Abstract
A condensation polymer (β-CD-E) of β-CD with epichlorohydrin was compared with β-CD and poly(β-CD acrylate) in regard to inclusion behavior in an aqueous solution. The stability of the inclusion complexes of β-CD-E with substrates of a single guest part is smaller than that of β-CD because of steric hindrance by substituents on β-CD. On the other hand, the stability of β-CD-E complexes for substrates with two guest parts is much larger than that of β-CD and is somewhat smaller than that of poly(β-CD acrylate). This is due to the cooperation in binding of the adjacent two CD units on a polymer chain.
Similar content being viewed by others
Article PDF
References
M. L. Bender and M. Komiyama, “Cyclodextrin Chemistry,” Springer-Verlag, Berlin, 1978.
W. Saenger, Angew. Chem. Int. Ed. Engl., 19, 344 (1980).
A. Harada, M. Fume, and S. Nozakura, Macromolecules, 9, 701 (1976).
A. Harada, M. Furue, and S. Nozakura, Macromolecules, 9, 705 (1976).
A. Harada, M. Furue, and S. Nozakura, Macromolecules, 10, 676 (1977).
A. Harada, M. Furue, and S. Nozakura, Polym. J., 12, 29 (1980).
N. Wiedenhof, J. N. J. J. Lammers, and C. L. van Panthaleon van Eck, Staerke, 21, 119 (1969).
P. Colson, H. J. Jennings, and I. C. P. Smith, J. Am. Chem. Soc., 96, 8081 (1974).
J. B. Stothers, “Carbon-13 NMR Spectroscopy,” Academic Press, New York, 1972, p 139.
S. Umezawa and K. Tatsuta, Bull. Chem. Soc. Jpn., 41, 464 (1968).
I. M. Klotz and D. L. Hunston, Biochemistry, 10, 3065 (1971).
T. Kinoshita, F. Iinuma, and A. Tsuji, Chem. Pharm. Bull., 23, 1166 (1975).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Harada, A., Furue, M. & Nozakura, Si. Inclusion of Aromatic Compounds by a β-Cyclodextrin–Epichlorohydrin Polymer. Polym J 13, 777–781 (1981). https://doi.org/10.1295/polymj.13.777
Issue Date:
DOI: https://doi.org/10.1295/polymj.13.777
Keywords
This article is cited by
-
Cyclodextrin-based hyperbranched polyester: synthesis, characterization, and antimicrobial activity
Journal of Coatings Technology and Research (2018)
-
A novel β-cyclodextrin polymer modified by sulfonate groups
Journal of Inclusion Phenomena and Macrocyclic Chemistry (2012)
-
Rendering cellulose fibers antimicrobial using cationic β-cyclodextrin-based polymers included with antibiotics
Cellulose (2009)
-
Cyclodextrin-based pharmaceutics: past, present and future
Nature Reviews Drug Discovery (2004)
-
Preparation of insoluble β-CD polymer and its application to enantiomers and isomers separation
Journal of Central South University of Technology (2001)