Abstract
The chiral magnetic effect is the generation of an electric current induced by chirality imbalance in the presence of a magnetic field. It is a macroscopic manifestation of the quantum anomaly^{1,2} in relativistic field theory of chiral fermions (massless spin 1/2 particles with a definite projection of spin on momentum)—a remarkable phenomenon arising from a collective motion of particles and antiparticles in the Dirac sea. The recent discovery^{3,4,5,6} of Dirac semimetals with chiral quasiparticles opens a fascinating possibility to study this phenomenon in condensed matter experiments. Here we report on the measurement of magnetotransport in zirconium pentatelluride, ZrTe_{5}, that provides strong evidence for the chiral magnetic effect. Our angleresolved photoemission spectroscopy experiments show that this material’s electronic structure is consistent with a threedimensional Dirac semimetal. We observe a large negative magnetoresistance when the magnetic field is parallel with the current. The measured quadratic field dependence of the magnetoconductance is a clear indication of the chiral magnetic effect. The observed phenomenon stems from the effective transmutation of a Dirac semimetal into a Weyl semimetal induced by parallel electric and magnetic fields that represent a topologically nontrivial gauge field background. We expect that the chiral magnetic effect may emerge in a wide class of materials that are near the transition between the trivial and topological insulators.
Main
The recent discovery of the threedimensional (3D) Dirac semimetals Cd_{3}As_{2} and Na_{3}Bi (refs 3,4,5,6) has enabled experimental studies of the quantum dynamics of relativistic field theory in condensed matter systems. The relativistic theory of charged chiral fermions in three spatial dimensions possesses the socalled chiral anomaly^{1,2}—nonconservation of chiral charge induced by external gauge fields with nontrivial topology, for example, by parallel electric and magnetic fields. The existence of chiral quasiparticles in Dirac and Weyl semimetals opens the possibility to observe the effects of the chiral anomaly^{7}. Of particular interest is the chiral magnetic effect (CME; ref. 8)—the generation of electric current in an external magnetic field induced by the chirality imbalance^{9}.
This phenomenon is at present under intense study in relativistic heavy ion collisions at the Relativistic Heavy Ion Collider (RHIC) at BNL and at the Large Hadron Collider (LHC) at CERN, where it was predicted^{10} to induce fluctuations in hadron charge asymmetry with respect to the reaction plane. The experimental data from the STAR (ref. 11) Collaboration at RHIC and the ALICE (ref. 12) Collaboration at LHC indicate the fluctuations are consistent with the theoretical expectations. Closely related phenomena are expected to play an important role in the Early Universe, possibly causing the generation of primordial magnetic fields^{13,14,15,16,17}. However, the interpretation in all these cases is under debate owing to lack of control over the chirality imbalance produced.
The most prominent signature of the CME in Dirac systems in parallel electric and magnetic fields is a positive contribution to the conductivity that has a quadratic dependence on magnetic field^{8,18,19}. This is because the CME current is proportional to the product of the chirality imbalance and the magnetic field, and the chirality imbalance in Dirac systems is generated dynamically through the anomaly with a rate that is proportional to the product of electric and magnetic fields. As a result, the longitudinal magnetoresistance becomes negative^{18,19}.
Let us explain how this mechanism works in Dirac semimetals in more detail. In the absence of external fields, each Dirac point initially contains left and righthanded fermions with equal chemical potentials, μ_{L} = μ_{R} = 0. If the energy degeneracy between the left and righthanded fermions gets broken, we can parameterize it by introducing the chiral chemical potential μ_{5} ≡ (μ_{R} − μ_{L})/2. The corresponding density of chiral charge is then given by^{8}
where μ = (μ_{R} + μ_{L})/2 and T are the chemical potential and the temperature, and v is the Fermi velocity.
