Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

Material witness

Who made the first glass?

Subjects

No other material continually exceeds itself as silica glass does. Whether it is in the stained glass of Gothic churches, the airy Crystal Palace of the Victorians or the modern skyscrapers that mirror the sky they reach towards, glass has been constantly refined to redefine its architectural possibilities. Meanwhile, in fibre composites and optical cables it challenges preconceptions about its properties and limits.

Philip Ball

So who could not wonder when this substance first entered the palette of human-made materials? It starts to appear in archaeological remains in significant quantities in the Late Bronze Age, around 1500 BC, and consensus has long located the geographical origins in the Middle East. But that still leaves options open. Ancient Egypt used to be the obvious and default assumption, but Mesopotamia — the region mostly overlapping with present-day Iraq, with a distinct culture — has been a contender too for at least a century.

Opinion in recent decades has shifted in that direction, thanks especially to the finding of extensive glass remains in the city of Nuzi, near Kirkuk in northern Iraq, which was excavated in the 1920s and 1930s. The material culture of Nuzi is currently being re-examined in an international project1. A new study of the Nuzi glass artefacts housed at the Harvard Semitic Museum now argues for another reconsideration of the origins of glassmaking, indicating that there is after all no compelling reason to prefer this region over Egypt2.

Shortland et al. have conducted scanning electron microscope-wavelength dispersive spectroscopy (SEM-WDS) analysis to deduce the elemental compositions of the samples (which include raw glass ingots, beads and fragments of worked objects), along with measurements of strontium and neodymium isotope ratios that help to distinguish different sources of the parent silica. The results reveal that some of the artefacts are modern: introduced, presumably, by local workers during the excavation because they were paid to hand over their finds. Most of the genuine Nuzi glass is tinted blue by traces of copper; in contrast, Egyptian glass from this period shows a wider range of colorants, suggesting a more mature glassmaking technology.

The latest dating of the strata at Nuzi where most of the glass was found3 puts it pretty much contemporaneous with extensive glass remains in Egypt, in the middle of the second millennium BC — undermining some of the rationale for thinking the Nuzi glassmaking industry came first. True, there are also texts on glassmaking from Nineveh, the Assyrian capital in Mesopotamia, from the first millennium, which may be copies of older documents, while no Egyptian records from this period have been found. But that doesn't mean Egyptians weren't making the material.

The only real reason still to prefer Nuzi over Egypt, then, would be if the former technology looked more sophisticated than the latter. But the results of Shortland et al. seem to offer no evidence of that. The Egyptian artefacts seem to be of higher quality, and moreover have a wider colour range. That too doesn't clinch the matter, but it leaves open the question of where humankind first mastered this most useful and beautiful of materials.

References

  1. 1

    Shortland, A., Eremin, K., Kirk, S. & Armstrong, J. in Materials Issues in Art and Archaeology VIII (eds Vandiver, P. B., McCarthy, B., Tykot, R. H., Ruvalcaba-Sil, J. L. & Casadio, F.) 217–232 (MRS, 2008).

    Google Scholar 

  2. 2

    Shortland, A. J., Kirk, S., Eremin, K., Degryse, P. & Walton, M. Archaeometry https://doi.org/10.1111/arcm.12332 (2017).

    Article  Google Scholar 

  3. 3

    Stein, D. L. Z. Assyriologie und Vorderasiatische Archäologie 79, 36–60 (1989).

    Google Scholar 

Download references

Authors

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Ball, P. Who made the first glass?. Nature Mater 16, 1172 (2017). https://doi.org/10.1038/nmat5051

Download citation

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing