Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • News & Views
  • Published:

Glasses

Heirs of liquid treasures

The temperature dependence of the viscosity of most glass-forming liquids is known to depart significantly from the classical Arrhenius behaviour of simple fluids. The discovery of an unexpected correlation between the extent of this departure and the Poisson ratio of the resulting glass could lead to new understanding of glass ageing and viscous liquid dynamics.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Figure 1: Correlation between the temperature (T) dependence of the shear viscosity (η) of a glass-forming liquid and Poisson's ratio of the resulting glass.

References

  1. Angell, C. A., Ngai, K. L., McKenna, G. B., McMillan, P. F. & Martin, S. W. J. Appl. Phys. 88, 3113–3157 (2000).

    Article  CAS  Google Scholar 

  2. Novikiv, V. N. & Sokolov, A. P. Nature 431, 961–963 (2004).

    Article  Google Scholar 

  3. Tobolsky, A., Powell, R. E. & Eyring, H. in Frontiers in Chemistry Vol. 1 (eds Burk, R. E. & Grummit, O.) 125–190 (Interscience, New York, 1943).

    Google Scholar 

  4. Mooney, M. Trans. Soc. Rheol. 1, 63–94 (1957).

    Article  Google Scholar 

  5. Nemilov, S. V. Russ. J. Phys. Chem. 42, 726–728 (1968).

    Google Scholar 

  6. Adam, G. & Gibbs, J. H. J. Chem. Phys. 43, 139–146 (1965).

    Article  CAS  Google Scholar 

  7. Dyre, J. C., Olsen, N. B. & Christensen, T. Phys. Rev. B 53, 2171–2174 (1996).

    Article  CAS  Google Scholar 

  8. Martinez, L. -M. & Angell, C. A. Nature 410, 663–667 (2001).

    Article  CAS  Google Scholar 

  9. Scopigno, T., Ruocco, G., Sette, F. & Monaco, G. Science 302, 849–852 (2003).

    Article  CAS  Google Scholar 

  10. Bordat, P., Affouard, F., Descamps, M. & Ngai, K.L. Phys. Rev. Lett. 93, 105502 (2004).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dyre, J. Heirs of liquid treasures. Nature Mater 3, 749–750 (2004). https://doi.org/10.1038/nmat1247

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1038/nmat1247

This article is cited by

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing