Abstract
To fulfil the promise that complete-photonic-bandgap materials hold for optoelectronics applications, the incorporation of three-dimensionally engineered defects must be realized. Previous attempts to create and characterize such defects were limited because of fabrication challenges. Here we report the optical and structural characterization of complex submicrometre features of unprecedented quality within silicon inverse opals. High-resolution three-dimensional features are first formed within a silica colloidal crystal by means of two-photon polymerization, followed by a high-index replication step and removal of the opal template to yield embedded defects in three-dimensional silicon photonic crystals. We demonstrate the coupling of bandgap frequencies to resonant modes in planar optical cavities and the first waveguiding of near-infrared light around sharp bends in a complete-photonic-bandgap material.
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References
Bykov, V. P. Spontaneous emission from a medium with a band spectrum. Sov. J. Quant. Electron. 4, 861–871 (1974).
John, S. Strong localization of photons in certain disordered dielectric superlattices. Phys. Rev. Lett. 58, 2486–2489 (1987).
Yablonovitch, E. Inhibited spontaneous emission in solid-state physics and electronics. Phys. Rev. Lett. 58, 2059–2062 (1987).
Meade, R. D. et al. Novel applications of photonic band-gap materials — low-loss bends and high Q-cavities. J. Appl. Phys. 75, 4753–4755 (1994).
Fan, S. H. et al. Guided and defect modes in periodic dielectric wave-guides. J. Opt. Soc. Am. B 12, 1267–1272 (1995).
Mekis, A. et al. High transmission through sharp bends in photonic crystal waveguides. Phys. Rev. Lett. 77, 3787–3790 (1996).
Joannopoulos, J. D., Villeneuve, P. R. & Fan, S. Photonic crystals: Putting a new twist on light. Nature 386, 143–149 (1997).
Fink, Y. et al. A dielectric omnidirectional reflector. Science 282, 1679–1682 (1998).
Russell, P. Photonic crystal fibers. Science 299, 358–362 (2003).
Noda, S., Tomoda, K., Yamamoto, N. & Chutinan, A. Full three-dimensional photonic bandgap crystals at near-infrared wavelengths. Science 289, 604–606 (2000).
Sozuer, H. S., Haus, J. W. & Inguva, R. Photonic bands—convergence problems with the plane-wave method. Phys. Rev. B 45, 13962–13972 (1992).
Braun, P. V., Rinne, S. A. & García-Santamaría, F. Introducing defects in 3D photonic crystals: State of the art. Adv. Mater. 18, 2665–2678 (2006).
Jun, Y. H., Leatherdale, C. A. & Norris, D. J. Tailoring air defects in self-assembled photonic bandgap crystals. Adv. Mater. 17, 1908–1911 (2005).
Lee, W. M., Pruzinsky, S. A. & Braun, P. V. Multi-photon polymerization of waveguide structures within three-dimensional photonic crystals. Adv. Mater. 14, 271–274 (2002).
Pruzinsky, S. A. & Braun, P. V. Fabrication and characterization of two-photon polymerized features in colloidal crystals. Adv. Funct. Mater. 15, 1995–2004 (2005).
Blanco, A. et al. Large-scale synthesis of a silicon photonic crystal with a complete three-dimensional bandgap near 1.5 micrometres. Nature 405, 437–440 (2000).
Vlasov, Y. A., Bo, X.-Z., Sturm, J. C. & Norris, D. J. On-chip natural assembly of silicon photonic bandgap crystals. Nature 414, 289–293 (2001).
Song, B. S., Noda, S., Asano, T. & Akahane, Y. Ultra-high-Q photonic double-heterostructure nanocavity. Nature Mater. 4, 207–210 (2005).
Nelson E. C. & Braun, P. V. Registration and optical properties of embedded two-photon polymerized features within self-organized photonic crystals. arXiv:0710.0851v1 <http://arxiv.org/abs/0710.0851v1> (2007).
Jiang, P., Bertone, J. F., Hwang, K. S. & Colvin, V. L. Single-crystal colloidal multilayers of controlled thickness. Chem. Mater. 11, 2132–2140 (1999).
Chabanov, A. A., Jun, Y. & Norris, D. J. Avoiding cracks in self-assembled photonic band-gap crystals. Appl. Phys. Lett. 84, 3573–3575 (2004).