The chiral anomaly of quantum electrodynamics dictates that the parallel external electric and magnetic fields generate the chiral charge with a rate given by
However, the left and righthanded fermions in Dirac semimetals can mix through chiralitychanging scattering, and this process will deplete the amount of chiral charge that can be produced. Denoting the chiralitychanging scattering time by τ_{V}, we thus get the equation
The solution of equation (3) at t ≫ τ_{V} is
According to equation (1), this leads to a nonzero chiral chemical potential μ_{5} (we assume that μ_{5} ≪ μ, T):
On the lowest Landau level, the spins of positive (negative) chiral fermions are parallel (antiparallel) to the external magnetic field. Therefore, for a positive fermion to be righthanded (that is, have a positive projection of spin on momentum) it means moving along the magnetic field, whereas for a negative fermion it means moving against the magnetic field. The lefthanded fermions will move in the opposite directions, so there will normally be no charge separation. However, if the densities of the right and lefthanded fermions are different, the currents of positive and negative charges do not compensate each other, and the system develops a net electric current—this is the CME. The corresponding current can be computed^{8} by fieldtheoretical methods and is given by
The formulae (6) and (5) yield the final expression for the CME current:
We see that the CME is described by the conductivity tensor σ_{CME}^{ik} ∼ B^{i}B^{k}. When the electric and magnetic fields are parallel, the CME conductivity is
Because the CME current is directed along the electric field, it will affect the measured conductivity, as the total current will be the sum of the Ohmic and CME currents:
where σ_{CME} ≡ σ_{CME}^{zz}. If the electric and magnetic fields are parallel (θ = 0), there is no conventional contribution to magnetoresistance induced by the Lorentz force. The magnetoconductance (8) has a characteristic quadratic dependence on magnetic field. It is precisely this contribution to magnetoconductance with a quadratic dependence on magnetic field that we have unambiguously observed in ZrTe_{5}.
ZrTe_{5} is a material that crystallizes in the layered orthorhombic crystal structure, with prismatic ZrTe_{6} chains running along the crystallographic aaxis and linked along the caxis by zigzag chains of Te atoms to form twodimensional (2D) layers, stacked along the baxis into a crystal. This material is known for its large thermoelectric power, resistivity anomaly^{20} and large positive magnetoresistance^{21}. It shows a semimetallic electronic structure with extremely small and light ellipsoidal Fermi surface(s), centred at the centre (Γ point) of the bulk Brillouin zone (BZ). The calculations predict a small direct gap at Γ(≅50 meV), but previous transport studies show semimetallic behaviour, with quantum oscillations indicating a tiny but finite Fermi surface^{22,23,24,25}. Quantum oscillations show that the effective mass in the chain direction (m_{a}^{∗}/m_{e}≅0.03) is comparable to that in a prototypical 3D Dirac semimetal, Cd_{3}As_{2} (refs 24,26).
Figure 1a shows the temperature dependence of resistivity along the chain direction (a) in a magnetic field perpendicular to the a–c plane. The zerofield transport shows a characteristic peak in resistivity at T ≅ 60 K, significantly lower than in earlier studies, probably due to a much lower impurity concentration in our samples^{20}. In B  b, the peak shifts to higher temperatures and we observe a very large positive magnetoresistance in the whole temperature range, consistent with previous studies^{21}. The inset shows the resistivity with the magnetic field applied along the three major crystal axes.
Figure 1c, d shows the magnetoresistance measured at 20 K for several angles of the applied magnetic field with respect to the current along the chain direction. The angle rotates from the baxis to the aaxis, so that at ϕ = 90° the field is parallel to the current (B  a)—the socalled Lorentzforcefree configuration. When the magnetic field is aligned along the baxis (ϕ = 0°), the magnetoresistance is positive and quadratic in low fields, and tends to saturate in high fields. The similar angular dependence is also observed for the field in the c–a plane. When the magnetic field is rotated away from the b or caxis, the positive magnetoresistance drops with cosφ, as expected for the Lorentz force component. However, in the Lorentzforcefree configuration (B  a), we see a large negative magnetoresistance, a clear indication of CME in this material.
Figure 2 shows the magnetoresistance at various temperatures in a magnetic field parallel to the current. At elevated temperatures, T ≥ 110 K, the ρ versus B curves show a small upward curvature, a contribution from an inevitable perpendicular field component due to imperfect alignment between the current and the magnetic field. In fact, the small perpendicular field contribution to the observed resistivity can be fitted with a simple quadratic term (Supplementary Information and Supplementary Fig. 1). This term is treated as a background and subtracted from the parallel field component for all magnetoresistance curves recorded at T ≤ 100 K.
