Single-molecule junctions with high rectification ratios can be realized by exposing different electrode surface areas to an ionic liquid.
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Cuevas, J. The environment does the trick. Nature Nanotech 10, 486–487 (2015). https://doi.org/10.1038/nnano.2015.98
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DOI: https://doi.org/10.1038/nnano.2015.98