García-Santamaría, F. et al. Refractive index properties of calcined silica submicrometer spheres. Langmuir 18, 1942–1944 (2002).
Groner, M. D., Elam, J. W., Fabreguette, F. H. & George, S. M. Electrical characterization of thin Al2O3 films grown by atomic layer deposition on silicon and various metal substrates. Thin Solid Films 413, 186–197 (2002).
Busch, K. & John, S. Photonic band gap formation in certain self-organizing systems. Phys. Rev. E 58, 3896–3908 (1998).
Scrimgeour, J. et al. Three-dimensional optical lithography for photonic microstructures. Adv. Mater. 18, 1557–1560 (2006).
Takada, K., Sun, H. B. & Kawata, S. Improved spatial resolution and surface roughness in photopolymerization-based laser nanowriting. Appl. Phys. Lett. 86, 071122 (2005).
García-Santamaría, F., Nelson E. C. & Braun, P. V. An optical surface resonance may render photonic crystals ineffective. Phys. Rev. B 76, 075132 (2007).
García-Santamaría, F. et al. Nanorobotic manipulation of microspheres for on-chip diamond architectures. Adv. Mater. 14, 1144–1147 (2002).
Palacios-Lidón, E., Galisteo-López, J. F., Juárez, B. H. & López, C. Engineered planar defects embedded in opals. Adv. Mater. 16, 341–345 (2004).
Tetreault, N. et al. Dielectric planar defects in colloidal photonic crystal films. Adv. Mater. 16, 346–349 (2004).
Kramper, P. et al. Highly directional emission from photonic crystal waveguides of subwavelength width. Phys. Rev. Lett. 92, 113901 (2004).
Frei, W. R., Tortorelli, D. A. & Johnson, H. T. Topology optimization of a photonic crystal waveguide termination to maximize directional emission. Appl. Phys. Lett. 86, 111114 (2005).
Lousse, V. & Fan, S. H. Waveguides in inverted opal photonic crystals. Opt. Express 14, 866–878 (2006).
Cumpston, B. H. et al. Two-photon polymerization initiators for three-dimensional optical data storage and microfabrication. Nature 398, 51–54 (1999).
Deubel, M. et al. Direct laser writing of three-dimensional photonic-crystal templates for telecommunications. Nature Mater. 3, 444–447 (2004).
Pruzinsky, S. A. Two-Photon Polymerization of Defects in Photonic Crystals. Thesis, Univ. Illinois at Urbana-Champaign (2006).
Sechrist, Z. A. et al. Modification of opal photonic crystals using Al2O3 atomic layer deposition. Chem. Mat. 18, 3562–3570 (2006).
Vlasov, Y. A., Deutsch, M. & Norris, D. J. Single-domain spectroscopy of self-assembled photonic crystals. Appl. Phys. Lett. 76, 1627–1629 (2000).
Acknowledgements
This material was based on work supported by US Army Research Office grant DAAD19-03-1-0227, National Science Foundation grant DMR 00-71645 and US Department of Energy, Division of Materials Sciences grant DE-FG02-07ER46471, through the Frederick Seitz Materials Research Laboratory at the University of Illinois at Urbana-Champaign (UIUC). This work was carried out in part in the Beckman Institute Microscopy Suite, UIUC, and the Center for Microanalysis of Materials, UIUC, which is partially supported by the US Department of Energy under grants DE-FG02-07ER46453 and DE-FG02-07ER46471. We gratefully thank L.-S. Tan (US Air Force Research Laboratory) for providing the two-photon sensitive dye, and E.C. Nelson, A.D. Stewart and E. Zettergren of our laboratory for providing some of the colloids and colloidal crystals used in this work.
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S.A.R. carried out the TPP, FIB, SEM, confocal and IR microscopy. F.G.S. carried out the ALD, CVD and bandgap calculations. S.A.R. and F.G.S. both performed HF etching, spectroscopy, RIE, and grew colloidal crystals. All authors conceived and designed the project, participated in discussions about the research and wrote the manuscript.
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Supplementary information: figures S1-S9 and supplementary references (PDF 1118 kb)
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Rinne, S., García-Santamaría, F. & Braun, P. Embedded cavities and waveguides in three-dimensional silicon photonic crystals. Nature Photon 2, 52–56 (2008). https://doi.org/10.1038/nphoton.2007.252
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DOI: https://doi.org/10.1038/nphoton.2007.252
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