Abstract
The glass transition^{1} is considered to be one of the most fundamental problems in statistical physics. Despite decades of effort, a general consensus on the validity of a universal theory for the large variety of glass systems is lacking^{2,3}—partly because of difficulties encountered in the experimental testing of the theoretical predictions^{4,5}. Here, we present experiments on a colloidal glass made of micrometresized particles in a fluid. We investigate the autocorrelation and response function to monitor the ageing of a colloidal glass. At equilibrium, all the observables are stationary, whereas in the outofequilibrium glassy state they have an explicit dependence on the age of the system. We find that the transport coefficients scale with the ageing time as a power law, a signature of the slow relaxation. Nevertheless, our analysis reveals that the glassy system has thermalized at a constant temperature independent of the age and warmer than the bath, reflecting the structural rearrangements of cage dynamics. Furthermore, we find a universal scaling law to describe the global and local fluctuations of the observables.
Main
Increasing the volume fraction of a colloidal system slows down the brownian dynamics of its constitutive particles, implying a limiting density, φ_{g}, above which the system can no longer be equilibrated with its bath^{1}. Hence, the thermal system falls out of equilibrium on the timescale of the experiment and thus undergoes a glass transition^{2}. Even above φ_{g} the particles continue to relax, but the nature of the relaxation is very different to that in equilibrium. This phenomenon of a structural slow evolution beyond the glassy state is known as 'ageing'^{3}. The system is no longer stationary and the relaxation time is found to increase with the age of the system, t_{w}, as measured from the time of sample preparation.
This picture applies not only to structural glasses such as colloids, silica and polymer melts, but also to spin glasses, ferromagnetic coarsening, elastic manifolds in quenched disorder and jammed matter such as grains and emulsions^{2,4,5}. Theories originally developed in the field of spin glasses^{6} attempt to develop a common framework for the understanding of ageing. For example, the structural glass and spinglass transitions have been coupled by the lowtemperature extension of the modecoupling theory^{4,5,7}. More generally, this approach is related to analogous ideas developed in the field of granular matter such as compactivity^{8,9,10,11}, and the inherent structure formalisms^{12}, adapted to the energy landscape of glasses^{13}.
One of the important features of this scenario is a separation of timescales where the observables are equilibrated at different temperatures, even though the system is far from equilibrium. Although theoretical results have flourished, the difficulties in the experimental testing of the fundamental predictions of the theories have hampered the development of an understanding of ageing in glasses^{14,15,16,17,18}. Experiments so far have shown conflicting results, which are usually masked by large intermittent fluctuations in the observables^{17}; a behaviour which seems beyond the current theoretical formalisms^{2}. On the other hand, some numerical results are more favourable^{19,20,21}. Furthermore, the concept of temperature has been shown to be useful to describe other far from equilibrium systems such as nonthermal granular materials^{9,10,11}.
Here we use a model glass that is one of the simplest systems undergoing a glass transition: a colloidal glass of micrometresized particles, where the interactions between particles can be approximated as hard core potentials^{1,22,23}. The system is index matched to allow the visualization of tracer particles in the microscope^{23}. Owing to the simplicity of the system, we are able to follow the trajectories of magnetic tracers embedded in the colloidal sample and use this information as an ideal 'thermometer' to measure the temperature for the different modes of relaxation. In turn, we measure the autocorrelation function of the displacements and the integrated response to an external magnetic field as an indicator of the dynamics via a fluctuationdissipation theorem (FDT). For this system we show that, even though the diffusivities and mobilities of the tracers scale with the age of the system, there is an effective temperature which is uniquely defined and remains constant independent of the age. This effective temperature is higher than the bath temperature and controls the slow relaxation of the system, as if the system was at 'equilibrium'. We find a scaling behaviour with the waiting time, which describes, in a unified way, not only the global but also the local fluctuations of the correlations and responses as well as the cage dynamics in the system.