A negative magnetoresistance is observed for T ≤ 100 K, increasing in magnitude as temperature decreases. We found that the magnetic field dependence of the negative magnetoresistance can be nicely fitted with the CME contribution to the electrical conductivity, given by σ_{CME} = σ_{0} + a(T)B^{2}, where σ_{0} represents the zerofield conductivity. The fitting is illustrated in Fig. 2b for T = 20 K, with an excellent agreement between the data and the CME fitting curve. At 4 T, the CME conductivity is about the same as the zerofield conductivity. At 9 T, the total magnetoconductivity increases by ∼400% over the zerofield value as a result of the CME contribution. This results in a negative magnetoresistance that is much stronger than any conventional magnetoresistance reported at an equivalent magnetic field in a nonmagnetic material. To demonstrate that the effect is not limited to any specific crystal direction, but locked only to the current direction, we have also performed magnetoresistance measurements with the current still in the a–c plane, but 18° off the chain direction (aaxis). In this direction, we observe the same ∝B^{2} dependence of CME when the magnetic field is parallel to the current.
To obtain a numerical theoretical estimate for CME, we take T = 20 K, ρ_{Ohm} ≅ 1.2 mΩ cm indicated by our measurements at B = 0, and assume that the rate of chiralitychanging transitions τ_{V}^{−1} = Δ/ℏ. Δ ≅ 50 meV and μ ≅ 9 meV is determined from the fit to the data. The ARPES data indicate that v ≅ 1/300 c. Evaluating equation (8), we reproduce the correct order of magnitude of the coefficient a(T) that we used to fit the quadratic dependence of magnetoresistance on magnetic field. The inset in Fig. 2b shows the temperature dependence of parameter a(T) for B and E along the aaxis (red solid symbols) and 18° off the aaxis, in the a–c plane (open circles), together with the dependence (line) predicted by equation (8) in which the effective value of μ is found to be μ ∼ 9 meV.
At very low field, the data show a small cusplike feature. The origin of this feature is not completely understood, but it probably indicates some form of weak antilocalization (WAL). This, and the large positive magnetoresistance for magnetic field perpendicular to current, seem to be common features in all the materials that were subsequently found to exhibit the CME in parallel fields^{27,28,29,30,31,32}. Although the reason for a simultaneous observation of CME in parallel fields and large magnetoresistance in perpendicular fields is not fully understood yet, we note that the general requirements for the observation of CME—that is, the low carrier concentration and nearly linear bands—seem to be also favourable for the observation of large positive magnetoresistance in perpendicular fields. In these situations, the system is either very close to the quantum limit^{33} or, if it contains two types of carriers, the charge compensation may lead to a large response in the way that was recently observed in WTe_{2} (refs 34,35,36).
A necessary requirement for observation of the CME is that a material has a 3D Dirac semimetallike (zero gap), or semiconductorlike (nonzero gap) electronic structure. Figure 3 shows angleresolved photoemission spectroscopy (ARPES) data from a freshly cleaved (a–c plane) ZrTe_{5} sample. The states forming the small, holelike Fermi surface (FS) disperse linearly over a large energy range, both along the chain direction (Fig. 3c) and perpendicular to it (Fig. 3a), indicating a Diraclike dynamics of carriers for the inplane propagation. The velocity, or the slope of dispersion, is very large in both the chain direction, v_{a} ≅ 6.4 eV Å (≅c/300), and perpendicular to it, v_{c} ≅ 4.5 eV Å. If extrapolated to the unoccupied part, the linear approximation for this band would place the Dirac point at ∼0.2 eV above the E_{F}.
In Fig. 3c, it also seems that the bottom of a tiny electron pocket is enclosed by the dominant holecone. However, owing to a sizable quasiparticle scattering, Γ_{Q} = ℏ/τ_{Q} ≅ 100 meV, the states are apparently too broad to completely resolve possible fine features in the lowenergy electronic structure, such as the existence of small gaps or changes in the velocity at low energies (E < 50 meV). Nevertheless, the magnitude of CME in ZrTe_{5} is not particularly sensitive to the fine details in the electronic structure on an energy scale smaller than Γ_{Q}. On the other hand, for the existence of CME, it is crucial that the electronic structure of a material is 3D Diraclike. Although recent magnetooptical studies have shown that ZrTe_{5} is indeed a 3D Dirac semimetal^{37}, it has been also suggested that this material might be either a weak or strong topological insulator^{25}. It is therefore important to verify that the states seen in ARPES are bulk states and not topological surface states.
This is done in Fig. 3e–h, which shows the dependence of the states forming the FS on the momentum k_{b} perpendicular to the a–c plane. Figure 3e, f shows a clear warping of the Fermi surface and a significant dispersion with k_{b}, indicating the bulk character of the measured states. Unfortunately, because the Dirac point is unoccupied, the ARPES studies cannot provide a complete picture of the electronic structure in its vicinity, and the existence of a small mass gap cannot be excluded. The occupied part of the cone (Fig. 3f–h) indicates that the outofplane velocity is an order of magnitude smaller than the inplane velocity, consistent with ZrTe_{5} being a highly anisotropic 3D Dirac semimetal.
We note that the possible coexistence of both the hole and electron pockets might be responsible for the large positive magnetoresistance seen in the perpendicular field, as the fine balance between them could lead to a perfect compensation at some temperature^{34,35,36}. We also note that the tiny volume of the FS indicates a very low carrier concentration, 10^{17}–10^{18} cm^{−3}, consistent with the absence of quantum oscillations in transport measurements in the probed field range.
As noted, the ARPES measurements cannot exclude a possible gap in the otherwise Diraclike spectrum. The gap Δ will in general induce chiralitychanging transitions with a rate Δ/ℏ—this is because the corresponding term in the effective Hamiltonian, namely , mixes the left and right components of the spinors—but it does not prevent the CME. The ARPES data also indicate that the quantum scattering rate determined from the broadening of quasiparticles is Γ_{Q} = ℏ/τ_{Q} ≅ 100 meV. Chirality conservation in the quasiparticle scattering processes implies that the chiralitychanging rate should be only a small fraction of the quantum scattering rate, Γ_{V} = ℏ/τ_{V} ≪ Γ_{Q}. It is therefore reasonable to assume that the measured Γ_{Q} represents the absolute upper limit to the chiralitychanging transition rate. The existence of intravalley transitions does not destroy the CME, although the chiralityflipping transitions do reduce the magnitude of the CME current, as can be seen in our equation (8) for the CME conductivity, which is inversely proportional to the chiralityflipping rate.
We note that equation (9) shows that, in the regime where ρ_{Ohm} ≫ ρ_{CME}, the measured magnetoresistivity ρ directly provides the CME resistivity, ρ ≅ ρ_{CME}. Therefore it is much easier to observe the CME in materials that have a relatively large zerofield resistivity. The zerofield resistivity in ZrTe_{5} is ρ_{Ohm} ≅ 1.2 mΩ cm at T = 20 K, and according to our theoretical estimates the CME and Ohmic resistivities become equal, ρ_{Ohm} ≅ ρ_{CME}, at B ≅ 3 T. On the other hand, if a material had a much smaller resistivity, the CME observation would have been more difficult.
The present study can be extended to a broad range of materials as 3D Dirac semimetals often emerge at quantum transitions between conventional (‘trivial’) and topological insulators, and between conventional and topological crystalline insulators. Indications that the CME occurs at the former type of transitions have already been observed in Bi_{1−x}Sb_{x} at x ≍ 0.03 (ref. 33). In addition, our experimental observation has important implications extending well beyond condensed matter physics.
Note added in proof:
After submission of our manuscript, we noticed a surging interest in the study of magnetotransport in Diraclike semimetals, with several recent preprints reporting a negative magnetoresistance as a consequence of the CME. The effect is observed in two types of 3D chiral materials. The first type consists of Dirac semimetals, where the Dirac points for left and righthanded fermions are not separated in momentum space. These materials are effectively transformed into Weyl semimetals by parallel electric and magnetic fields, with an imbalance between the densities of left and righthanded fermions induced by the chiral anomaly. Members of that class are ZrTe_{5}, Na_{3}Bi (ref. 27), Cd_{3}As_{2} (ref. 32) and Bi_{1−x}Sb_{x} (x ≍ 0.03; ref. 33). In particular, a very detailed transport measurement was performed recently with the Dirac semimetal Na_{3}Bi (ref. 27), with results similar to ours. They observed both a cusp of longitudinal magnetoresistance near zero magnetic field and a negative longitudinal magnetoresistance in stronger fields due to the CME, with a steep dependence on the angle between electric and magnetic fields^{27}. The second type of 3D chiral materials consists of inversion asymmetric Weyl semimetals, such as TaAs (ref. 28), NbAs (ref. 29), NbP (ref. 30) and TaP (ref. 31). In both types of materials, parallel electric and magnetic fields are required to observe the CME.
