Abstract
In order to test the validity of previously developed formulas for the partial molar volume Vp0 of a 1—2 binary copolymer in a mixture of two solvents, density measurements were carried out on styrene–methyl methacrylate and p-chlorostyrene-methyl acrylate copolymers dissolved in the relevant monomer(s). The values of the six parameters necessary to compute Vp0 were determined for each system, and some comments have been made on the individual parameter values. The predicted values of Vp0 were in good agreement with those directly measured. Based on the results, numerical expressions for the volume contraction factors for the low-conversion copolymerizations of the two monomer pairs were derived.
Similar content being viewed by others
Article PDF
References
T. Fukuda, Y.-D. Ma, M. Nagata, and H. Inagaki, Polym. J., 14, 729 (1982).
T. Fukuda, Y.-D. Ma, and H. Inagaki, Polym. J., 14, 705 (1982).
T. M. Aminabhavi and P. Munk, Macromolecules, 12, 1186 (1979).
B. Rosen, J. Polym. Sci., 17, 559 (1955).
W. Heller and A. C. Thompson, J. Colloid Sci., 6, 57 (1951).
G. V. Schulz and M. Hoffmann, Makromol. Chem., 23, 220 (1957).
A. Horth, D. Patterson, and M. Rinfret, J. Polym. Sci., 39, 189 (1959).
T. Fukuda, M. Nagata, Y.-D. Ma, and H. Inagaki, Polym. Prepr., Jpn., 31, 2153 (1982).
M. Griffel, R. S. Jessup, J. A. Cogliano, and R. P. Park, J. Res. Natl. Bur. Stand., 52, 217 (1954).
B. Trathnigg, Makromol. Chem., 181, 1979 (1980).
J. Francois and F. Candau, Eur. Polym. J., 9, 1355 (1973).
Th. G. Scholte, J. Polym. Sci., A-2, 8, 841 (1970).
H. Inagaki, Makromol. Chem., 75, 217 (1964).
A. Nakazawa, Y. Murakami, T. Kotaka, and H. Inagaki, Bull. Inst. Chem. Res., Kyoto Univ., 53, 387 (1975).
F. Tüdös, T. Kelen, and T. F. Berezhnikh, J. Polym. Sci., Polym. Symp., 50, 109 (1975).
J. A. Seiner and M. Litt, Macromolecules, 4, 308 (1971).
M. Kamachi, Adv. Polym. Sci., 38, 56 (1981).
H. J. Harwood and W. M. Ritckey, J. Polym. Sci., B, 2, 601 (1964).
Y.-D. Ma, T. Fukuda, and H. Inagaki, to be published.
A. Nakajima, H. Sotobayashi, and I. Sakurada, Kobunshi Kagaku, 14, 566 (1957).
W. Mächtle and H. Fischer, Angew. Makromol. Chem., 7, 147 (1969).
D. Braun and G. Disselhoff, Polymer, 18, 963 (1977).
G. G. Cameron and J. Cameron, Polymer, 14, 107 (1973).
D. J. Streeter and R. F. Boyer, Ind. Eng. Chem., 43, 1970 (1951).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ma, YD., Fukuda, T. & Inagaki, H. Free-Radical Copolymerization II. Volume Contraction Factors for Some Copolymerization Systems. An Approach Based on Partial Specific Volume. Polym J 15, 673–681 (1983). https://doi.org/10.1295/polymj.15.673
Issue Date:
DOI: https://doi.org/10.1295/polymj.15.673
Keywords
This article is cited by
-
Synthesis and characterization of crosslinked transparent poly(ester-urethane-acrylate) containing methyl methacrylate
Macromolecular Research (2017)