Correlations and responses
Our experiments use a colloidal suspension consisting of a mixture of poly(methylmethacrylate) sterically stabilized colloidal particles (radius a_{p}=1.5 μm, density ρ_{p}=1.19 g cm^{−3}, polydispersity ∼14%) plus a small fraction of superparamagnetic beads (radius a_{m}=1.6 μm and density ρ_{m}=1.3 g cm^{−3}, from Dynal Biotech) as the tracers (see the Methods section for further details). To investigate the dynamical properties of the ageing regime, we first consider the autocorrelation function as the mean square displacement (MSD) averaged over 82 tracer particles, C(t,t_{w})≡〈Δx^{2}(t,t_{w})〉/2=〈[x(t_{w}+Δt,t_{w})−x(t_{w},t_{w})]^{2}〉/2, at a given observation time, t=t_{w}+Δt, after the sample has been ageing for t_{w} as measured from the end of the stirring process (see Supplementary Information, Appendix C). Then, we measure the integrated response function (by adding the external magnetic force, F) given by the average position of the tracers, χ(t,t_{w})≡〈x(t_{w}+Δt,t_{w})−x(t_{w},t_{w})〉/F.
Analytical extensions of the modecoupling theory for supercooled liquids to the lowtemperature regime of glasses allow for the interpretation of the ageing of global correlation and response functions^{2,5}. In these frameworks, the evolution of C(t,t_{w}) and χ(t,t_{w}) are separated into a stationary part (short time) and an ageing part (long time): C(t,t_{w})=C_{st}(t−t_{w})+C_{ag}(t,t_{w}) and χ(t,t_{w})=χ_{st}(t−t_{w})+χ_{ag}(t,t_{w}), where we have included the explicit dependence on t_{w} in the ageing part.
This result can be rationalized in terms of the socalled 'cage dynamics'. As the density of the system increases the particles are trapped in cages. The motion inside the cage is still equilibrated at the bath temperature and is determined by the Gibbs distribution of states. The dynamics give rise to the stationary part of the response and correlation functions, which satisfy the usual equilibrium relations such as the FDT. However, the correlation does not decay to zero but remains constant because particles are trapped in cages for a long time. Thermally activated motions lead to a second structural relaxation that is responsible for the ageing part of the dynamics. In this regime the system is off equilibrium, and correlations and responses depend not only on the time of observation t but also on the waiting time, t_{w}. Slow, nonexponential relaxation ensues and a violation of the FDT is expected. However, this breakdown leads to a new definition of temperature for the slow modes, which has been proposed to be the starting point of a unifying description of ageing in glassy systems^{2}.
Figure 1a shows 〈Δx^{2}(t,t_{w})〉 as a function of Δt at a fixed t_{w}=100 s calculated for the three colloidal samples at φ_{C}<φ_{g}<φ_{A}<φ_{B}, and Fig. 1b shows the age dependence for the glassy sample A. Sample B shows t_{w} dependence similar to sample A, whereas sample C, being at equilibrium, is independent of t_{w}, that is, it is stationary (see Supplementary Information, Appendix E).
The cage dynamics are evinced by the plateau observed in the MSD in the two glassy samples. The rattling of particles inside the cages is too fast (∼10^{−2} s)^{24} to be observed with our visualization capabilities. As we focus mainly on the longrelaxationtime regime, the stationary parts, C_{st} and χ_{st}, are negligible compared with C_{ag} and χ_{ag}, in the following we concentrate only on the ageing part of the observables and drop the subscript ag: C=C_{ag} and χ=χ_{ag}. The tracers' motion is confined by the cage, which persists for a time of the order of the relaxation time τ(t_{w}). As expected for an ageing system, this relaxation time increases with t_{w} as observed in Fig. 1b. For longer times, Δt>τ(t_{w}), structural rearrangements lead to a second increase of the MSD, defining a diffusion regime characterized by a diffusion constant, D(t_{w}), which depends on the waiting time. We find an asymptotic form:
Figure 1c shows the average displacement of the magnetic beads under the external force as a function of time Δt, for various ageing times, t_{w}, in sample A. The magnetic force is set as small as possible to observe the linearresponse regime, F=1.7×10^{−14} N (see Supplementary Information, Appendix F). In contrast to the behaviour of the MSD, the integrated response function does not show the plateau characteristic of the cage effect. The data can be fitted to:
where M(t_{w}) is the mobility of the tracers, which is again waitingtime dependent as seen in the figure.
