang-Minlon, J. Am. Chem. Soc., 71, 3301 (1949).
D. Todd, Org. React., 4, 378 (1948).
K. Tamao, K. Sumitani, Y. Kiso, M. Zenbayashi, A. Fujioka, I. Nakajima, A. Minato, and M. Kumada, Bull. Chem. Soc. Jpn., 49, 1958 (1976).
H. A. Daynes, Proc. R. Soc. London, Ser. A, 97, 286 (1920).
R. M. Barrer, Trans. Faraday Soc., 35, 628 (1939).
R. M. Barrer, Trans. Faraday Soc., 35, 644 (1939).
W. A. Rogers, R. S. Burity, and D. Alpert, J. Appl. Phys., 25, 868 (1954).
A. S. Michaels and H. J. Bixler, J. Polym. Sci., 50, 413 (1961).
R. M. Bawer and H. T. Chio, J. Polym. Sci., C, 10, 111 (1966).
T. Nakagawa, “Makugaku Nyuumon”, Kitami Syobou, Tokyo, 1978, p 273.
J. A. Barrie and K. Munday, J. Membr. Sci., 13, 175 (1983).
K. D. Ziegel and F. R. Eirich, J. Polym. Sci., A-2, 8, 2015 (1970).
H. Fujita, A. Kishimoto, and K. Matsumoto, Trans. Faraday Soc., 56, 424 (1960).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kawakami, Y., Karasawa, H., Kamiya, H. et al. The Role of p-Oligosiloxane Substituents of Polystyrene in Selective Oxygen Permeation through the Polymer Film. Polym J 18, 237–241 (1986). https://doi.org/10.1295/polymj.18.237
Issue Date:
DOI: https://doi.org/10.1295/polymj.18.237