Methods
Crystal growth.
Crystals of ZrTe_{5} were grown by the flux growth method using Te as flux. Highpurity elements (99.99999% Te and 99.9999% Zr) were loaded into a doublewalled quartz ampoule and sealed under vacuum. The composition of the Zr–Te melt used for the ZrTe_{5} growth was Zr_{0.0025}Te_{0.9975}. The materials were first melted at 900 °C in a box furnace and fully rocked for 72 h to achieve a homogeneous mixture. The melt was then slowly cooled and rapidly heated (for remelting of small size crystals) between 445 and 505 °C for 21 days. The largest single crystals were ∼0.1 × 0.3 × 20 mm^{3}. Crystals were chemically and structurally characterized by powder Xray diffraction, scanning electron microscopy with energy dispersive Xray analysis, and transmission electron microscopy with electron diffraction.
Transport measurements.
The magnetoresistance of ZrTe_{5} samples was measured using the fourpoint probe inline method in a Quantum Design Physical Property Measurement System (PPMS) equipped with 9 T superconducting magnet. Measurements have been performed with the current along the chain direction (a) and 18° off the chain direction, but still in the a–c plane. The off aaxis measurements were extremely difficult, owing to the needlelike aspect of our single crystals and their small size along the c and baxes. For crystal alignment with the magnetic field, horizontal and vertical sample rotators were used with an angular resolution of ∼0.1°. Temperaturedependent data were taken from 1.8 to 400 K, at various fields up to 9 T.
ARPES experiments.
The ARPES measurements were conducted using a Scienta SES2002 analyser at the U13 beam line of the National Synchrotron Light Source at Brookhaven National Laboratory (hv = 21 eV), and at the 12.0.1 beam line of the Advanced Light Source at Lawrence Berkeley National Laboratory (35–80 eV) using a Scienta R 3000 analyzer. The total experimental resolution was ≅15 meV in energy and ≤0.2° in angle, in both experimental setups. The twodimensional Brillouin zone mapping was accomplished by rotating the sample perpendicularly to the analyser slit, in steps of 1° at hv = 21 eV and 0.5° at higher photon energies. The samples were glued to the holder using a conductive epoxy resin and cleaved at the a–c plane in an ultrahigh vacuum (p < 10^{−8} Pa) just before the measurements. Sample cooling was provided through contact with cryostats filled with liquid helium or liquid nitrogen.
The evolution of electronic structure with photon energy reflects the dispersion along k_{z} (k_{b} in our notation). Even though k_{z} is not conserved in a photoemission process, it can be approximated by , where E_{k} is the kinetic energy of a photoelectron and V is the inner potential. A set of ARPES spectra taken along k_{a} = 0 in the surface BZ at different photon energies (39 ≤ hv ≤ 79 eV, in 2 eV steps) is converted into a (k_{c}, k_{b}, E) data set by using the inner potential V = 13 eV. The E = 0 slice, representing the FS, is shown in Fig. 3e, and the dispersion of the states at k_{a} = 0, k_{c} = −0.055 Å^{−1} is shown in Fig. 3f. We note that in this photon energy range, the 9th to the 11th BZs are probed. States localized to the surface (surface states) do not disperse with k_{z} and would form straight vertical streaks in Fig. 3e, if they existed.
By evaluating the volume of the FS from our ARPES measurements, V_{FS}, we can estimate the carrier concentration in our samples, n = 2 ⋅ V_{FS}/(2π)^{3}, in the low 10^{18} cm^{−3} range. Here, we have taken into account the spin degeneracy.
References
 1
Adler, S. L. Axialvector vertex in spinor electrodynamics. Phys. Rev. 177, 2426–2438 (1969).
 2
Bell, J. S. & Jackiw, R. A PCAC puzzle: π^{0} → γγ in the σmodel. Il Nuovo Cimento A 60, 47–61 (1969).