To investigate the nature of the scaling behaviour of the ageing regime, we study the dynamical behaviour with respect to t_{w}. Figure 2 shows both the diffusivity and mobility as a function of t_{w} for sample A. Both D(t_{w}) and M(t_{w}) decrease with t_{w} signalling the slowing down in the dynamics. More importantly, they decrease according to a power law with the same exponent for both quantities:
with γ=0.32±0.08. This result is consistent with previous work in a similar ageing colloidal system, where it was found that the MSD 〈Δx^{2}〉 has a powerlaw decay with t_{w} (ref. 25). The fact that all the quantities scale as power laws indicates that the ageing regime lasts for a very long time, perhaps without ever equilibrating.
Effective temperature
The same powerlaw decay of the diffusivity and mobility implies that the system has thermalized at a constant effective temperature T_{eff} independent of t_{w}. This temperature is given by an extension of the Stokes—Einstein relation or FDT to outofequilibrium systems. Even though both D and M depend on the age of the system, their ratio is constant:
The inset of Fig. 2 plots T_{eff} as a function of t_{w}. We obtain T_{eff}≈690 K, which is more than double the ambient temperature of 297 K. For very large t_{w}, T_{eff} shows large fluctuations that are mainly due to the larger statistical error (owing to the limited number of tracers) in obtaining the mobilities and diffusivities in the large Δt and t_{w} regime. It remains a question whether the longwaitingtime regime may show interrupted ageing.
Equation (2) is easy to understand when the system is at equilibrium: we extract energy from many identical tracers located in distant regions of the colloidal system and transfer it to the thermometer system. The thermometer receives work from the diffusive motion of the tracers, and it dissipates energy through the viscosity of the system. These two opposing effects make the thermometer stabilize at a temperature guaranteed by the Einstein relation. Naturally, we have applied the diffusionmobility calculations to dilute sample C and find that it is equilibrated at the bath temperature (see Supplementary Information, Appendix E). On the other hand, the colloidal sample is ageing out of equilibrium. Nevertheless, the fact that the ratio of diffusion to mobility yields a constant temperature can be taken as an indication that the longtime behaviour of the system has thermalized at a larger effective temperature T_{eff}≈690 K.
Although it may seem counterintuitive that the slow relaxation at long times corresponds to a temperature that is actually higher than the equilibrium bath temperature, there is an interesting physical picture that rationalizes this observation. One can think of the energy landscape of configurations of the colloidal glass being explored less frequently, yet the amplitude of the jumps between basins corresponds to 'hotter' explorations of a broader distribution of energy states. Although this mechanism violates the usual relations between particle motion and temperature, it gives rise to the effective temperature measured in our experiments.
Scaling ansatz for the global correlations and responses
Further insight into the understanding of the slow relaxation can be obtained from the study of the universal dynamic scaling of the observables with t_{w}. On the basis of spinglass models, different scaling scenarios have been proposed^{2,26} for correlation and response functions. Our analysis indicates that the observables can be described as
where f_{D} and f_{M} are two universal functions and α and β are the ageing exponents. Evidence for the validity of these scaling laws is provided in Fig. 3 where the data of the correlation function and the integrated response function collapse onto a master curve when plotted as t_{w}^{α}C(t_{w}+Δt,t_{w}) and t_{w}^{α}χ(t_{w}+Δt,t_{w}) versus Δt/t_{w}^{β}. By minimizing the σ^{2} value of the difference between the master curve and the data (see Supplementary Information, Appendix H) we find that the best data collapse is obtained for the following ageing exponents: α+β=0.34±0.05 and β=0.48±0.05. We find (Fig. 3) that the scaling functions satisfy the following asymptotic behaviour:
in agreement with the fact that the motion of the particles is diffusive at long times, 〈Δx^{2}〉∼Δt, and the existence of a welldefined mobility, respectively. Therefore at long times, both the correlation and response functions exhibit the same powerlaw decay:
The result C(t_{w}+Δt,t_{w})∼χ(t_{w}+Δt,t_{w})∼t_{w}^{−0.34} confirms our previous result, equation (1), D(t_{w})∼M(t_{w})∼t_{w}^{−0.32}. This is in further agreement with the finding that T_{eff} is independent of the age of the system, t_{w}. For short times, the MSD scaling function crosses over to a subdiffusive behaviour of the particles. We obtain, 〈x^{2}(t_{w}+Δt,t_{w})〉∼t_{w}^{−α}(Δt/t_{w}^{β})^{0.3}=t_{w}^{−0.004}Δt^{0.3}. As the trapping time corresponds to the size of the cages denoted by q(t_{w}), we can determine the cage dependence on t_{w} as q(t_{w})∼t_{w}^{−0.002}. The resulting exponent is so small that we can say that the cages are not evolving with the waiting time, within experimental uncertainty. Furthermore, the scaling ansatz of equation (3a) indicates that the relaxation time of the cages scales as τ(t_{w})∼t_{w}^{β} because this is the time for the subdiffusive behaviour to cross over to the longtime diffusive regime.
