Abstract
Dichlorofluoroacetaldehyde was prepared from methyl dichlorofluoroacetate by reduction with lithium aluminum hydride. Highly purified dichlorofluoroacetaldehyde was polymerized using various cationic and anionic initiators to a crystalline insoluble polymer or an amorphous soluble polymer, depending on polymerization conditions. It could be stabilized and the thermal degradation behavior was compared with polymers of other perhaloacetaldehydes. The monomer was also copolymerized with other haloacetaldehydes and phenyl pocyanate.
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Yamada, B., Campbell, R. & Vogl, O. Haloaldehyde Polymers. VIII. Preparation and Polymerization of Dichlorofluoroacetaldehyde. Polym J 9, 23–31 (1977). https://doi.org/10.1295/polymj.9.23
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DOI: https://doi.org/10.1295/polymj.9.23