Abstract
The polymerization of terephthalaldehyde and hexamethylenediamine to obtain a film-forming high molecular weight polyimine solution was considerably facilitated through the use of m-cresol as a solvent under mild conditions. The reaction was reversible, though the equilibrium favored a high product concentration. A crystalline but partially cross-linked powder and film were obtained from the solution.
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Suematsu, K., Nakamura, K. & Takeda, J. Polyimine, a C=N Double Bond Containing Polymers: Synthesis and Properties. Polym J 15, 71–79 (1983). https://doi.org/10.1295/polymj.15.71
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DOI: https://doi.org/10.1295/polymj.15.71
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