From Fig. 3 we see that the asymptotic Δt linear regime appears when the reduced variable Δt/t_{w}^{β}>10. The time separation between Δt and t_{w} can be determined using the cutoff: Δt/t_{w}^{0.48}∼10. For smaller times, Δt/t_{w}^{β}<10, we obtain a subdiffusion regime (with exponent 0.3), which is characteristic of the cage dynamics. For longer times, Δt/t_{w}^{β}>10, we observe the asymptotic Δt linear regime where the diffusivity is calculated. The measurement of MSD in Fig. 1 extends up to t_{w}=6,000 s. For this t_{w}, the separation of timescales appears when Δt>10×6,000^{0.48}≃10^{3} s. Our measurements for MSD extend to 10^{4} s, ensuring a separation of timescales even for this longest waiting time. For the smaller t_{w} considered in the calculation of T_{eff}, the separation of timescales is even more pronounced. For instance, for a typical t_{w}=1,000 s where the T_{eff} is calculated, the separation of timescales occurs at 10×1,000^{0.48}≃275 s, again ensuring a welldefined longtime asymptotic behaviour for Δt=10^{4} s.
Although the existence of an effective temperature can be rationalized using theoretical frameworks of disordered spinglass models^{4}, we find that the scaling forms of the correlations and responses are not consistent with such models. On the basis of invariance properties under time reparametrization, spinglass models predict a general scaling form C_{ag}(t,t_{w})=C_{ag}(h(t)/h(t_{w})), where h(t) is a generic monotonic function^{2}. We find that the scaling of our observables from equations (3a), (3b) cannot be collapsed with the ratio h(t)/h(t_{w}). The scaling with h(t)/h(t_{w}) is expected for a system in which the correlation function saturates at long times^{27}. On the other hand, our system is diffusive, and the studied correlation function is not bounded. Indeed, similar scaling as in our system has been found in the ageing dynamics of another unbounded system: an elastic manifold in a disordered media^{28}. The suggestion is that this problem and that of particle diffusing in a colloidal glass may belong to the same universality class. Furthermore, our results can be interpreted in terms of the droplet picture of the ageing of spin glass, where the growth of the dynamical heterogeneities controls the ageing.
Local fluctuations of autocorrelations and responses
Previous work has revealed the existence of dynamical heterogeneities, associated with the cooperative motion of the particles, as a precursor to the glass transition as well as in the glassy state^{22,23,25,29}. Instead of the average global quantities studied above, the existence of dynamical heterogeneities requires a microscopic insight into the structure of the glassy state. Earlier studies focused mainly on probability distributions of the particles’ displacement near the glass transition. More recent analytical work in spin glasses^{30} shows that the probability distribution function (PDF) of the local correlation P(C) and the local integrated response P(χ) could reveal essential features of the dynamical heterogeneities.
Here we carry out a systematic study of P(C) and P(χ) in sample A, and the resulting PDFs are shown in Fig. 4. The scaling ansatz of equation (3a) implies that P(C) and P(χ) should be collapsed by rescaling the time Δt by t_{w}^{β} and the local fluctuations by t_{w}^{α} (see Supplementary Information, Appendix I for further details). Indeed, this scaling ansatz provides the correct collapse of all the local fluctuations captured by the PDFs, as shown in Fig. 4a,b,c for P(C) and in Fig. 4d for P(χ).