 3
Wang, Z. et al. Dirac semimetal and topological phase transitions in A3Bi(A = Na, K, Rb). Phys. Rev. B 85, 195320 (2012).
 4
Wang, Z., Weng, H., Wu, Q., Dai, X. & Fang, Z. Threedimensional Dirac semimetal and quantum transport in Cd3As2 . Phys. Rev. B 88, 125427 (2013).
 5
Borisenko, S. et al. Experimental realization of a threedimensional Dirac semimetal. Phys. Rev. Lett. 113, 027603 (2014).
 6
Liu, Z. K. et al. Discovery of a threedimensional topological Dirac semimetal, Na3Bi. Science 343, 864–867 (2014).
 7
Nielsen, H. B. & Ninomiya, M. The Adler–Bell–Jackiw anomaly and Weyl fermions in a crystal. Phys. Lett. B 130, 389–396 (1983).
 8
Fukushima, K., Kharzeev, D. & Warringa, H. Chiral magnetic effect. Phys. Rev. D 78, 074033 (2008).
 9
Kharzeev, D. E. The chiral magnetic effect and anomalyinduced transport. Prog. Part. Nucl. Phys. 75, 133–151 (2014).
 10
Kharzeev, D. Parity violation in hot QCD: Why it can happen, and how to look for it. Phys. Lett. B 633, 260–264 (2006).
 11
Abelev, B. et al. Azimuthal chargedparticle correlations and possible local strong parity violation. Phys. Rev. Lett. 103, 251601 (2009).
 12
Abelev, B. et al. Charge separation relative to the reaction plane in Pb–Pb collisions at sNN = 2.76 TeV. Phys. Rev. Lett. 110, 012301 (2013).
 13
Vilenkin, A. & Leahy, D. Parity nonconservation and the origin of cosmic magnetic fields. Astrophys. J. 254, 77–81 (1982).
 14
Fröhlich, J. & Pedrini, B. New applications of the chiral anomaly. Preprint at http://arxiv.org/abs/hepth/0002195 (2000).
 15
Joyce, M. & Shaposhnikov, M. Primordial magnetic fields, right electrons, and the Abelian anomaly. Phys. Rev. Lett. 79, 1193–1196 (1997).
 16
Giovannini, M. & Shaposhnikov, M. E. Primordial hypermagnetic fields and the triangle anomaly. Phys. Rev. D 57, 2186–2206 (1998).
 17
Vachaspati, T. Estimate of the primordial magnetic field helicity. Phys. Rev. Lett. 87, 251302 (2001).
 18
Son, D. T. & Spivak, B. Z. Chiral anomaly and classical negative magnetoresistance of Weyl metals. Phys. Rev. B 88, 104412 (2013).
 19
Burkov, A. A. Chiral anomaly and diffusive magnetotransport in Weyl metals. Phys. Rev. Lett. 113, 247203 (2014).
 20
Okada, S., Sambongi, T. & Ido, M. Giant resistivity anomaly in ZrTe5 . J. Phys. Soc. Jpn 49, 839–840 (1980).
 21
Tritt, T. et al. Large enhancement of the resistive anomaly in the pentatelluride materials HfTe5 and ZrTe5 with applied magnetic field. Phys. Rev. B 60, 7816–7819 (1999).
 22
Whangbo, M., DiSalvo, F. & Fleming, R. Electronic structure of ZrTe5 . Phys. Rev. B 26, 687–689 (1982).
 23
McIlroy, D. N. et al. Observation of a semimetalsemiconductor phase transition in the intermetallic ZrTe5 . J. Phys. Condens. Matter 16, L359–L365 (2004).
 24
Kamm, G., Gillespie, D., Ehrlich, A., Wieting, T. & Levy, F. Fermi surface, effective masses, and Dingle temperatures of ZrTe5 as derived from the Shubnikovde Haas effect. Phys. Rev. B 31, 7617–7623 (1985).
 25
Weng, H., Dai, X. & Fang, Z. Transitionmetal pentatelluride ZrTe5 and HfTe5 . Phys. Rev. X 4, 011002 (2014).
 26
He, L. P. et al. Quantum transport evidence for the threedimensional Dirac semimetal phase in Cd3As2 . Phys. Rev. Lett. 113, 246402 (2014).
 27
Xiong, J. et al. Evidence for the chiral anomaly in the Dirac semimetal Na3Bi. Science 350, 413–416 (2015).
 28
Huang, X. et al. Observation of the chiralanomalyinduced negative magnetoresistance in 3d Weyl semimetal TaAs. Phys. Rev. X 5, 031023 (2015).
 29
Yang, X., Li, Y., Wang, Z., Zhen, Y. & Xu, Z.A. Observation of negative magnetoresistance and nontrivial π Berrys phase in 3D Weyl semimetal NbAs. Preprint at http://arxiv.org/abs/1506.02283 (2015).
 30
Wang, Z. et al. Helicity protected ultrahigh mobility Weyl fermions in NbP. Preprint at http://arxiv.org/abs/1506.00924 (2015).
 31
Shekhar, C. et al. Large and unsaturated negative magnetoresistance induced by the chiral anomaly in the Weyl semimetal TaP. Preprint at http://arxiv.org/abs/1506.06577 (2015).
 32
Li, C.Z. et al. Giant negative magnetoresistance induced by the chiral anomaly in individual Cd3As2 nanowires. Nature Commun. 6, 10137 (2015).
 33
Kim, H.J. et al. Dirac versus Weyl fermions in topological insulators: Adler–Bell–Jackiw anomaly in transport phenomena. Phys. Rev. Lett. 111, 246603 (2013).
 34
Pippard, A. Magnetoresistance in Metals. Cambridge Studies in Low Temperature Physics (Cambridge Univ. Press, 1989).
 35
Ali, M. N. et al. Large, nonsaturating magnetoresistance in WTe2 . Nature 514, 205–208 (2014).
 36
Pletikosić, I., Ali, M. N., Fedorov, A. V., Cava, R. J. & Valla, T. Electronic structure basis for the extraordinary magnetoresistance in WTe2 . Phys. Rev. Lett. 113, 216601 (2014).
 37
Chen, R. Y. et al. Magnetoinfrared spectroscopy of Landau levels and Zeeman splitting of threedimensional massless Dirac fermions in ZrTe5 . Phys. Rev. Lett. 115, 176404 (2015).
Acknowledgements
We thank J. Misewich, P. Johnson, A. Abanov and G. Monteiro for discussions. This work was supported by the US Department of Energy, Office of Basic Energy Sciences, contracts No. DEAC0298CH10886, No. DEFG88ER40388, Office of Nuclear Physics, contract No. DEFG88ER41723 and ARO MURI Program, grant W911NF1210461. ALS is operated by the US DOE under Contract No. DEAC0205CH11231.
Author information
Affiliations
Contributions
D.E.K. designed and, with Q.L. and T.V., directed the study, analysed results, and wrote the manuscript. Q.L. and C.Z. performed the transport measurements and analysed results. R.D.Z., J.A.S. and G.D.G. grew the crystals and performed Xray diffraction experiments, Y.H. performed the SEM/TEM measurements and provided analysis. I.P., A.V.F. and T.V. performed the ARPES measurements and analysed results. All authors made contributions to writing the manuscript.
Corresponding authors
Ethics declarations
Competing interests
The authors declare no competing financial interests.
Supplementary information
Supplementary information
Supplementary information (PDF 396 kb)
Rights and permissions
About this article
Cite this article
Li, Q., Kharzeev, D., Zhang, C. et al. Chiral magnetic effect in ZrTe_{5}. Nature Phys 12, 550–554 (2016). https://doi.org/10.1038/nphys3648
Received:
Accepted:
Published:
Issue Date:
Further reading

Lowenergy electrodynamics of Dirac semimetal phases in the doped Mott insulator Sr2IrO4
Physical Review B (2021)

Temperature Dependent InPlane Anisotropic Magnetoresistance in HfTe5 Thin Layers
Chinese Physics Letters (2021)

Anomalous planar Hall effect in twodimensional trigonal crystals
Physical Review Research (2021)

A lightinduced phononic symmetry switch and giant dissipationless topological photocurrent in ZrTe5
Nature Materials (2021)

Thicknessdependent quantum transport of Weyl fermions in ultrahighquality SrRuO3 films
Applied Physics Letters (2021)