The PDF of the autocorrelation function exhibits a universal behaviour following a modified power law t_{w}^{−α}P(C)∝ (t_{w}^{α}C+C_{0})^{−λ}, where C_{0} and λ only depend on the time ratio Δt/t_{w}^{β}. For the smaller values of C (C<t_{w}^{−α}C_{0}), the existence of a flat plateau in P(C) indicates that the tracers are confined in the cage. For larger values of C, the salient feature of the PDF is the very broad character of the distribution, with an asymptotic behaviour P(C)∼C^{−λ}. This large deviation from a gaussian behaviour is a clear indication of the heterogeneous character of the dynamics. Furthermore, the exponent λ decreases from 2.6 to 1.4 with the time ratio Δt/t_{w}^{β} ranging from 10 to 60. We notice that λ=2 corresponds to the crossover between the shorttime and longtime regime in Fig. 3, where Δt/t_{w}^{β}≈40. The significance of λ=2 is seen in the integral . For λ>2 (Δt/t_{w}^{β}<40), the plateau dominates over the powerlaw tail in the integral and the dynamics is less heterogeneous. For λ<2 (Δt/t_{w}^{β}>40) the powerlaw tail dominates and this regime corresponds to the highly heterogeneous longtime regime (see Supplementary Information, Appendix J).
In contrast, P(χ), shown in Fig. 4d, exhibits a different behaviour. The fluctuations are more narrow and the PDF can be approximated by a gaussian. This is consistent with the fact that we did not find cage dynamics for the global response in Fig. 1c. Moreover, numerical simulations of spinglass models^{30} seem to indicate a narrower distribution as found here.
We have presented experimental results on an ageing colloidal glass showing a welldefined temperature for the slow modes of relaxation of the system. This T_{eff} is larger than the bath temperature because it implies largescale structural rearrangements of the particles. In other words, it controls the cooperative motion of particles needed to relax the cages. The interesting result is that this temperature remains constant independent of the age, even though both the diffusivity and the mobility are age dependent. The powerlaw scaling found to describe the transport coefficients indicates the slow relaxation of the system. A universal scaling form is found to describe all the observables. That is, not only the global averages, but also the local fluctuations. The scaling ansatz, however, cannot be described using present models of spin glasses, but it is more akin to that observed in elastic manifolds in random environments, suggesting that our system may share the same universality class.
Methods
Experimental details
The colloidal suspension is immersed in a solution containing 76% weight fraction of cyclohexylbromide and 24% cisdecalin, which are chosen for their density and index of refraction matching capabilities^{23}. For such a system the glass transition occurs at φ_{g}≈0.57—0.58 (refs 1, 22, 23). In our experiments, we consider three samples at different densities and determine the glassy phase for the samples that exhibit ageing. The main results are obtained for sample A just above the glass transition φ_{A}=0.58±0.01. We also consider a denser sample, B, with φ_{B}=0.60±0.01, although this sample is so deep in the glassy phase that we are not able to study the slow relaxation of the system and the dependence of the waiting time within the timescales of our experiments. Finally, we also consider a sample C below the glass transition φ_{C}=0.13±0.01<φ_{g} for which we find the usual equilibrium relations. Before our measurements, the samples are homogenized by stirring for 2 h to achieve a reproducible initial time (see Supplementary Information, Appendix A for a full discussion).
We use a magnetic force as the external perturbation to generate twodimensional motion of the tracers (see Supplementary Information, Appendix A) on a microscope stage following a simplified design of ref. 31. Video microscopy and computerized image analysis are used to locate the tracers in each image. We calculate the response and correlation functions in the x—y plane.
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Acknowledgements
We wish to thank M. Shattuck for help in the design of the experiments and J. Brujić and S. Mistry for providing the colloidal particles and illuminating discussions. We acknowledge the financial support from DOE Division of Materials Sciences and Engineering and NSFCMMT.
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Wang, P., Song, C. & Makse, H. Dynamic particle tracking reveals the ageing temperature of a colloidal glass. Nature Phys 2, 526–531 (2006). https://doi.org/10.1038/nphys366
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